Crystallography Open Database

Information card for entry 7037593

Preview

Coordinates	7037593.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	[Eu(p-HC6F4NC2H4NEt2)2(dme)]
Chemical name	[Eu(p-HC6F4NC2H4NEt2)2(dme)]
Formula	C28 H40 Eu F8 N4 O2
Calculated formula	C28 H40 Eu F8 N4 O2
SMILES	[Eu]12345([F]c6c(N1CC[N]3(CC)CC)c(F)c(F)cc6F)([O](CC[O]2C)C)N(CC[N]4(CC)CC)c1c([F]5)c(F)cc(F)c1F
Title of publication	Exploring the effect of the Ln(III)/Ln(II) redox potential on C-F activation and on oxidation of some lanthanoid organoamides.
Authors of publication	Deacon, Glen B.; Junk, Peter C.; Kelly, Rory P.; Wang, Jun
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2016
Journal volume	45
Journal issue	4
Pages of publication	1422 - 1435
a	12.435 ± 0.003 Å
b	18.083 ± 0.004 Å
c	13.998 ± 0.003 Å
α	90°
β	90.39 ± 0.03°
γ	90°
Cell volume	3147.5 ± 1.2 Å³
Cell temperature	123 ± 1 K
Ambient diffraction temperature	123 ± 1 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.0408
Residual factor for significantly intense reflections	0.0325
Weighted residual factors for significantly intense reflections	0.0903
Weighted residual factors for all reflections included in the refinement	0.0989
Goodness-of-fit parameter for all reflections included in the refinement	1.034
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176013 (current)	2016-02-05	cif/ Updating files of 7037593, 7037594, 7037595, 7037596, 7037597, 7037598, 7037599, 7037600, 7037601, 7037602, 7037603 Original log message: Adding full bibliography for 7037593--7037603.cif.	7037593.cif
170898	2015-12-09	cif/ Adding structures of 7037593, 7037594, 7037595, 7037596, 7037597, 7037598, 7037599, 7037600, 7037601, 7037602, 7037603 via cif-deposit CGI script.	7037593.cif