#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:34:43 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180045 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/39/7033924.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7033924
loop_
_publ_author_name
'Wang, Xiufeng'
'Li, Yungai'
'Hu, Peng'
'Wang, Juanjuan'
'Li, Licun'
_publ_section_title
;
 Slow magnetic relaxation and field-induced metamagnetism in nitronyl
 nitroxide-Dy(iii) magnetic chains.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4560
_journal_page_last               4567
_journal_paper_doi               10.1039/c4dt01878h
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C30 H24 Eu F18 N2 O10'
_chemical_formula_weight         1066.47
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-06-20 deposited with the CCDC.
2015-01-16 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 117.00(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   22.204(4)
_cell_length_b                   16.575(3)
_cell_length_c                   23.444(5)
_cell_measurement_reflns_used    22738
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      27.8904
_cell_measurement_theta_min      2.1126
_cell_volume                     7688(3)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      113(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0513
_diffrn_reflns_av_sigmaI/netI    0.0388
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            62273
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.11
_exptl_absorpt_coefficient_mu    1.774
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8206
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   CrystalClear
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.843
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             4184
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.108
_refine_diff_density_min         -0.871
_refine_diff_density_rms         0.097
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.998
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1111
_refine_ls_number_reflns         13559
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0422
_refine_ls_R_factor_gt           0.0354
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0700P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0960
_refine_ls_wR_factor_ref         0.1015
_reflns_number_gt                11984
_reflns_number_total             13559
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt01878h2.cif
_cod_data_source_block           Eu
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 7033922--7033925.cif.
;
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7033924
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.488174(8) 0.323733(10) 0.752264(8) 0.01545(7) Uani 1 1 d .
Eu2 Eu 0.008210(8) 0.631366(10) 0.737605(8) 0.01675(7) Uani 1 1 d .
F1 F 0.73177(11) 0.38072(15) 0.82575(11) 0.0352(6) Uani 1 1 d .
F2 F 0.73889(12) 0.28989(15) 0.89410(13) 0.0455(7) Uani 1 1 d .
F3 F 0.76105(12) 0.41456(17) 0.92302(12) 0.0470(7) Uani 1 1 d .
F4 F 0.59093(17) 0.48161(18) 0.99418(14) 0.0638(9) Uani 1 1 d .
F5 F 0.58104(19) 0.35703(19) 1.00211(14) 0.0682(10) Uani 1 1 d .
F6 F 0.49357(13) 0.4261(2) 0.94839(13) 0.0756(11) Uani 1 1 d .
F7 F 0.66297(11) 0.18511(14) 0.94079(11) 0.0368(6) Uani 1 1 d .
F8 F 0.60329(13) 0.07666(13) 0.91134(14) 0.0452(7) Uani 1 1 d .
F9 F 0.60509(14) 0.1485(2) 0.98830(12) 0.0580(8) Uani 1 1 d .
F10 F 0.3553(2) 0.3241(2) 0.8712(2) 0.1008(15) Uani 1 1 d .
F11 F 0.37583(16) 0.2086(3) 0.91208(18) 0.1129(17) Uani 1 1 d U
F12 F 0.31141(14) 0.2245(2) 0.81229(16) 0.0764(10) Uani 1 1 d .
F13 F 0.42745(16) 0.43621(18) 0.49791(12) 0.0592(8) Uani 1 1 d .
F14 F 0.51667(16) 0.47520(16) 0.58135(12) 0.0543(8) Uani 1 1 d .
F15 F 0.51072(18) 0.35528(18) 0.54580(15) 0.0650(9) Uani 1 1 d .
F16 F 0.23876(16) 0.3428(2) 0.51830(15) 0.0890(13) Uani 1 1 d .
F17 F 0.24809(16) 0.3840(2) 0.6068(2) 0.1131(19) Uani 1 1 d .
F18 F 0.25004(13) 0.25920(16) 0.58904(15) 0.0566(8) Uani 1 1 d .
F19 F 0.24848(15) 0.6139(4) 0.85347(16) 0.1140(18) Uani 1 1 d .
F20 F 0.26022(13) 0.55051(17) 0.93488(15) 0.0595(9) Uani 1 1 d .
F21 F 0.25978(14) 0.67690(16) 0.93833(19) 0.0741(12) Uani 1 1 d .
F22 F 0.08413(15) 0.5304(2) 0.99856(12) 0.0591(8) Uani 1 1 d .
F23 F -0.00677(15) 0.48667(16) 0.92137(12) 0.0500(7) Uani 1 1 d .
F24 F -0.00084(17) 0.60956(18) 0.94981(14) 0.0609(9) Uani 1 1 d .
F25 F 0.1251(2) 0.6475(2) 0.5995(2) 0.1128(17) Uani 1 1 d .
F26 F 0.17856(15) 0.7312(3) 0.67102(17) 0.0837(11) Uani 1 1 d .
F27 F 0.11318(18) 0.7723(3) 0.57818(19) 0.1008(15) Uani 1 1 d .
F28 F -0.11752(15) 0.83132(17) 0.51504(12) 0.0522(8) Uani 1 1 d .
F29 F -0.10393(13) 0.89282(13) 0.60129(12) 0.0409(6) Uani 1 1 d .
F30 F -0.16895(12) 0.78946(15) 0.56739(12) 0.0422(6) Uani 1 1 d .
F31 F -0.13957(13) 0.49072(16) 0.48379(11) 0.0455(7) Uani 1 1 d .
F32 F -0.03327(13) 0.47101(16) 0.53845(12) 0.0477(7) Uani 1 1 d .
F33 F -0.07076(16) 0.58843(15) 0.50047(13) 0.0513(7) Uani 1 1 d .
F34 F -0.27052(11) 0.54098(16) 0.58783(12) 0.0422(6) Uani 1 1 d .
F35 F -0.24240(12) 0.66375(15) 0.61656(13) 0.0385(6) Uani 1 1 d .
F36 F -0.23006(11) 0.57413(15) 0.68724(11) 0.0367(6) Uani 1 1 d .
O1 O 0.54969(12) 0.22293(14) 0.83312(11) 0.0213(5) Uani 1 1 d .
O2 O 0.41589(13) 0.27349(15) 0.79324(12) 0.0257(6) Uani 1 1 d .
O3 O 0.60365(12) 0.36323(14) 0.80097(11) 0.0193(5) Uani 1 1 d .
O4 O 0.51164(12) 0.39395(15) 0.84985(11) 0.0216(5) Uani 1 1 d .
O5 O 0.49134(13) 0.37035(14) 0.65635(12) 0.0236(6) Uani 1 1 d .
O6 O 0.37817(13) 0.30832(14) 0.66607(11) 0.0232(6) Uani 1 1 d .
O7 O 0.43899(13) 0.45545(13) 0.72681(12) 0.0246(6) Uani 1 1 d .
O8 O 0.48961(13) 0.71522(13) 0.80305(11) 0.0219(6) Uani 1 1 d .
O9 O 0.74669(14) 0.56409(18) 0.79678(15) 0.0379(7) Uani 1 1 d .
O10 O 0.59116(14) 0.60435(18) 0.88692(12) 0.0307(6) Uani 1 1 d .
O11 O 0.01187(13) 0.58149(14) 0.83647(12) 0.0229(6) Uani 1 1 d .
O12 O 0.12174(13) 0.64233(15) 0.81866(12) 0.0254(6) Uani 1 1 d .
O13 O -0.02736(13) 0.56684(15) 0.63480(12) 0.0251(6) Uani 1 1 d .
O14 O -0.10662(12) 0.59399(14) 0.69787(11) 0.0191(5) Uani 1 1 d .
O15 O 0.07548(13) 0.68248(15) 0.69091(12) 0.0262(6) Uani 1 1 d .
O16 O -0.05334(13) 0.73749(14) 0.66480(12) 0.0240(6) Uani 1 1 d .
O17 O -0.00559(13) 0.73516(14) 0.80255(12) 0.0239(6) Uani 1 1 d .
O18 O -0.05546(14) 1.00044(14) 0.74480(13) 0.0293(6) Uani 1 1 d .
O19 O 0.24543(15) 0.88570(18) 0.78967(15) 0.0396(7) Uani 1 1 d .
O20 O 0.09974(14) 0.84443(18) 0.89034(13) 0.0318(6) Uani 1 1 d .
N1 N 0.43556(15) 0.52424(16) 0.75068(14) 0.0188(7) Uani 1 1 d .
N2 N 0.45887(16) 0.64631(17) 0.78624(14) 0.0210(7) Uani 1 1 d .
N3 N -0.03525(16) 0.80386(17) 0.79247(14) 0.0209(7) Uani 1 1 d .
N4 N -0.05779(15) 0.92985(17) 0.76600(15) 0.0217(7) Uani 1 1 d .
C1 C 0.6044(2) 0.1533(3) 0.93164(19) 0.0303(9) Uani 1 1 d .
C2 C 0.54313(19) 0.1997(2) 0.88115(17) 0.0226(8) Uani 1 1 d .
C3 C 0.48820(19) 0.2094(2) 0.89294(18) 0.0260(9) Uani 1 1 d .
H3 H 0.4909 0.1929 0.9320 0.031 Uiso 1 1 calc R
C4 C 0.42799(19) 0.2441(2) 0.84668(18) 0.0260(9) Uani 1 1 d .
C5 C 0.3683(2) 0.2486(3) 0.8617(2) 0.0432(12) Uani 1 1 d .
C6 C 0.7200(2) 0.3659(3) 0.8748(2) 0.0296(10) Uani 1 1 d .
C7 C 0.64478(18) 0.3768(2) 0.85803(17) 0.0221(8) Uani 1 1 d .
C8 C 0.63175(18) 0.3959(2) 0.90924(17) 0.0242(8) Uani 1 1 d .
H8 H 0.6676 0.4049 0.9495 0.029 Uiso 1 1 calc R
C9 C 0.56540(19) 0.4019(2) 0.90086(17) 0.0214(8) Uani 1 1 d .
C10 C 0.5562(2) 0.4188(3) 0.96109(18) 0.0291(9) Uani 1 1 d .
C11 C 0.4748(2) 0.4127(3) 0.55535(19) 0.0364(11) Uani 1 1 d .
C12 C 0.4472(2) 0.3823(2) 0.59995(17) 0.0257(9) Uani 1 1 d .
C13 C 0.3768(2) 0.3701(2) 0.57396(18) 0.0297(10) Uani 1 1 d .
H13 H 0.3488 0.3854 0.5320 0.036 Uiso 1 1 calc R
C14 C 0.3489(2) 0.3356(2) 0.61033(17) 0.0231(8) Uani 1 1 d .
C15 C 0.2714(2) 0.3304(2) 0.5813(2) 0.0366(11) Uani 1 1 d .
C16 C 0.8045(2) 0.5818(3) 0.8559(2) 0.0436(12) Uani 1 1 d .
H16A H 0.8447 0.5757 0.8508 0.065 Uiso 1 1 calc R
H16B H 0.8060 0.5454 0.8884 0.065 Uiso 1 1 calc R
H16C H 0.8015 0.6363 0.8684 0.065 Uiso 1 1 calc R
C17 C 0.6845(2) 0.5670(2) 0.7943(2) 0.0285(9) Uani 1 1 d .
C18 C 0.6739(2) 0.5870(2) 0.84654(19) 0.0284(9) Uani 1 1 d .
H18 H 0.7102 0.5985 0.8860 0.034 Uiso 1 1 calc R
C19 C 0.6300(2) 0.5479(2) 0.73476(19) 0.0292(9) Uani 1 1 d .
H19 H 0.6380 0.5333 0.7005 0.035 Uiso 1 1 calc R
C20 C 0.5651(2) 0.5507(2) 0.72727(18) 0.0228(8) Uani 1 1 d .
H20 H 0.5291 0.5378 0.6879 0.027 Uiso 1 1 calc R
C21 C 0.6075(2) 0.5894(2) 0.83859(17) 0.0242(8) Uani 1 1 d .
C22 C 0.6449(2) 0.6264(3) 0.9490(2) 0.0365(11) Uani 1 1 d .
H22A H 0.6688 0.6722 0.9445 0.055 Uiso 1 1 calc R
H22B H 0.6756 0.5819 0.9663 0.055 Uiso 1 1 calc R
H22C H 0.6260 0.6396 0.9774 0.055 Uiso 1 1 calc R
C23 C 0.55265(18) 0.5729(2) 0.77839(17) 0.0201(8) Uani 1 1 d .
C24 C 0.48453(18) 0.5801(2) 0.77118(16) 0.0191(8) Uani 1 1 d .
C25 C 0.37059(19) 0.5518(2) 0.74948(18) 0.0223(8) Uani 1 1 d .
C26 C 0.3451(2) 0.4858(2) 0.7782(2) 0.0346(10) Uani 1 1 d .
H26A H 0.3321 0.4395 0.7506 0.052 Uiso 1 1 calc R
H26B H 0.3067 0.5052 0.7827 0.052 Uiso 1 1 calc R
H26C H 0.3803 0.4710 0.8195 0.052 Uiso 1 1 calc R
C27 C 0.3199(2) 0.5680(3) 0.6793(2) 0.0351(10) Uani 1 1 d .
H27A H 0.3368 0.6103 0.6625 0.053 Uiso 1 1 calc R
H27B H 0.2773 0.5840 0.6769 0.053 Uiso 1 1 calc R
H27C H 0.3139 0.5198 0.6546 0.053 Uiso 1 1 calc R
C28 C 0.3955(2) 0.6297(2) 0.7917(2) 0.0253(9) Uani 1 1 d .
C29 C 0.4181(2) 0.6158(3) 0.8628(2) 0.0438(12) Uani 1 1 d .
H29A H 0.3797 0.6018 0.8692 0.066 Uiso 1 1 calc R
H29B H 0.4384 0.6641 0.8862 0.066 Uiso 1 1 calc R
H29C H 0.4505 0.5726 0.8778 0.066 Uiso 1 1 calc R
C30 C 0.3483(2) 0.7020(3) 0.7668(3) 0.0454(12) Uani 1 1 d .
H30A H 0.3402 0.7140 0.7238 0.068 Uiso 1 1 calc R
H30B H 0.3687 0.7478 0.7937 0.068 Uiso 1 1 calc R
H30C H 0.3063 0.6897 0.7672 0.068 Uiso 1 1 calc R
C31 C 0.2311(2) 0.6154(3) 0.9001(2) 0.0408(12) Uani 1 1 d .
C32 C 0.15350(19) 0.6152(2) 0.87401(18) 0.0271(9) Uani 1 1 d .
C33 C 0.1283(2) 0.5857(3) 0.91423(19) 0.0320(10) Uani 1 1 d .
H33 H 0.1580 0.5729 0.9564 0.038 Uiso 1 1 calc R
C34 C 0.05858(19) 0.5746(2) 0.89238(18) 0.0236(8) Uani 1 1 d .
C35 C 0.0345(2) 0.5500(3) 0.9418(2) 0.0330(10) Uani 1 1 d .
C36 C 0.1194(2) 0.7179(3) 0.6206(2) 0.0417(11) Uani 1 1 d .
C37 C 0.0620(2) 0.7188(2) 0.64001(18) 0.0273(9) Uani 1 1 d .
C38 C 0.0019(2) 0.7585(2) 0.59986(18) 0.0271(9) Uani 1 1 d .
H38 H -0.0031 0.7799 0.5613 0.033 Uiso 1 1 calc R
C39 C -0.0500(2) 0.7666(2) 0.61639(17) 0.0238(8) Uani 1 1 d .
C40 C -0.1113(2) 0.8196(2) 0.5742(2) 0.0324(10) Uani 1 1 d .
C41 C -0.0818(2) 0.5239(2) 0.52769(19) 0.0301(9) Uani 1 1 d .
C42 C -0.08324(19) 0.5474(2) 0.59027(17) 0.0219(8) Uani 1 1 d .
C43 C -0.14579(19) 0.5480(2) 0.59046(17) 0.0210(8) Uani 1 1 d .
H43 H -0.1839 0.5305 0.5544 0.025 Uiso 1 1 calc R
C44 C -0.15225(18) 0.5744(2) 0.64385(17) 0.0199(8) Uani 1 1 d .
C45 C -0.22475(19) 0.5870(2) 0.63454(18) 0.0260(9) Uani 1 1 d .
C46 C 0.3052(2) 0.8683(3) 0.8468(2) 0.0448(12) Uani 1 1 d .
H46A H 0.3438 0.8735 0.8390 0.067 Uiso 1 1 calc R
H46B H 0.3028 0.8142 0.8603 0.067 Uiso 1 1 calc R
H46C H 0.3091 0.9055 0.8798 0.067 Uiso 1 1 calc R
C47 C 0.1848(2) 0.8835(2) 0.7910(2) 0.0287(9) Uani 1 1 d .
C48 C 0.1772(2) 0.8614(2) 0.8445(2) 0.0294(9) Uani 1 1 d .
H48 H 0.2146 0.8473 0.8824 0.035 Uiso 1 1 calc R
C49 C 0.1287(2) 0.9054(2) 0.73325(19) 0.0296(9) Uani 1 1 d .
H49 H 0.1346 0.9204 0.6979 0.036 Uiso 1 1 calc R
C50 C 0.0650(2) 0.9043(2) 0.72950(18) 0.0257(9) Uani 1 1 d .
H50 H 0.0279 0.9200 0.6918 0.031 Uiso 1 1 calc R
C51 C 0.1128(2) 0.8607(2) 0.84035(18) 0.0245(8) Uani 1 1 d .
C52 C 0.1549(2) 0.8214(3) 0.9509(2) 0.0385(11) Uani 1 1 d .
H52A H 0.1746 0.7721 0.9458 0.058 Uiso 1 1 calc R
H52B H 0.1383 0.8136 0.9818 0.058 Uiso 1 1 calc R
H52C H 0.1885 0.8632 0.9654 0.058 Uiso 1 1 calc R
C53 C 0.05581(19) 0.8799(2) 0.78222(17) 0.0218(8) Uani 1 1 d .
C54 C -0.01093(18) 0.8721(2) 0.77944(17) 0.0193(8) Uani 1 1 d .
C55 C -0.09661(19) 0.8174(2) 0.80221(19) 0.0226(8) Uani 1 1 d .
C56 C -0.1460(2) 0.7480(2) 0.7716(2) 0.0359(10) Uani 1 1 d .
H56A H -0.1554 0.7427 0.7276 0.054 Uiso 1 1 calc R
H56B H -0.1872 0.7587 0.7740 0.054 Uiso 1 1 calc R
H56C H -0.1264 0.6988 0.7940 0.054 Uiso 1 1 calc R
C57 C -0.0707(2) 0.8170(3) 0.8750(2) 0.0380(11) Uani 1 1 d .
H57A H -0.0513 0.7653 0.8918 0.057 Uiso 1 1 calc R
H57B H -0.1076 0.8274 0.8847 0.057 Uiso 1 1 calc R
H57C H -0.0369 0.8581 0.8940 0.057 Uiso 1 1 calc R
C58 C -0.12030(19) 0.9014(2) 0.76963(19) 0.0258(9) Uani 1 1 d .
C59 C -0.1766(2) 0.8969(3) 0.7010(2) 0.0418(11) Uani 1 1 d .
H59A H -0.1835 0.9492 0.6815 0.063 Uiso 1 1 calc R
H59B H -0.2176 0.8791 0.7012 0.063 Uiso 1 1 calc R
H59C H -0.1641 0.8594 0.6770 0.063 Uiso 1 1 calc R
C60 C -0.1377(2) 0.9630(2) 0.8083(2) 0.0405(11) Uani 1 1 d .
H60A H -0.0984 0.9734 0.8481 0.061 Uiso 1 1 calc R
H60B H -0.1731 0.9421 0.8168 0.061 Uiso 1 1 calc R
H60C H -0.1525 1.0123 0.7844 0.061 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Eu1 O6 71.46(9) . .
O2 Eu1 O3 133.24(8) . .
O6 Eu1 O3 155.16(9) . .
O2 Eu1 O7 96.06(9) . .
O6 Eu1 O7 73.09(8) . .
O3 Eu1 O7 98.00(8) . .
O2 Eu1 O8 107.46(9) . 2_646
O6 Eu1 O8 81.00(9) . 2_646
O3 Eu1 O8 91.40(9) . 2_646
O7 Eu1 O8 137.13(8) . 2_646
O2 Eu1 O4 71.20(9) . .
O6 Eu1 O4 123.86(9) . .
O3 Eu1 O4 71.88(9) . .
O7 Eu1 O4 70.90(9) . .
O8 Eu1 O4 150.42(8) 2_646 .
O2 Eu1 O5 143.61(9) . .
O6 Eu1 O5 72.22(9) . .
O3 Eu1 O5 82.98(9) . .
O7 Eu1 O5 71.21(9) . .
O8 Eu1 O5 68.60(8) 2_646 .
O4 Eu1 O5 130.36(8) . .
O2 Eu1 O1 71.68(9) . .
O6 Eu1 O1 125.95(8) . .
O3 Eu1 O1 73.31(8) . .
O7 Eu1 O1 148.62(8) . .
O8 Eu1 O1 74.04(8) 2_646 .
O4 Eu1 O1 77.77(8) . .
O5 Eu1 O1 134.81(9) . .
O18 Eu2 O14 98.16(9) 2_546 .
O18 Eu2 O15 94.92(9) 2_546 .
O14 Eu2 O15 134.70(9) . .
O18 Eu2 O12 72.85(9) 2_546 .
O14 Eu2 O12 153.80(8) . .
O15 Eu2 O12 71.35(9) . .
O18 Eu2 O16 149.49(9) 2_546 .
O14 Eu2 O16 75.39(9) . .
O15 Eu2 O16 71.62(9) . .
O12 Eu2 O16 124.58(9) . .
O18 Eu2 O17 136.02(9) 2_546 .
O14 Eu2 O17 90.71(9) . .
O15 Eu2 O17 108.91(9) . .
O12 Eu2 O17 80.39(9) . .
O16 Eu2 O17 74.40(8) . .
O18 Eu2 O13 71.71(9) 2_546 .
O14 Eu2 O13 71.68(9) . .
O15 Eu2 O13 71.78(9) . .
O12 Eu2 O13 125.35(9) . .
O16 Eu2 O13 78.02(9) . .
O17 Eu2 O13 150.30(8) . .
O18 Eu2 O11 72.60(9) 2_546 .
O14 Eu2 O11 81.36(9) . .
O15 Eu2 O11 143.79(9) . .
O12 Eu2 O11 72.49(9) . .
O16 Eu2 O11 133.65(9) . .
O17 Eu2 O11 66.31(8) . .
O13 Eu2 O11 130.94(9) . .
C2 O1 Eu1 131.0(2) . .
C4 O2 Eu1 131.7(2) . .
C7 O3 Eu1 131.9(2) . .
C9 O4 Eu1 131.2(2) . .
C12 O5 Eu1 134.0(3) . .
C14 O6 Eu1 134.1(3) . .
N1 O7 Eu1 144.1(2) . .
N2 O8 Eu1 134.9(2) . 2_656
C17 O9 C16 118.9(3) . .
C21 O10 C22 118.2(3) . .
C34 O11 Eu2 133.0(2) . .
C32 O12 Eu2 134.3(3) . .
C42 O13 Eu2 134.3(2) . .
C44 O14 Eu2 134.3(2) . .
C37 O15 Eu2 133.3(3) . .
C39 O16 Eu2 132.1(2) . .
N3 O17 Eu2 136.1(2) . .
N4 O18 Eu2 149.7(2) . 2_556
C47 O19 C46 118.8(3) . .
C51 O20 C52 118.9(3) . .
O7 N1 C24 124.7(3) . .
O7 N1 C25 120.5(3) . .
C24 N1 C25 114.4(3) . .
O8 N2 C24 124.5(3) . .
O8 N2 C28 121.5(3) . .
C24 N2 C28 113.4(3) . .
O17 N3 C54 124.2(3) . .
O17 N3 C55 122.1(3) . .
C54 N3 C55 113.3(3) . .
O18 N4 C54 125.4(3) . .
O18 N4 C58 120.6(3) . .
C54 N4 C58 113.6(3) . .
F9 C1 F7 107.3(3) . .
F9 C1 F8 106.6(3) . .
F7 C1 F8 106.9(3) . .
F9 C1 C2 113.8(3) . .
F7 C1 C2 112.6(3) . .
F8 C1 C2 109.2(3) . .
O1 C2 C3 128.0(3) . .
O1 C2 C1 114.7(3) . .
C3 C2 C1 117.2(3) . .
C2 C3 C4 120.8(4) . .
O2 C4 C3 128.8(4) . .
O2 C4 C5 113.5(3) . .
C3 C4 C5 117.7(3) . .
F11 C5 F10 106.2(5) . .
F11 C5 F12 108.7(4) . .
F10 C5 F12 103.7(4) . .
F11 C5 C4 114.9(4) . .
F10 C5 C4 111.2(4) . .
F12 C5 C4 111.5(4) . .
F1 C6 F2 108.4(3) . .
F1 C6 F3 107.1(3) . .
F2 C6 F3 106.9(3) . .
F1 C6 C7 112.1(3) . .
F2 C6 C7 109.4(3) . .
F3 C6 C7 112.6(3) . .
O3 C7 C8 128.8(3) . .
O3 C7 C6 115.6(3) . .
C8 C7 C6 115.5(3) . .
C7 C8 C9 120.8(3) . .
O4 C9 C8 127.7(3) . .
O4 C9 C10 115.3(3) . .
C8 C9 C10 117.0(3) . .
F6 C10 F4 110.1(4) . .
F6 C10 F5 106.6(4) . .
F4 C10 F5 103.9(3) . .
F6 C10 C9 112.5(3) . .
F4 C10 C9 113.5(3) . .
F5 C10 C9 109.6(3) . .
F15 C11 F13 107.3(3) . .
F15 C11 F14 106.6(4) . .
F13 C11 F14 107.4(3) . .
F15 C11 C12 109.9(3) . .
F13 C11 C12 114.3(4) . .
F14 C11 C12 110.9(3) . .
O5 C12 C13 128.0(4) . .
O5 C12 C11 114.3(4) . .
C13 C12 C11 117.7(3) . .
C14 C13 C12 120.7(3) . .
O6 C14 C13 128.9(4) . .
O6 C14 C15 112.7(4) . .
C13 C14 C15 118.3(3) . .
F17 C15 F18 107.9(5) . .
F17 C15 F16 105.9(4) . .
F18 C15 F16 104.0(3) . .
F17 C15 C14 110.9(3) . .
F18 C15 C14 113.0(3) . .
F16 C15 C14 114.6(4) . .
O9 C17 C18 123.2(4) . .
O9 C17 C19 115.7(4) . .
C18 C17 C19 121.1(4) . .
C17 C18 C21 118.6(4) . .
C20 C19 C17 119.9(4) . .
C19 C20 C23 120.3(4) . .
O10 C21 C18 123.9(3) . .
O10 C21 C23 115.7(3) . .
C18 C21 C23 120.4(3) . .
C20 C23 C21 119.5(3) . .
C20 C23 C24 121.6(3) . .
C21 C23 C24 118.8(3) . .
N1 C24 N2 106.5(3) . .
N1 C24 C23 128.3(3) . .
N2 C24 C23 125.2(3) . .
N1 C25 C26 108.7(3) . .
N1 C25 C27 107.7(3) . .
C26 C25 C27 111.1(3) . .
N1 C25 C28 100.2(3) . .
C26 C25 C28 114.1(3) . .
C27 C25 C28 114.1(3) . .
N2 C28 C30 109.5(3) . .
N2 C28 C29 105.5(3) . .
C30 C28 C29 111.4(4) . .
N2 C28 C25 100.0(3) . .
C30 C28 C25 114.9(3) . .
C29 C28 C25 114.3(3) . .
F19 C31 F21 110.3(5) . .
F19 C31 F20 104.5(4) . .
F21 C31 F20 105.1(3) . .
F19 C31 C32 111.5(3) . .
F21 C31 C32 112.3(4) . .
F20 C31 C32 112.8(4) . .
O12 C32 C33 128.6(4) . .
O12 C32 C31 114.5(4) . .
C33 C32 C31 117.0(4) . .
C32 C33 C34 121.1(4) . .
O11 C34 C33 128.4(4) . .
O11 C34 C35 114.0(3) . .
C33 C34 C35 117.6(3) . .
F22 C35 F24 108.3(4) . .
F22 C35 F23 106.9(3) . .
F24 C35 F23 106.4(4) . .
F22 C35 C34 114.1(4) . .
F24 C35 C34 109.9(3) . .
F23 C35 C34 110.9(3) . .
F25 C36 F27 109.2(5) . .
F25 C36 F26 105.1(4) . .
F27 C36 F26 106.6(4) . .
F25 C36 C37 111.0(4) . .
F27 C36 C37 113.8(4) . .
F26 C36 C37 110.6(4) . .
O15 C37 C38 127.9(4) . .
O15 C37 C36 114.0(4) . .
C38 C37 C36 118.1(4) . .
C39 C38 C37 121.3(4) . .
O16 C39 C38 127.7(4) . .
O16 C39 C40 113.5(4) . .
C38 C39 C40 118.8(3) . .
F30 C40 F28 107.0(3) . .
F30 C40 F29 107.6(4) . .
F28 C40 F29 106.9(3) . .
F30 C40 C39 112.8(3) . .
F28 C40 C39 113.1(4) . .
F29 C40 C39 109.1(3) . .
F32 C41 F33 108.4(4) . .
F32 C41 F31 106.6(3) . .
F33 C41 F31 106.4(3) . .
F32 C41 C42 110.8(3) . .
F33 C41 C42 110.2(3) . .
F31 C41 C42 114.1(3) . .
O13 C42 C43 127.6(4) . .
O13 C42 C41 114.9(3) . .
C43 C42 C41 117.4(3) . .
C42 C43 C44 121.0(3) . .
O14 C44 C43 128.6(3) . .
O14 C44 C45 115.0(3) . .
C43 C44 C45 116.3(3) . .
F36 C45 F35 108.2(3) . .
F36 C45 F34 108.5(3) . .
F35 C45 F34 106.1(3) . .
F36 C45 C44 112.3(3) . .
F35 C45 C44 108.2(3) . .
F34 C45 C44 113.2(3) . .
O19 C47 C48 123.6(4) . .
O19 C47 C49 115.1(4) . .
C48 C47 C49 121.2(4) . .
C47 C48 C51 118.9(4) . .
C50 C49 C47 119.6(4) . .
C49 C50 C53 120.2(4) . .
O20 C51 C48 124.0(4) . .
O20 C51 C53 115.4(3) . .
C48 C51 C53 120.5(4) . .
C50 C53 C51 119.4(4) . .
C50 C53 C54 122.5(3) . .
C51 C53 C54 118.0(3) . .
N4 C54 N3 107.7(3) . .
N4 C54 C53 127.7(3) . .
N3 C54 C53 124.6(3) . .
N3 C55 C56 108.9(3) . .
N3 C55 C57 105.1(3) . .
C56 C55 C57 110.3(3) . .
N3 C55 C58 100.8(3) . .
C56 C55 C58 115.6(3) . .
C57 C55 C58 115.0(3) . .
N4 C58 C60 108.2(3) . .
N4 C58 C59 106.9(3) . .
C60 C58 C59 110.6(4) . .
N4 C58 C55 101.1(3) . .
C60 C58 C55 115.2(3) . .
C59 C58 C55 113.9(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O2 2.365(3) .
Eu1 O6 2.373(3) .
Eu1 O3 2.377(2) .
Eu1 O7 2.392(2) .
Eu1 O8 2.396(2) 2_646
Eu1 O4 2.404(2) .
Eu1 O5 2.409(2) .
Eu1 O1 2.429(2) .
Eu2 O18 2.364(2) 2_546
Eu2 O14 2.366(2) .
Eu2 O15 2.373(3) .
Eu2 O12 2.377(3) .
Eu2 O16 2.399(2) .
Eu2 O17 2.407(2) .
Eu2 O13 2.418(3) .
Eu2 O11 2.427(3) .
F1 C6 1.313(5) .
F2 C6 1.339(5) .
F3 C6 1.350(5) .
F4 C10 1.317(5) .
F5 C10 1.341(5) .
F6 C10 1.289(5) .
F7 C1 1.327(5) .
F8 C1 1.353(5) .
F9 C1 1.324(5) .
F10 C5 1.325(6) .
F11 C5 1.296(5) .
F12 C5 1.330(6) .
F13 C11 1.336(5) .
F14 C11 1.340(5) .
F15 C11 1.324(5) .
F16 C15 1.334(5) .
F17 C15 1.302(6) .
F18 C15 1.314(5) .
F19 C31 1.315(6) .
F20 C31 1.326(5) .
F21 C31 1.315(6) .
F22 C35 1.326(5) .
F23 C35 1.332(5) .
F24 C35 1.327(5) .
F25 C36 1.295(6) .
F26 C36 1.327(6) .
F27 C36 1.301(5) .
F28 C40 1.343(5) .
F29 C40 1.345(5) .
F30 C40 1.315(5) .
F31 C41 1.346(5) .
F32 C41 1.322(4) .
F33 C41 1.323(5) .
F34 C45 1.343(5) .
F35 C45 1.341(5) .
F36 C45 1.311(4) .
O1 C2 1.260(4) .
O2 C4 1.254(4) .
O3 C7 1.251(4) .
O4 C9 1.255(4) .
O5 C12 1.254(4) .
O6 C14 1.250(4) .
O7 N1 1.288(4) .
O8 N2 1.297(4) .
O8 Eu1 2.396(2) 2_656
O9 C17 1.357(5) .
O9 C16 1.428(5) .
O10 C21 1.360(4) .
O10 C22 1.449(5) .
O11 C34 1.254(4) .
O12 C32 1.246(4) .
O13 C42 1.248(4) .
O14 C44 1.253(4) .
O15 C37 1.246(4) .
O16 C39 1.266(4) .
O17 N3 1.283(4) .
O18 N4 1.282(4) .
O18 Eu2 2.364(2) 2_556
O19 C47 1.361(5) .
O19 C46 1.423(5) .
O20 C51 1.356(5) .
O20 C52 1.443(5) .
N1 C24 1.340(5) .
N1 C25 1.501(5) .
N2 C24 1.356(5) .
N2 C28 1.494(5) .
N3 C54 1.347(5) .
N3 C55 1.497(5) .
N4 C54 1.342(5) .
N4 C58 1.504(5) .
C1 C2 1.543(5) .
C2 C3 1.377(5) .
C3 C4 1.406(5) .
C4 C5 1.521(6) .
C6 C7 1.543(5) .
C7 C8 1.393(5) .
C8 C9 1.399(5) .
C9 C10 1.541(5) .
C11 C12 1.518(6) .
C12 C13 1.412(6) .
C13 C14 1.384(6) .
C14 C15 1.541(6) .
C17 C18 1.387(6) .
C17 C19 1.407(6) .
C18 C21 1.401(5) .
C19 C20 1.373(6) .
C20 C23 1.395(5) .
C21 C23 1.410(5) .
C23 C24 1.449(5) .
C25 C26 1.522(5) .
C25 C27 1.538(5) .
C25 C28 1.567(5) .
C28 C30 1.523(6) .
C28 C29 1.525(6) .
C31 C32 1.545(5) .
C32 C33 1.387(6) .
C33 C34 1.404(5) .
C34 C35 1.534(5) .
C36 C37 1.538(6) .
C37 C38 1.398(5) .
C38 C39 1.380(5) .
C39 C40 1.543(5) .
C41 C42 1.532(5) .
C42 C43 1.391(5) .
C43 C44 1.394(5) .
C44 C45 1.538(5) .
C47 C48 1.388(6) .
C47 C49 1.408(6) .
C48 C51 1.389(5) .
C49 C50 1.377(6) .
C50 C53 1.401(5) .
C51 C53 1.412(5) .
C53 C54 1.459(5) .
C55 C56 1.525(5) .
C55 C57 1.534(6) .
C55 C58 1.560(5) .
C58 C60 1.527(5) .
C58 C59 1.527(6) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O2 Eu1 O1 C2 -26.7(3) .
O6 Eu1 O1 C2 -75.9(3) .
O3 Eu1 O1 C2 121.8(3) .
O7 Eu1 O1 C2 44.0(4) .
O8 Eu1 O1 C2 -141.8(3) 2_646
O4 Eu1 O1 C2 47.3(3) .
O5 Eu1 O1 C2 -176.8(3) .
O6 Eu1 O2 C4 167.6(4) .
O3 Eu1 O2 C4 -15.6(4) .
O7 Eu1 O2 C4 -122.6(3) .
O8 Eu1 O2 C4 93.7(3) 2_646
O4 Eu1 O2 C4 -55.1(3) .
O5 Eu1 O2 C4 171.1(3) .
O1 Eu1 O2 C4 27.8(3) .
O2 Eu1 O3 C7 -13.1(3) .
O6 Eu1 O3 C7 159.7(3) .
O7 Eu1 O3 C7 93.0(3) .
O8 Eu1 O3 C7 -128.9(3) 2_646
O4 Eu1 O3 C7 26.2(3) .
O5 Eu1 O3 C7 162.9(3) .
O1 Eu1 O3 C7 -56.0(3) .
O2 Eu1 O4 C9 123.1(3) .
O6 Eu1 O4 C9 173.9(3) .
O3 Eu1 O4 C9 -27.7(3) .
O7 Eu1 O4 C9 -133.2(3) .
O8 Eu1 O4 C9 30.7(4) 2_646
O5 Eu1 O4 C9 -91.1(3) .
O1 Eu1 O4 C9 48.6(3) .
O2 Eu1 O5 C12 4.1(4) .
O6 Eu1 O5 C12 7.7(3) .
O3 Eu1 O5 C12 -170.9(3) .
O7 Eu1 O5 C12 -70.0(3) .
O8 Eu1 O5 C12 94.8(3) 2_646
O4 Eu1 O5 C12 -112.0(3) .
O1 Eu1 O5 C12 131.1(3) .
O2 Eu1 O6 C14 162.0(3) .
O3 Eu1 O6 C14 -12.5(4) .
O7 Eu1 O6 C14 59.4(3) .
O8 Eu1 O6 C14 -86.0(3) 2_646
O4 Eu1 O6 C14 111.4(3) .
O5 Eu1 O6 C14 -15.7(3) .
O1 Eu1 O6 C14 -148.7(3) .
O2 Eu1 O7 N1 76.6(4) .
O6 Eu1 O7 N1 145.1(4) .
O3 Eu1 O7 N1 -58.7(4) .
O8 Eu1 O7 N1 -159.5(3) 2_646
O4 Eu1 O7 N1 8.9(4) .
O5 Eu1 O7 N1 -138.4(4) .
O1 Eu1 O7 N1 12.2(5) .
O18 Eu2 O11 C34 77.3(3) 2_546
O14 Eu2 O11 C34 178.7(3) .
O15 Eu2 O11 C34 3.3(4) .
O12 Eu2 O11 C34 0.3(3) .
O16 Eu2 O11 C34 -121.1(3) .
O17 Eu2 O11 C34 -86.7(3) .
O13 Eu2 O11 C34 122.3(3) .
O18 Eu2 O12 C32 -63.7(3) 2_546
O14 Eu2 O12 C32 9.4(5) .
O15 Eu2 O12 C32 -165.2(4) .
O16 Eu2 O12 C32 144.4(3) .
O17 Eu2 O12 C32 81.0(4) .
O13 Eu2 O12 C32 -115.3(3) .
O11 Eu2 O12 C32 13.0(3) .
O18 Eu2 O13 C42 118.4(3) 2_546
O14 Eu2 O13 C42 12.9(3) .
O15 Eu2 O13 C42 -139.9(3) .
O12 Eu2 O13 C42 170.4(3) .
O16 Eu2 O13 C42 -65.5(3) .
O17 Eu2 O13 C42 -43.5(4) .
O11 Eu2 O13 C42 73.1(3) .
O18 Eu2 O14 C44 -84.3(3) 2_546
O15 Eu2 O14 C44 21.0(3) .
O12 Eu2 O14 C44 -151.8(3) .
O16 Eu2 O14 C44 65.2(3) .
O17 Eu2 O14 C44 138.9(3) .
O13 Eu2 O14 C44 -16.8(3) .
O11 Eu2 O14 C44 -155.2(3) .
O18 Eu2 O15 C37 128.1(3) 2_546
O14 Eu2 O15 C37 21.5(4) .
O12 Eu2 O15 C37 -161.9(4) .
O16 Eu2 O15 C37 -23.9(3) .
O17 Eu2 O15 C37 -89.4(3) .
O13 Eu2 O15 C37 59.2(3) .
O11 Eu2 O15 C37 -164.9(3) .
O18 Eu2 O16 C39 -43.4(4) 2_546
O14 Eu2 O16 C39 -124.6(3) .
O15 Eu2 O16 C39 23.9(3) .
O12 Eu2 O16 C39 74.3(3) .
O17 Eu2 O16 C39 140.5(3) .
O13 Eu2 O16 C39 -50.6(3) .
O11 Eu2 O16 C39 173.0(3) .
O18 Eu2 O17 N3 -174.0(3) 2_546
O14 Eu2 O17 N3 -71.5(3) .
O15 Eu2 O17 N3 66.9(3) .
O12 Eu2 O17 N3 133.3(3) .
O16 Eu2 O17 N3 3.1(3) .
O13 Eu2 O17 N3 -19.3(4) .
O11 Eu2 O17 N3 -151.7(3) .
Eu1 O7 N1 C24 75.0(5) .
Eu1 O7 N1 C25 -113.0(4) .
Eu1 O8 N2 C24 75.4(4) 2_656
Eu1 O8 N2 C28 -114.3(3) 2_656
Eu2 O17 N3 C54 -77.2(4) .
Eu2 O17 N3 C55 110.6(4) .
Eu2 O18 N4 C54 -72.8(6) 2_556
Eu2 O18 N4 C58 115.4(5) 2_556
Eu1 O1 C2 C3 18.6(6) .
Eu1 O1 C2 C1 -162.6(2) .
F9 C1 C2 O1 162.7(4) .
F7 C1 C2 O1 40.2(5) .
F8 C1 C2 O1 -78.4(4) .
F9 C1 C2 C3 -18.5(5) .
F7 C1 C2 C3 -140.9(4) .
F8 C1 C2 C3 100.5(4) .
O1 C2 C3 C4 4.8(6) .
C1 C2 C3 C4 -173.9(3) .
Eu1 O2 C4 C3 -21.2(6) .
Eu1 O2 C4 C5 158.2(3) .
C2 C3 C4 O2 -4.0(7) .
C2 C3 C4 C5 176.6(4) .
O2 C4 C5 F11 170.5(4) .
C3 C4 C5 F11 -10.0(7) .
O2 C4 C5 F10 -68.8(5) .
C3 C4 C5 F10 110.7(5) .
O2 C4 C5 F12 46.3(5) .
C3 C4 C5 F12 -134.2(4) .
Eu1 O3 C7 C8 -21.0(6) .
Eu1 O3 C7 C6 155.1(2) .
F1 C6 C7 O3 29.4(5) .
F2 C6 C7 O3 -90.9(4) .
F3 C6 C7 O3 150.4(3) .
F1 C6 C7 C8 -154.0(3) .
F2 C6 C7 C8 85.7(4) .
F3 C6 C7 C8 -33.1(5) .
O3 C7 C8 C9 0.4(6) .
C6 C7 C8 C9 -175.6(3) .
Eu1 O4 C9 C8 23.9(6) .
Eu1 O4 C9 C10 -155.1(2) .
C7 C8 C9 O4 -2.2(6) .
C7 C8 C9 C10 176.8(3) .
O4 C9 C10 F6 -3.2(5) .
C8 C9 C10 F6 177.7(4) .
O4 C9 C10 F4 -129.0(4) .
C8 C9 C10 F4 51.8(5) .
O4 C9 C10 F5 115.3(4) .
C8 C9 C10 F5 -63.8(5) .
Eu1 O5 C12 C13 -0.7(6) .
Eu1 O5 C12 C11 -180.0(2) .
F15 C11 C12 O5 68.2(4) .
F13 C11 C12 O5 -171.0(3) .
F14 C11 C12 O5 -49.4(5) .
F15 C11 C12 C13 -111.1(4) .
F13 C11 C12 C13 9.7(5) .
F14 C11 C12 C13 131.2(4) .
O5 C12 C13 C14 -5.2(6) .
C11 C12 C13 C14 174.0(4) .
Eu1 O6 C14 C13 17.5(6) .
Eu1 O6 C14 C15 -160.7(2) .
C12 C13 C14 O6 -3.2(6) .
C12 C13 C14 C15 174.9(3) .
O6 C14 C15 F17 73.5(5) .
C13 C14 C15 F17 -104.9(5) .
O6 C14 C15 F18 -47.8(5) .
C13 C14 C15 F18 133.8(4) .
O6 C14 C15 F16 -166.7(3) .
C13 C14 C15 F16 14.9(5) .
C16 O9 C17 C18 0.4(6) .
C16 O9 C17 C19 -179.2(3) .
O9 C17 C18 C21 179.1(4) .
C19 C17 C18 C21 -1.3(6) .
O9 C17 C19 C20 -178.8(3) .
C18 C17 C19 C20 1.6(6) .
C17 C19 C20 C23 0.3(6) .
C22 O10 C21 C18 5.9(5) .
C22 O10 C21 C23 -176.4(3) .
C17 C18 C21 O10 176.7(4) .
C17 C18 C21 C23 -0.9(6) .
C19 C20 C23 C21 -2.5(5) .
C19 C20 C23 C24 177.1(3) .
O10 C21 C23 C20 -175.0(3) .
C18 C21 C23 C20 2.8(5) .
O10 C21 C23 C24 5.4(5) .
C18 C21 C23 C24 -176.8(3) .
O7 N1 C24 N2 173.7(3) .
C25 N1 C24 N2 1.3(4) .
O7 N1 C24 C23 -8.0(6) .
C25 N1 C24 C23 179.6(3) .
O8 N2 C24 N1 -174.2(3) .
C28 N2 C24 N1 14.8(4) .
O8 N2 C24 C23 7.4(5) .
C28 N2 C24 C23 -163.6(3) .
C20 C23 C24 N1 56.3(5) .
C21 C23 C24 N1 -124.1(4) .
C20 C23 C24 N2 -125.6(4) .
C21 C23 C24 N2 54.0(5) .
O7 N1 C25 C26 52.3(4) .
C24 N1 C25 C26 -135.0(3) .
O7 N1 C25 C27 -68.2(4) .
C24 N1 C25 C27 104.6(3) .
O7 N1 C25 C28 172.3(3) .
C24 N1 C25 C28 -15.0(4) .
O8 N2 C28 C30 44.4(5) .
C24 N2 C28 C30 -144.3(3) .
O8 N2 C28 C29 -75.6(4) .
C24 N2 C28 C29 95.7(4) .
O8 N2 C28 C25 165.5(3) .
C24 N2 C28 C25 -23.2(4) .
N1 C25 C28 N2 20.6(3) .
C26 C25 C28 N2 136.5(3) .
C27 C25 C28 N2 -94.2(4) .
N1 C25 C28 C30 137.7(4) .
C26 C25 C28 C30 -106.4(4) .
C27 C25 C28 C30 22.9(5) .
N1 C25 C28 C29 -91.5(4) .
C26 C25 C28 C29 24.4(5) .
C27 C25 C28 C29 153.7(4) .
Eu2 O12 C32 C33 -19.3(7) .
Eu2 O12 C32 C31 160.8(3) .
F19 C31 C32 O12 -24.5(6) .
F21 C31 C32 O12 99.8(5) .
F20 C31 C32 O12 -141.8(4) .
F19 C31 C32 C33 155.5(5) .
F21 C31 C32 C33 -80.2(5) .
F20 C31 C32 C33 38.3(6) .
O12 C32 C33 C34 7.3(7) .
C31 C32 C33 C34 -172.7(4) .
Eu2 O11 C34 C33 -8.5(6) .
Eu2 O11 C34 C35 172.1(2) .
C32 C33 C34 O11 6.8(7) .
C32 C33 C34 C35 -173.8(4) .
O11 C34 C35 F22 170.0(3) .
C33 C34 C35 F22 -9.4(5) .
O11 C34 C35 F24 -68.1(4) .
C33 C34 C35 F24 112.5(4) .
O11 C34 C35 F23 49.3(5) .
C33 C34 C35 F23 -130.2(4) .
Eu2 O15 C37 C38 16.8(6) .
Eu2 O15 C37 C36 -162.7(3) .
F25 C36 C37 O15 73.6(5) .
F27 C36 C37 O15 -162.7(4) .
F26 C36 C37 O15 -42.7(5) .
F25 C36 C37 C38 -106.0(5) .
F27 C36 C37 C38 17.7(6) .
F26 C36 C37 C38 137.7(4) .
O15 C37 C38 C39 5.0(6) .
C36 C37 C38 C39 -175.5(4) .
Eu2 O16 C39 C38 -17.3(6) .
Eu2 O16 C39 C40 165.4(2) .
C37 C38 C39 O16 -4.4(6) .
C37 C38 C39 C40 172.8(3) .
O16 C39 C40 F30 -40.7(5) .
C38 C39 C40 F30 141.8(4) .
O16 C39 C40 F28 -162.2(3) .
C38 C39 C40 F28 20.2(5) .
O16 C39 C40 F29 78.9(4) .
C38 C39 C40 F29 -98.7(4) .
Eu2 O13 C42 C43 -9.9(6) .
Eu2 O13 C42 C41 167.3(2) .
F32 C41 C42 O13 49.3(5) .
F33 C41 C42 O13 -70.7(4) .
F31 C41 C42 O13 169.7(3) .
F32 C41 C42 C43 -133.2(4) .
F33 C41 C42 C43 106.8(4) .
F31 C41 C42 C43 -12.9(5) .
O13 C42 C43 C44 1.9(6) .
C41 C42 C43 C44 -175.2(3) .
Eu2 O14 C44 C43 18.3(5) .
Eu2 O14 C44 C45 -157.0(2) .
C42 C43 C44 O14 -6.0(6) .
C42 C43 C44 C45 169.2(3) .
O14 C44 C45 F36 -34.3(4) .
C43 C44 C45 F36 149.9(3) .
O14 C44 C45 F35 85.1(4) .
C43 C44 C45 F35 -90.8(4) .
O14 C44 C45 F34 -157.6(3) .
C43 C44 C45 F34 26.6(5) .
C46 O19 C47 C48 -3.2(6) .
C46 O19 C47 C49 177.0(3) .
O19 C47 C48 C51 -179.5(4) .
C49 C47 C48 C51 0.3(6) .
O19 C47 C49 C50 179.4(3) .
C48 C47 C49 C50 -0.4(6) .
C47 C49 C50 C53 -1.6(6) .
C52 O20 C51 C48 -4.0(6) .
C52 O20 C51 C53 177.8(3) .
C47 C48 C51 O20 -176.3(3) .
C47 C48 C51 C53 1.9(6) .
C49 C50 C53 C51 3.6(5) .
C49 C50 C53 C54 -175.5(3) .
O20 C51 C53 C50 174.5(3) .
C48 C51 C53 C50 -3.8(5) .
O20 C51 C53 C54 -6.3(5) .
C48 C51 C53 C54 175.4(3) .
O18 N4 C54 N3 -172.2(3) .
C58 N4 C54 N3 0.1(4) .
O18 N4 C54 C53 9.8(6) .
C58 N4 C54 C53 -177.9(3) .
O17 N3 C54 N4 174.5(3) .
C55 N3 C54 N4 -12.7(4) .
O17 N3 C54 C53 -7.5(5) .
C55 N3 C54 C53 165.4(3) .
C50 C53 C54 N4 -59.9(5) .
C51 C53 C54 N4 120.9(4) .
C50 C53 C54 N3 122.4(4) .
C51 C53 C54 N3 -56.7(5) .
O17 N3 C55 C56 -46.0(5) .
C54 N3 C55 C56 141.0(3) .
O17 N3 C55 C57 72.2(4) .
C54 N3 C55 C57 -100.8(3) .
O17 N3 C55 C58 -168.0(3) .
C54 N3 C55 C58 19.0(4) .
O18 N4 C58 C60 -54.6(4) .
C54 N4 C58 C60 132.7(3) .
O18 N4 C58 C59 64.6(4) .
C54 N4 C58 C59 -108.1(4) .
O18 N4 C58 C55 -176.0(3) .
C54 N4 C58 C55 11.3(4) .
N3 C55 C58 N4 -16.5(3) .
C56 C55 C58 N4 -133.7(3) .
C57 C55 C58 N4 96.0(4) .
N3 C55 C58 C60 -132.8(3) .
C56 C55 C58 C60 110.0(4) .
C57 C55 C58 C60 -20.4(5) .
N3 C55 C58 C59 97.8(4) .
C56 C55 C58 C59 -19.4(5) .
C57 C55 C58 C59 -149.7(4) .
