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Information card for entry 7042576
Preview
| Coordinates | 7042576.cif |
|---|---|
| Original paper (by DOI) | HTML |
| External links | PubChem |
| Common name | AG125 |
|---|---|
| Formula | C74 H78 Ag2 B2 F8 N2 O5 P4 |
| Calculated formula | C74 H78 Ag2 B2 F8 N2 O5 P4 |
| SMILES | [Ag]([P](c1ccccc1)(c1ccccc1)N([P]([Ag]1[O]2CCCC2)(c2ccccc2)c2ccccc2)c2ccc(cc2)OC)[P](c2ccccc2)(c2ccccc2)N([P]1(c1ccccc1)c1ccccc1)c1ccc(cc1)OC.[B](F)(F)(F)[F-].[B](F)(F)(F)[F-].C1CCOC1.C1OCCC1 |
| Title of publication | Mono- and polynuclear Ag(i) complexes of N-functionalized bis(diphenylphosphino)amine DPPA-type ligands: synthesis, solid-state structures and reactivity. |
| Authors of publication | Ghisolfi, Alessio; Fliedel, Christophe; de Frémont, Pierre; Braunstein, Pierre |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2017 |
| Journal volume | 46 |
| Journal issue | 17 |
| Pages of publication | 5571 - 5586 |
| a | 11.2883 ± 0.0002 Å |
| b | 23.0676 ± 0.0004 Å |
| c | 27.7279 ± 0.0003 Å |
| α | 90° |
| β | 101.891 ± 0.001° |
| γ | 90° |
| Cell volume | 7065.23 ± 0.19 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 8 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.1013 |
| Residual factor for significantly intense reflections | 0.0621 |
| Weighted residual factors for significantly intense reflections | 0.1233 |
| Weighted residual factors for all reflections included in the refinement | 0.1352 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.023 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301850 (current) | 2025-08-21 | Add cross-references to PubChem compounds in COD range 7/04/ Each referenced PubChem compound corresponds to the full crystal structure. |
7042576.cif |
| 196408 | 2017-05-06 | cif/ Updating files of 7042575, 7042576, 7042577, 7042578, 7042579, 7042580, 7042581 Original log message: Adding full bibliography for 7042575--7042581.cif. |
7042576.cif |
| 194441 | 2017-03-23 | cif/ Adding structures of 7042575, 7042576, 7042577, 7042578, 7042579, 7042580, 7042581 via cif-deposit CGI script. |
7042576.cif |
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