Crystallography Open Database

Information card for entry 7117028

Preview

Coordinates	7117028.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	(PPh4)[Ge(N3)3]
Chemical name	(PPh4)[Ge(N3)3]
Formula	C24 H20 Ge N9 P
Calculated formula	C24 H20 Ge N9 P
SMILES	[Ge](N=N#N)(N=N#N)N=N#N.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
Title of publication	Homoleptic low-valent polyazides of group 14 elements
Authors of publication	Benjamin Peerless; Theo Keane; Anthony J. H. M. Meijer; Peter Portius
Journal of publication	Chem.Commun.
Year of publication	2015
Journal volume	51
Pages of publication	7435
a	7.7712 ± 0.0002 Å
b	11.4711 ± 0.0004 Å
c	14.2003 ± 0.0004 Å
α	93.278 ± 0.002°
β	99.357 ± 0.002°
γ	100.865 ± 0.002°
Cell volume	1221.59 ± 0.06 Å³
Cell temperature	120 ± 2 K
Ambient diffraction temperature	120 ± 2 K
Number of distinct elements	5
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0645
Residual factor for significantly intense reflections	0.0376
Weighted residual factors for significantly intense reflections	0.0731
Weighted residual factors for all reflections included in the refinement	0.0807
Goodness-of-fit parameter for all reflections included in the refinement	1.09
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
180284 (current)	2016-03-26	cif/7/11/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/11/70.	7117028.cif
135315	2015-04-17	cif/ Adding structures of 7117027, 7117028 via cif-deposit CGI script.	7117028.cif