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Information card for entry 7118472
Preview
| Coordinates | 7118472.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C30 H25 F9 N O9 P2 S3 Sb |
|---|---|
| Calculated formula | C30 H25 F9 N O9 P2 S3 Sb |
| SMILES | [Sb]1([P](C[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(OS(=O)(=O)C(F)(F)F)(OS(=O)(=O)C(F)(F)F)OS(=O)(=O)C(F)(F)F.N#CC |
| Title of publication | Distinction between coordination and phosphine ligand oxidation: interactions of di- and triphosphines with Pn^3+^ (Pn = P, As, Sb, Bi) |
| Authors of publication | Chitnis, Saurabh S.; Vos, Kevin A.; Burford, Neil; McDonald, Robert; Ferguson, Michael J. |
| Journal of publication | Chemical Communications (Cambridge, United Kingdom) |
| Year of publication | 2016 |
| Journal volume | 52 |
| Pages of publication | 685 - 688 |
| a | 9.1263 ± 0.0005 Å |
| b | 19.3196 ± 0.001 Å |
| c | 21.6426 ± 0.0011 Å |
| α | 90° |
| β | 99.3749 ± 0.0006° |
| γ | 90° |
| Cell volume | 3765 ± 0.3 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 8 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0282 |
| Residual factor for significantly intense reflections | 0.0233 |
| Weighted residual factors for significantly intense reflections | 0.0543 |
| Weighted residual factors for all reflections included in the refinement | 0.0568 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.034 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Duplicate of | 7118192 |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 209786 (current) | 2018-08-16 | cif/7/11/ Updating bibliography in entries 7118191-7118193, 7118471-7118473. Marking entries 7118471-7118473 as duplicates of entries 7118191-7118193. |
7118472.cif |
| 176428 | 2016-02-13 | Replaced deprecated COD CIF data names with their more modern alternatives. The _cod_cif_authors_sg_Hall and _cod_cif_authors_sg_H-M data items were renamed to _cod_original_sg_symbol_Hall and _cod_cif_authors_sg_H-M respectively. |
7118472.cif |
| 174538 | 2016-01-18 | cif/ Adding structures of 7118471, 7118472, 7118473 via cif-deposit CGI script. |
7118472.cif |
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Users of the data should acknowledge the original authors of the
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