Crystallography Open Database

Information card for entry 7044763

Preview

Coordinates	7044763.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C62 H99 Cl Li N6 O8 Si4 Sm
Calculated formula	C62 H99 Cl Li N6 O8 Si4 Sm
Title of publication	Rare-earth metal-mediated PhC[triple bond, length as m-dash]N insertion into N,N-bis(trimethylsilyl)naphthalene-1,8-diamido dianion - a synthetic approach to complexes coordinated by ansa-bridged amido-amidinato ligand.
Authors of publication	Lyubov, Dmitry M.; Cherkasov, Anton V.; Fukin, Georgy K.; Lyssenko, Konstantin A.; Rychagova, Elena A.; Ketkov, Sergey Yu; Trifonov, Alexander A.
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2018
Journal volume	47
Journal issue	2
Pages of publication	438 - 451
a	12.4061 ± 0.0004 Å
b	27.5182 ± 0.0009 Å
c	20.9997 ± 0.0007 Å
α	90°
β	95.374 ± 0.001°
γ	90°
Cell volume	7137.7 ± 0.4 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	8
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0835
Residual factor for significantly intense reflections	0.0617
Weighted residual factors for significantly intense reflections	0.1626
Weighted residual factors for all reflections included in the refinement	0.1798
Goodness-of-fit parameter for all reflections included in the refinement	1.045
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
229571 (current)	2019-11-17	cif/ Updating files of 7044761, 7044762, 7044763, 7044764, 7044765, 7044766, 7044767 Original log message: Adding full bibliography for 7044761--7044767.cif.	7044763.cif
203207	2017-11-15	cif/ Adding structures of 7044761, 7044762, 7044763, 7044764, 7044765, 7044766, 7044767 via cif-deposit CGI script.	7044763.cif