#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:35:29 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179978 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/72/7027216.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7027216
loop_
_publ_author_name
'Distler, Anne'
'Lohse, Douglas L.'
'Sevov, Slavi C.'
_publ_section_title
;
 Chains, planes, and tunnels of metal diphosphonates: synthesis,
 structure, and characterization of Na3Co(O3PCH2PO3)(OH),
 Na3Mg(O3PCH2PO3)F·H2O, Na2Co(O3PCH2PO3)·H2O,
 NaCo2(O3PCH2CH2CH2PO3)(OH), and Co2(O3PCH2PO3)(H2O)
;
_journal_issue                   11
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1805
_journal_paper_doi               10.1039/a809671f
_journal_year                    1999
_chemical_formula_sum            'C H3 Co Na3 O7 P2'
_chemical_formula_weight         316.87
_chemical_name_common            'sodium-cobalt methylene diphosphonate'
_chemical_name_systematic
;
 Na3Co(O3PCH2PO3)(OH)
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 118.650(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   7.7890(10)
_cell_length_b                   7.3290(10)
_cell_length_c                   7.9570(10)
_cell_measurement_temperature    293(2)
_cell_volume                     398.62(10)
_computing_cell_refinement       CAD4_(Enraf-Nonius,_1977)
_computing_data_collection       CAD4_(Enraf-Nonius,_1977)
_computing_data_reduction        SDP_Package_(Enraf-Nonius,_1985)
_computing_molecular_graphics    SHELXTL-V5.0
_computing_publication_material  SHELXTL-V5.0
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       'Enraf-Nonius CAD4'
_diffrn_measurement_method       omega-2theta
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0533
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            760
_diffrn_reflns_theta_max         24.95
_diffrn_reflns_theta_min         2.92
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  '2 hours'
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.719
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.5425
_exptl_absorpt_correction_type   Xabs
_exptl_crystal_colour            'colorless, transparent'
_exptl_crystal_density_diffrn    2.640
_exptl_crystal_description       'elongated plate'
_exptl_crystal_F_000             310
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.01
_refine_diff_density_max         1.335
_refine_diff_density_min         -0.552
_refine_diff_density_rms         0.152
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.182
_refine_ls_goodness_of_fit_obs   1.174
_refine_ls_hydrogen_treatment    reall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     83
_refine_ls_number_reflns         760
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.182
_refine_ls_restrained_S_obs      1.174
_refine_ls_R_factor_all          0.0724
_refine_ls_R_factor_obs          0.0444
_refine_ls_shift/esd_max         0.000
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0460P)²+0.2775P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1175
_refine_ls_wR_factor_obs         0.0978
_reflns_number_observed          556
_reflns_number_total             760
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            809671fsup1.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0460P)^2^+0.2775P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0460P)^2^+0.2775P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        398.62(9)
_cod_original_sg_symbol_H-M      P2(1)/m
_cod_database_code               7027216
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Co Co 0.0000 0.0000 0.0000 0.0109(4) Uani 1 d S
P1 P 0.6085(3) 0.2500 0.7533(3) 0.0084(5) Uani 1 d S
P2 P 0.7886(3) 0.2500 0.1960(3) 0.0091(5) Uani 1 d S
Na1 Na 0.3909(5) 0.2500 0.2745(5) 0.0162(8) Uani 1 d S
Na2 Na 0.2016(3) 0.0036(3) 0.4745(3) 0.0164(6) Uani 1 d .
O1 O 0.7102(8) 0.2500 0.3389(8) 0.0144(13) Uani 1 d S
O2 O 0.1074(9) 0.2500 0.0006(9) 0.0129(13) Uani 1 d S
O3 O 0.7202(5) 0.0755(5) 0.7630(5) 0.0130(9) Uani 1 d .
O4 O 0.9051(5) 0.0764(6) 0.2159(6) 0.0155(9) Uani 1 d .
O5 O 0.4051(8) 0.2500 0.5764(8) 0.0130(13) Uani 1 d S
C6 C 0.5719(12) 0.2500 -0.0373(12) 0.012(2) Uani 1 d S
H1 H 0.1330(135) 0.2500 -0.0827(137) 0.013(27) Uiso 1 d S
H2 H 0.4981(90) 0.1516(83) -0.0402(81) 0.012(16) Uiso 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Co O2 180.0 . 3
O2 Co O3 90.8(2) . 1_454
O2 Co O3 89.2(2) 3 1_454
O2 Co O3 89.2(2) . 3_656
O2 Co O3 90.8(2) 3 3_656
O3 Co O3 180.0 1_454 3_656
O2 Co O4 86.6(2) . 3_655
O2 Co O4 93.4(2) 3 3_655
O3 Co O4 87.73(14) 1_454 3_655
O3 Co O4 92.27(14) 3_656 3_655
O2 Co O4 93.4(2) . 1_455
O2 Co O4 86.6(2) 3 1_455
O3 Co O4 92.27(14) 1_454 1_455
O3 Co O4 87.73(14) 3_656 1_455
O4 Co O4 180.0 3_655 1_455
O2 Co Na1 41.2(2) . .
O2 Co Na1 138.8(2) 3 .
O3 Co Na1 130.99(11) 1_454 .
O3 Co Na1 49.01(11) 3_656 .
O4 Co Na1 96.13(11) 3_655 .
O4 Co Na1 83.87(11) 1_455 .
O2 Co Na1 138.8(2) . 3
O2 Co Na1 41.2(2) 3 3
O3 Co Na1 49.01(11) 1_454 3
O3 Co Na1 130.99(11) 3_656 3
O4 Co Na1 83.87(11) 3_655 3
O4 Co Na1 96.13(11) 1_455 3
Na1 Co Na1 180.0 . 3
O2 Co Na2 88.8(2) . 3
O2 Co Na2 91.2(2) 3 3
O3 Co Na2 44.03(11) 1_454 3
O3 Co Na2 135.97(11) 3_656 3
O4 Co Na2 43.71(10) 3_655 3
O4 Co Na2 136.29(10) 1_455 3
Na1 Co Na2 122.47(7) . 3
Na1 Co Na2 57.53(7) 3 3
O2 Co Na2 91.2(2) . .
O2 Co Na2 88.8(2) 3 .
O3 Co Na2 135.97(11) 1_454 .
O3 Co Na2 44.03(11) 3_656 .
O4 Co Na2 136.29(10) 3_655 .
O4 Co Na2 43.71(10) 1_455 .
Na1 Co Na2 57.53(7) . .
Na1 Co Na2 122.47(7) 3 .
Na2 Co Na2 180.0 3 .
O3 P1 O3 113.7(3) 4_565 .
O3 P1 O5 111.0(2) 4_565 .
O3 P1 O5 111.0(2) . .
O3 P1 C6 106.8(2) 4_565 1_556
O3 P1 C6 106.8(2) . 1_556
O5 P1 C6 107.1(4) . 1_556
O3 P1 Na1 91.3(2) 4_565 .
O3 P1 Na1 91.3(2) . .
O5 P1 Na1 38.6(2) . .
C6 P1 Na1 145.7(3) 1_556 .
O3 P1 Na2 144.1(2) 4_565 .
O3 P1 Na2 85.3(2) . .
O5 P1 Na2 33.80(7) . .
C6 P1 Na2 95.2(2) 1_556 .
Na1 P1 Na2 56.66(6) . .
O3 P1 Na2 85.3(2) 4_565 4_565
O3 P1 Na2 144.1(2) . 4_565
O5 P1 Na2 33.80(8) . 4_565
C6 P1 Na2 95.2(2) 1_556 4_565
Na1 P1 Na2 56.66(6) . 4_565
Na2 P1 Na2 64.38(9) . 4_565
O3 P1 Na2 95.9(2) 4_565 3_656
O3 P1 Na2 35.3(2) . 3_656
O5 P1 Na2 91.9(2) . 3_656
C6 P1 Na2 142.12(13) 1_556 3_656
Na1 P1 Na2 60.27(7) . 3_656
Na2 P1 Na2 82.46(6) . 3_656
Na2 P1 Na2 116.92(7) 4_565 3_656
O3 P1 Na2 35.3(2) 4_565 2_656
O3 P1 Na2 95.9(2) . 2_656
O5 P1 Na2 91.9(2) . 2_656
C6 P1 Na2 142.12(14) 1_556 2_656
Na1 P1 Na2 60.27(7) . 2_656
Na2 P1 Na2 116.92(7) . 2_656
Na2 P1 Na2 82.46(6) 4_565 2_656
Na2 P1 Na2 66.48(9) 3_656 2_656
O4 P2 O4 112.9(3) . 4_565
O4 P2 O1 110.7(2) . .
O4 P2 O1 110.7(2) 4_565 .
O4 P2 C6 108.7(2) . .
O4 P2 C6 108.7(2) 4_565 .
O1 P2 C6 104.7(4) . .
O4 P2 Na2 128.5(2) . 2_656
O4 P2 Na2 69.5(2) 4_565 2_656
O1 P2 Na2 41.19(11) . 2_656
C6 P2 Na2 119.1(2) . 2_656
O4 P2 Na2 69.5(2) . 3_656
O4 P2 Na2 128.5(2) 4_565 3_656
O1 P2 Na2 41.19(11) . 3_656
C6 P2 Na2 119.1(2) . 3_656
Na2 P2 Na2 71.42(9) 2_656 3_656
O4 P2 Na2 92.6(2) . 4_665
O4 P2 Na2 33.3(2) 4_565 4_665
O1 P2 Na2 96.1(2) . 4_665
C6 P2 Na2 142.0(2) . 4_665
Na2 P2 Na2 60.94(7) 2_656 4_665
Na2 P2 Na2 97.53(7) 3_656 4_665
O4 P2 Na2 33.3(2) . 1_655
O4 P2 Na2 92.6(2) 4_565 1_655
O1 P2 Na2 96.1(2) . 1_655
C6 P2 Na2 142.0(2) . 1_655
Na2 P2 Na2 97.53(7) 2_656 1_655
Na2 P2 Na2 60.94(7) 3_656 1_655
Na2 P2 Na2 63.78(8) 4_665 1_655
O4 P2 Na1 121.6(2) . .
O4 P2 Na1 121.6(2) 4_565 .
O1 P2 Na1 31.6(2) . .
C6 P2 Na1 73.1(3) . .
Na2 P2 Na1 61.25(7) 2_656 .
Na2 P2 Na1 61.25(7) 3_656 .
Na2 P2 Na1 122.12(7) 4_665 .
Na2 P2 Na1 122.12(7) 1_655 .
O2 Na1 O1 132.7(3) . .
O2 Na1 O5 122.4(3) . .
O1 Na1 O5 104.9(2) . .
O2 Na1 O3 76.16(12) . 3_656
O1 Na1 O3 107.65(11) . 3_656
O5 Na1 O3 88.06(12) . 3_656
O2 Na1 O3 76.16(12) . 2_656
O1 Na1 O3 107.65(11) . 2_656
O5 Na1 O3 88.06(12) . 2_656
O3 Na1 O3 144.3(2) 3_656 2_656
O2 Na1 Na2 90.5(2) . .
O1 Na1 Na2 126.90(14) . .
O5 Na1 Na2 45.44(10) . .
O3 Na1 Na2 46.07(10) 3_656 .
O3 Na1 Na2 112.43(14) 2_656 .
O2 Na1 Na2 90.5(2) . 4_565
O1 Na1 Na2 126.90(14) . 4_565
O5 Na1 Na2 45.44(10) . 4_565
O3 Na1 Na2 112.43(14) 3_656 4_565
O3 Na1 Na2 46.07(10) 2_656 4_565
Na2 Na1 Na2 68.79(11) . 4_565
O2 Na1 Co 36.29(7) . 2
O1 Na1 Co 134.71(12) . 2
O5 Na1 Co 104.56(15) . 2
O3 Na1 Co 106.95(13) 3_656 2
O3 Na1 Co 40.61(10) 2_656 2
Na2 Na1 Co 98.21(9) . 2
Na2 Na1 Co 61.27(6) 4_565 2
O2 Na1 Co 36.29(7) . .
O1 Na1 Co 134.71(12) . .
O5 Na1 Co 104.56(15) . .
O3 Na1 Co 40.61(10) 3_656 .
O3 Na1 Co 106.95(13) 2_656 .
Na2 Na1 Co 61.27(6) . .
Na2 Na1 Co 98.21(9) 4_565 .
Co Na1 Co 67.00(6) 2 .
O2 Na1 P1 146.4(2) . .
O1 Na1 P1 80.9(2) . .
O5 Na1 P1 24.02(15) . .
O3 Na1 P1 95.34(12) 3_656 .
O3 Na1 P1 95.34(12) 2_656 .
Na2 Na1 P1 62.35(7) . .
Na2 Na1 P1 62.35(7) 4_565 .
Co Na1 P1 123.59(8) 2 .
Co Na1 P1 123.59(8) . .
O2 Na1 Na2 141.56(11) . 2_656
O1 Na1 Na2 41.89(10) . 2_656
O5 Na1 Na2 79.95(15) . 2_656
O3 Na1 Na2 140.01(14) 3_656 2_656
O3 Na1 Na2 73.74(10) 2_656 2_656
Na2 Na1 Na2 122.88(11) . 2_656
Na2 Na1 Na2 85.52(7) 4_565 2_656
Co Na1 Na2 112.97(4) 2 2_656
Co Na1 Na2 175.42(12) . 2_656
P1 Na1 Na2 60.53(7) . 2_656
O2 Na1 Na2 141.56(11) . 3_656
O1 Na1 Na2 41.89(10) . 3_656
O5 Na1 Na2 79.95(15) . 3_656
O3 Na1 Na2 73.74(10) 3_656 3_656
O3 Na1 Na2 140.01(14) 2_656 3_656
Na2 Na1 Na2 85.52(7) . 3_656
Na2 Na1 Na2 122.87(11) 4_565 3_656
Co Na1 Na2 175.42(12) 2 3_656
Co Na1 Na2 112.97(4) . 3_656
P1 Na1 Na2 60.53(7) . 3_656
Na2 Na1 Na2 66.67(10) 2_656 3_656
O2 Na1 H1 16.8(21) . .
O1 Na1 H1 115.9(21) . .
O5 Na1 H1 139.2(21) . .
O3 Na1 H1 80.0(6) 3_656 .
O3 Na1 H1 80.0(6) 2_656 .
Na2 Na1 H1 104.3(17) . .
Na2 Na1 H1 104.3(17) 4_565 .
Co Na1 H1 44.8(13) 2 .
Co Na1 H1 44.8(13) . .
P1 Na1 H1 163.2(21) . .
Na2 Na1 H1 131.8(14) 2_656 .
Na2 Na1 H1 131.8(14) 3_656 .
O1 Na2 O5 118.3(2) 3_656 .
O1 Na2 O4 129.4(2) 3_656 1_455
O5 Na2 O4 111.3(2) . 1_455
O1 Na2 O3 102.3(2) 3_656 3_656
O5 Na2 O3 94.5(2) . 3_656
O4 Na2 O3 82.7(2) 1_455 3_656
O1 Na2 O4 54.6(2) 3_656 3_656
O5 Na2 O4 106.3(2) . 3_656
O4 Na2 O4 102.98(14) 1_455 3_656
O3 Na2 O4 154.3(2) 3_656 3_656
O1 Na2 P2 26.28(13) 3_656 3_656
O5 Na2 P2 115.5(2) . 3_656
O4 Na2 P2 119.29(14) 1_455 3_656
O3 Na2 P2 127.78(14) 3_656 3_656
O4 Na2 P2 28.35(8) 3_656 3_656
O1 Na2 Na1 136.1(2) 3_656 .
O5 Na2 Na1 47.3(2) . .
O4 Na2 Na1 85.90(14) 1_455 .
O3 Na2 Na1 51.07(11) 3_656 .
O4 Na2 Na1 153.06(12) 3_656 .
P2 Na2 Na1 154.80(10) 3_656 .
O1 Na2 Co 124.52(15) 3_656 .
O5 Na2 Co 106.2(2) . .
O4 Na2 Co 42.32(11) 1_455 .
O3 Na2 Co 40.34(10) 3_656 .
O4 Na2 Co 139.71(10) 3_656 .
P2 Na2 Co 137.96(8) 3_656 .
Na1 Na2 Co 61.20(7) . .
O1 Na2 Na2 85.1(2) 3_656 3_556
O5 Na2 Na2 120.1(2) . 3_556
O4 Na2 Na2 61.03(12) 1_455 3_556
O3 Na2 Na2 136.17(15) 3_656 3_556
O4 Na2 Na2 41.95(9) 3_656 3_556
P2 Na2 Na2 62.96(8) 3_656 3_556
Na1 Na2 Na2 138.71(12) . 3_556
Co Na2 Na2 100.24(8) . 3_556
O1 Na2 Na1 42.2(2) 3_656 3_656
O5 Na2 Na1 85.95(13) . 3_656
O4 Na2 Na1 155.61(15) 1_455 3_656
O3 Na2 Na1 78.76(12) 3_656 3_656
O4 Na2 Na1 87.64(11) 3_656 3_656
P2 Na2 Na1 63.11(8) 3_656 3_656
Na1 Na2 Na1 94.48(7) . 3_656
Co Na2 Na1 117.71(8) . 3_656
Na2 Na2 Na1 126.00(11) 3_556 3_656
O1 Na2 P1 96.49(15) 3_656 .
O5 Na2 P1 21.97(12) . .
O4 Na2 P1 133.20(14) 1_455 .
O3 Na2 P1 97.93(12) 3_656 .
O4 Na2 P1 96.11(10) 3_656 .
P2 Na2 P1 97.25(7) 3_656 .
Na1 Na2 P1 61.00(8) . .
Co Na2 P1 122.17(7) . .
Na2 Na2 P1 124.41(11) 3_556 .
Na1 Na2 P1 65.66(5) 3_656 .
O1 Na2 P1 80.09(14) 3_656 3_656
O5 Na2 P1 102.5(2) . 3_656
O4 Na2 P1 99.03(13) 1_455 3_656
O3 Na2 P1 22.40(11) 3_656 3_656
O4 Na2 P1 133.85(11) 3_656 3_656
P2 Na2 P1 106.00(7) 3_656 3_656
Na1 Na2 P1 67.66(6) . 3_656
Co Na2 P1 58.51(5) . 3_656
Na2 Na2 P1 136.85(11) 3_556 3_656
Na1 Na2 P1 59.21(7) 3_656 3_656
P1 Na2 P1 97.54(6) . 3_656
P2 O1 Na2 112.5(2) . 2_656
P2 O1 Na2 112.5(2) . 3_656
Na2 O1 Na2 109.9(3) 2_656 3_656
P2 O1 Na1 127.9(3) . .
Na2 O1 Na1 95.9(2) 2_656 .
Na2 O1 Na1 95.9(2) 3_656 .
Co O2 Co 131.1(3) . 2
Co O2 Na1 102.5(2) . .
Co O2 Na1 102.5(2) 2 .
Co O2 H1 105.9(23) . .
Co O2 H1 105.9(22) 2 .
Na1 O2 H1 107.1(70) . .
P1 O3 Co 124.7(2) . 1_656
P1 O3 Na2 122.3(2) . 3_656
Co O3 Na2 95.6(2) 1_656 3_656
P1 O3 Na1 129.4(2) . 3_656
Co O3 Na1 90.4(2) 1_656 3_656
Na2 O3 Na1 82.9(2) 3_656 3_656
P2 O4 Co 121.8(2) . 1_655
P2 O4 Na2 125.3(2) . 1_655
Co O4 Na2 94.0(2) 1_655 1_655
P2 O4 Na2 82.1(2) . 3_656
Co O4 Na2 154.1(2) 1_655 3_656
Na2 O4 Na2 77.02(14) 1_655 3_656
P1 O5 Na2 124.2(2) . 4_565
P1 O5 Na2 124.23(15) . .
Na2 O5 Na2 104.7(2) 4_565 .
P1 O5 Na1 117.4(3) . .
Na2 O5 Na1 87.3(2) 4_565 .
Na2 O5 Na1 87.3(2) . .
P2 C6 P1 117.3(5) . 1_554
P2 C6 H2 106.9(37) . .
P1 C6 H2 110.4(37) 1_554 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co O2 2.013(3) .
Co O2 2.013(3) 3
Co O3 2.161(4) 1_454
Co O3 2.161(4) 3_656
Co O4 2.242(4) 3_655
Co O4 2.242(4) 1_455
Co Na1 3.320(3) .
Co Na1 3.320(3) 3
Co Na2 3.322(2) 3
Co Na2 3.322(2) .
P1 O3 1.528(4) 4_565
P1 O3 1.528(4) .
P1 O5 1.534(6) .
P1 C6 1.820(9) 1_556
P1 Na1 3.346(4) .
P1 Na2 3.389(3) .
P1 Na2 3.389(3) 4_565
P1 Na2 3.391(3) 3_656
P1 Na2 3.391(3) 2_656
P2 O4 1.526(4) .
P2 O4 1.526(4) 4_565
P2 O1 1.527(6) .
P2 C6 1.814(9) .
P2 Na2 3.185(3) 2_656
P2 Na2 3.185(3) 3_656
P2 Na2 3.418(3) 4_665
P2 Na2 3.418(3) 1_655
P2 Na1 3.441(4) .
Na1 O2 2.239(7) .
Na1 O1 2.286(7) .
Na1 O5 2.351(7) .
Na1 O3 2.506(4) 3_656
Na1 O3 2.506(4) 2_656
Na1 Na2 3.196(4) .
Na1 Na2 3.196(4) 4_565
Na1 Co 3.320(3) 2
Na1 Na2 3.383(4) 2_656
Na1 Na2 3.383(4) 3_656
Na1 H1 2.58(9) .
Na2 O1 2.270(4) 3_656
Na2 O5 2.280(4) .
Na2 O4 2.301(4) 1_455
Na2 O3 2.320(4) 3_656
Na2 O4 3.012(5) 3_656
Na2 P2 3.185(3) 3_656
Na2 Na2 3.354(4) 3_556
Na2 Na1 3.383(4) 3_656
Na2 P1 3.391(3) 3_656
O1 Na2 2.270(4) 2_656
O1 Na2 2.270(4) 3_656
O2 Co 2.013(3) 2
O2 H1 0.78(9) .
O3 Co 2.161(4) 1_656
O3 Na2 2.320(4) 3_656
O3 Na1 2.506(4) 3_656
O4 Co 2.242(4) 1_655
O4 Na2 2.301(4) 1_655
O4 Na2 3.012(5) 3_656
O5 Na2 2.280(4) 4_565
C6 P1 1.820(9) 1_554
C6 H2 0.92(6) .
