Crystallography Open Database

Information card for entry 7021797

Preview

Coordinates	7021797.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C252 H258 Au12 O86 P14 W24
Calculated formula	C252 H252 Au12 O86 P14 W24
Title of publication	Two types of tetranuclear phosphanegold(i) cations as dimers of dinuclear units, [{(Au{P(p-RPh)3})2(μ-OH)}2](2+) (R = Me, F), synthesized by polyoxometalate-mediated clusterization.
Authors of publication	Yoshida, Takuya; Matsunaga, Satoshi; Nomiya, Kenji
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2013
Journal volume	42
Journal issue	32
Pages of publication	11418 - 11425
a	44.4487 ± 0.0009 Å
b	44.4487 ± 0.0009 Å
c	44.4487 ± 0.0009 Å
α	90°
β	90°
γ	90°
Cell volume	87817 ± 3 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	6
Space group number	230
Hermann-Mauguin space group symbol	I a -3 d
Hall space group symbol	-I 4bd 2c 3
Residual factor for all reflections	0.114
Residual factor for significantly intense reflections	0.0921
Weighted residual factors for significantly intense reflections	0.2235
Weighted residual factors for all reflections included in the refinement	0.2367
Goodness-of-fit parameter for all reflections included in the refinement	1.159
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179922 (current)	2016-03-25	cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/17.	7021797.cif
87692	2013-08-27	cif/ Adding structures of 7021797, 7021798, 7021799 via cif-deposit CGI script.	7021797.cif