Crystallography Open Database

Information card for entry 7063350

Preview

Coordinates	7063350.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C33 H33 Cl2 F9 N3 O Si V
Calculated formula	C33 H33 Cl2 F9 N3 O Si V
Title of publication	Vanadium(v) arylimido alkylidene N-heterocyclic carbene complexes containing fluorinated alkoxide or halogenated phenoxide ligands for the syndiospecific ROMP of cyclic olefins
Authors of publication	Nomura, Kotohiro; Kuwahara, Shuko; Suthala, Jirapa; Kawamoto, Yuta; Shimoyama, Daisuke; Buchmeiser, Michael R.
Journal of publication	New Journal of Chemistry
Year of publication	2024
Journal volume	48
Journal issue	34
Pages of publication	14865 - 14872
a	15.1196 ± 0.0005 Å
b	16.0398 ± 0.0005 Å
c	15.517 ± 0.0005 Å
α	90°
β	102.341 ± 0.003°
γ	90°
Cell volume	3676.2 ± 0.2 Å³
Cell temperature	93 ± 2 K
Ambient diffraction temperature	93 ± 2 K
Number of distinct elements	8
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.1007
Residual factor for significantly intense reflections	0.0818
Weighted residual factors for significantly intense reflections	0.2132
Weighted residual factors for all reflections included in the refinement	0.2234
Goodness-of-fit parameter for all reflections included in the refinement	1.12
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
294617 (current)	2024-09-06	cif/ Updating files of 7063350, 7063351 Original log message: Adding full bibliography for 7063350--7063351.cif.	7063350.cif
293400	2024-07-13	cif/ Adding structures of 7063350, 7063351 via cif-deposit CGI script.	7063350.cif