Crystallography Open Database

Information card for entry 7049153

Preview

Coordinates	7049153.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C22 H39 Cl Ir N O Si
Calculated formula	C22 H39 Cl Ir N O Si
Title of publication	Selective reduction of formamides to O-silylated hemiaminals or methylamines with HSiMe<sub>2</sub>Ph catalyzed by iridium complexes.
Authors of publication	Guzmán, Jefferson; Bernal, Ana M.; García-Orduña, Pilar; Lahoz, Fernando J.; Oro, Luis A.; Fernández-Alvarez, Francisco J
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2019
Journal volume	48
Journal issue	13
Pages of publication	4255 - 4262
a	8.8806 ± 0.0004 Å
b	10.5584 ± 0.0004 Å
c	12.7712 ± 0.0005 Å
α	94.479 ± 0.001°
β	91.398 ± 0.001°
γ	94.67 ± 0.001°
Cell volume	1189.3 ± 0.08 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0182
Residual factor for significantly intense reflections	0.0172
Weighted residual factors for significantly intense reflections	0.0398
Weighted residual factors for all reflections included in the refinement	0.0404
Goodness-of-fit parameter for all reflections included in the refinement	1.101
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
224273 (current)	2019-11-08	cif/ Updating files of 7049153 Original log message: Adding full bibliography for 7049153.cif.	7049153.cif
213864	2019-02-27	cif/ Adding structures of 7049153 via cif-deposit CGI script.	7049153.cif