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Information card for entry 7035419
Preview
| Coordinates | 7035419.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | 3,3-dichloro-2,4,6,7-tetrakis(trimethylsilyl)-2,4,6,7-tetraaza-1,5-diphospha-3-silabicyclo[3.1.1]heptane |
|---|---|
| Chemical name | 3,3-dichloro-2,4,6,7-tetrakis(trimethylsilyl)-2,4,6,7-tetraaza-1,5-diphospha-3-silabicyclo[3.1.1]heptane |
| Formula | C12 H36 Cl2 N4 P2 Si5 |
| Calculated formula | C12 H36 Cl2 N4 P2 Si5 |
| Title of publication | Formation of the spirocyclic, Si-centered cage cations [ClP(NSiMe3)2Si(NSiMe3)2P5](+) and [P5(NSiMe3)2Si(NSiMe3)2P5](2.). |
| Authors of publication | Holthausen, M. H.; Weigand, J. J. |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2016 |
| Journal volume | 45 |
| Journal issue | 5 |
| Pages of publication | 1953 - 1961 |
| a | 10.418 ± 0.0003 Å |
| b | 10.3333 ± 0.0003 Å |
| c | 12.9878 ± 0.0004 Å |
| α | 90° |
| β | 90.739 ± 0.001° |
| γ | 90° |
| Cell volume | 1398.05 ± 0.07 Å3 |
| Cell temperature | 153 ± 2 K |
| Ambient diffraction temperature | 153 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 4 |
| Hermann-Mauguin space group symbol | P 1 21 1 |
| Hall space group symbol | P 2yb |
| Residual factor for all reflections | 0.0279 |
| Residual factor for significantly intense reflections | 0.0267 |
| Weighted residual factors for significantly intense reflections | 0.0677 |
| Weighted residual factors for all reflections included in the refinement | 0.0687 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.072 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 176428 (current) | 2016-02-13 | Replaced deprecated COD CIF data names with their more modern alternatives. The _cod_cif_authors_sg_Hall and _cod_cif_authors_sg_H-M data items were renamed to _cod_original_sg_symbol_Hall and _cod_cif_authors_sg_H-M respectively. |
7035419.cif |
| 176093 | 2016-02-05 | cif/ Updating files of 7035419, 7035420, 7035421, 7035422 Original log message: Adding full bibliography for 7035419--7035422.cif. |
7035419.cif |
| 139245 | 2015-06-16 | cif/ Adding structures of 7035419, 7035420, 7035421, 7035422 via cif-deposit CGI script. |
7035419.cif |
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