Crystallography Open Database

Information card for entry 7049121

Preview

Coordinates	7049121.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C78 H110 F24 N14 O3 P6 Rh2
Calculated formula	C78 H110 F24 N14 O3 P6 Rh2
Title of publication	Unbridged Rh(ii)-Rh(ii) complexes of N-heterocyclic carbenes and reactions with O<sub>2</sub> to form dirhodium(μ-η<sup>1</sup>:η<sup>1</sup>-O<sub>2</sub>) complexes.
Authors of publication	Yi, Xiaofei; Liu, Bin; Chen, Kai; Chen, Wei; Chen, Wanzhi
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2019
Journal volume	48
Journal issue	12
Pages of publication	3835 - 3839
a	13.1037 ± 0.0015 Å
b	14.8822 ± 0.0017 Å
c	15.3583 ± 0.0011 Å
α	104.336 ± 0.008°
β	111.184 ± 0.009°
γ	106.435 ± 0.01°
Cell volume	2465.1 ± 0.6 Å³
Cell temperature	293 ± 2 K
Ambient diffraction temperature	293 ± 2 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0659
Residual factor for significantly intense reflections	0.0512
Weighted residual factors for significantly intense reflections	0.1314
Weighted residual factors for all reflections included in the refinement	0.1456
Goodness-of-fit parameter for all reflections included in the refinement	1.056
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
224568 (current)	2019-11-08	cif/ Updating files of 7049117, 7049118, 7049119, 7049120, 7049121 Original log message: Adding full bibliography for 7049117--7049121.cif.	7049121.cif
213780	2019-02-22	cif/ Adding structures of 7049117, 7049118, 7049119, 7049120, 7049121 via cif-deposit CGI script.	7049121.cif