Crystallography Open Database

Information card for entry 7033631

Preview

Coordinates	7033631.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	[V2(PS3)2(mu-Se2)(mu-Se)][PPh4]2
Formula	C91 H72 N3 O0.25 P4 S6 Se3 V2
Calculated formula	C91 H72 N3 O0.25 P4 S6 Se3 V2
Title of publication	Non-oxido divanadium(iv) and divanadium(v) thiolate complexes with a new type of chalcogenide bridging motif.
Authors of publication	Wu, Hong-Ming; Chang, Ya-Ho; Tsai, Yi-Fang; Hsu, Kuei-Fang; Lee, Gene-Hsiang; Hsu, Hua-Fen
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2015
Journal volume	44
Journal issue	10
Pages of publication	4468 - 4473
a	23.551 ± 0.019 Å
b	13.683 ± 0.011 Å
c	27.38 ± 0.02 Å
α	90°
β	99.212 ± 0.014°
γ	90°
Cell volume	8709 ± 12 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	8
Space group number	13
Hermann-Mauguin space group symbol	P 1 2/c 1
Hall space group symbol	-P 2yc
Residual factor for all reflections	0.1348
Residual factor for significantly intense reflections	0.0578
Weighted residual factors for significantly intense reflections	0.132
Weighted residual factors for all reflections included in the refinement	0.184
Goodness-of-fit parameter for all reflections included in the refinement	1.035
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
180042 (current)	2016-03-25	cif/7/03/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/03/36.	7033631.cif
133312	2015-03-06	cif/ Updating files of 7033631, 7033632, 7033633, 7033634 Original log message: Adding full bibliography for 7033631--7033634.cif.	7033631.cif
129667	2015-01-15	cif/ Adding structures of 7033631, 7033632, 7033633, 7033634 via cif-deposit CGI script.	7033631.cif