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Information card for entry 7103785
Preview
| Coordinates | 7103785.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C46 H64 N3 O3 Si2 Y |
|---|---|
| Calculated formula | C46 H64 N3 O3 Si2 Y |
| SMILES | [Y]123(N([SiH](C)C)[SiH](C)C)(Oc4c(ccc(c4C=[N]2c2cccc(c2c2c(cccc2[N]3=Cc2c(ccc(c2O1)C(C)(C)C)C)C)C)C)C(C)(C)C)[O]1CCCC1 |
| Title of publication | Chiral-at-metal organolanthanides: enantioselective aminoalkene hydroamination/cyclisation with non-cyclopentadienyls |
| Authors of publication | Peter Scott; Kevin M. Gillespie; Paul D. Knight; Colin Morton; O.Paul N |
| Journal of publication | Chemical communications (Cambridge, England) |
| Year of publication | 2003 |
| a | 15.92 ± 0.02 Å |
| b | 17.51 ± 0.03 Å |
| c | 16.8 ± 0.02 Å |
| α | 90° |
| β | 95.16 ± 0.13° |
| γ | 90° |
| Cell volume | 4666 ± 12 Å3 |
| Cell temperature | 180 ± 2 K |
| Ambient diffraction temperature | 180 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/a 1 |
| Hall space group symbol | -P 2yab |
| Residual factor for all reflections | 0.3134 |
| Residual factor for significantly intense reflections | 0.1607 |
| Weighted residual factors for significantly intense reflections | 0.3003 |
| Weighted residual factors for all reflections included in the refinement | 0.3725 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.009 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 213973 (current) | 2019-03-05 | cod/ Removed potentially copyrighted or irrelevant data items from 1289 entries. |
7103785.cif |
| 180140 | 2016-03-26 | cif/7/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/10/37. |
7103785.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7103785.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7103785.cif |
| 966 | 2010-01-30 | cif/ Adding _cod_database_code tags to all COD entries. Adding tag description to the cif_cod.dic dictionary so that COD entries can be validated. |
7103785.cif |
| 919 | 2009-12-07 | cif/7/ Fixing values that started with a square bracket ("[") in 36 series 7 files (enclosing such values in single quotes). |
7103785.cif |
| 823 | 2009-09-25 | cif/ Depositing information from the Chem-Comm-2003_01-17 and J-Org-Chem-2007_13-20 publications. |
7103785.cif |
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