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Information card for entry 7044766
Preview
| Coordinates | 7044766.cif |
|---|---|
| Original paper (by DOI) | HTML |
| External links | PubChem |
| Formula | C66 H100 Li N6 O5 Si4 Y |
|---|---|
| Calculated formula | C66 H100 Li N6 O5 Si4 Y |
| SMILES | [Y]123(OC(C)(C)C)([N]([Si](C)(C)C)=C(N1c1c4c(N3[Si](C)(C)C)cccc4ccc1)c1ccccc1)[N]([Si](C)(C)C)=C(N2c1c2c(N[Si](C)(C)C)cccc2ccc1)c1ccccc1.[O]1(CCCC1)[Li]([O]1CCCC1)([O]1CCCC1)[O]1CCCC1 |
| Title of publication | Rare-earth metal-mediated PhC[triple bond, length as m-dash]N insertion into N,N-bis(trimethylsilyl)naphthalene-1,8-diamido dianion - a synthetic approach to complexes coordinated by ansa-bridged amido-amidinato ligand. |
| Authors of publication | Lyubov, Dmitry M.; Cherkasov, Anton V.; Fukin, Georgy K.; Lyssenko, Konstantin A.; Rychagova, Elena A.; Ketkov, Sergey Yu; Trifonov, Alexander A. |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2018 |
| Journal volume | 47 |
| Journal issue | 2 |
| Pages of publication | 438 - 451 |
| a | 13.9163 ± 0.0011 Å |
| b | 14.9401 ± 0.0013 Å |
| c | 34.281 ± 0.003 Å |
| α | 90° |
| β | 97.727 ± 0.002° |
| γ | 90° |
| Cell volume | 7062.7 ± 1 Å3 |
| Cell temperature | 150 ± 2 K |
| Ambient diffraction temperature | 150 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.1715 |
| Residual factor for significantly intense reflections | 0.071 |
| Weighted residual factors for significantly intense reflections | 0.1381 |
| Weighted residual factors for all reflections included in the refinement | 0.1746 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.953 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301850 (current) | 2025-08-21 | Add cross-references to PubChem compounds in COD range 7/04/ Each referenced PubChem compound corresponds to the full crystal structure. |
7044766.cif |
| 229571 | 2019-11-17 | cif/ Updating files of 7044761, 7044762, 7044763, 7044764, 7044765, 7044766, 7044767 Original log message: Adding full bibliography for 7044761--7044767.cif. |
7044766.cif |
| 203207 | 2017-11-15 | cif/ Adding structures of 7044761, 7044762, 7044763, 7044764, 7044765, 7044766, 7044767 via cif-deposit CGI script. |
7044766.cif |
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