Crystallography Open Database

Information card for entry 7106723

Preview

Coordinates	7106723.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	H54 K14 Mo12 O102 Te2 V12
Calculated formula	K7.3 Mo12 O88.8 Te2 V12
Title of publication	Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32-: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}
Authors of publication	Leroy Cronin; Neus Corella Ochoa; Haralampos Miras; Alastair Kidd; De-Liang Long
Journal of publication	Chem.Commun.
Year of publication	2011
Journal volume	47
Pages of publication	8799
a	23.2791 ± 0.0007 Å
b	13.3972 ± 0.0004 Å
c	29.3216 ± 0.0008 Å
α	90°
β	93.479 ± 0.002°
γ	90°
Cell volume	9127.8 ± 0.5 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	6
Space group number	12
Hermann-Mauguin space group symbol	C 1 2/m 1
Hall space group symbol	-C 2y
Residual factor for all reflections	0.1186
Residual factor for significantly intense reflections	0.0859
Weighted residual factors for significantly intense reflections	0.225
Weighted residual factors for all reflections included in the refinement	0.254
Goodness-of-fit parameter for all reflections included in the refinement	1.055
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
180171 (current)	2016-03-26	cif/7/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/10/67.	7106723.cif
130086	2015-01-23	cod/ (robertas@burundukas) The 'cif_fix_values' program was applied to CIFs that have generated the validation messages containing tag '_exptl_crystal_density_meas'. 16946 CIFs had a values that were perceived as 'not measured' and they were changed to '?'. The total of 17089 CIFs was changed. Those that were not corrected by 'cif_fix_values' were reformatted by the parser (e.g. a doi tag was moved to another place). The processing command was: mysql -u cod_reader -h www.crystallography.net cod -e \ 'select distinct codid from validation \ where message like \ "%tag%_exptl_crystal_density_meas'\''%"' -NB \ \| xargs -i sh -c 'cif_fix_values {} \ \| cif_filter --add-cif-header {} \ \| sponge {}'	7106723.cif
120112	2014-07-12	Adding DOIs to range 7 structures.	7106723.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7106723.cif
24494	2011-08-25	../uploads/cif-deposit/cod/cif Adding structures of 7106722, 7106723, 7106724 via cif-deposit CGI script.	7106723.cif