Crystallography Open Database

Information card for entry 7025418

Preview

Coordinates	7025418.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C71 H68 P4 Pt2 Si2
Calculated formula	C71 H68 P4 Pt2 Si2
SMILES	[Pt]12([P](CC[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[SiH]1([Pt]3([P](CC[P]3(c3ccccc3)c3ccccc3)(c3ccccc3)c3ccccc3)[SiH]21c1ccccc1)c1ccccc1.c1(ccccc1)C
Title of publication	Syntheses of mono- and dinuclear silylplatinum complexes bearing a diphosphino ligand via stepwise bond activation of unsymmetric disilanes.
Authors of publication	Arii, Hidekazu; Takahashi, Makiko; Nanjo, Masato; Mochida, Kunio
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2010
Journal volume	39
Journal issue	28
Pages of publication	6434 - 6440
a	12.675 ± 0.0003 Å
b	16.388 ± 0.0006 Å
c	29.958 ± 0.001 Å
α	90°
β	90°
γ	90°
Cell volume	6222.8 ± 0.3 Å³
Cell temperature	123 ± 2 K
Ambient diffraction temperature	123 ± 2 K
Number of distinct elements	5
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for all reflections	0.0583
Residual factor for significantly intense reflections	0.0526
Weighted residual factors for significantly intense reflections	0.1349
Weighted residual factors for all reflections included in the refinement	0.1396
Goodness-of-fit parameter for all reflections included in the refinement	1.022
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179960 (current)	2016-03-25	cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/54.	7025418.cif
93038	2014-01-12	cif/ Adding structures of 7025413, 7025414, 7025415, 7025416, 7025417, 7025418 via cif-deposit CGI script.	7025418.cif