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#$Date: 2016-07-01 15:04:40 +0300 (Fri, 01 Jul 2016) $
#$Revision: 184118 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/90/7119089.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7119089
loop_
_publ_author_name
'Long Huang'
'Frank Rominger'
'Matthias Rudolph'
'A. Stephen K. Hashmi'
_publ_section_title
;
 A general access to organogold(III) complexes by oxidative addition of
 diazonium salts
;
_journal_name_full               Chem.Commun.
_journal_page_first              6435
_journal_volume                  52
_journal_year                    2016
_chemical_formula_sum            'C27 H20 Au B Cl2 F4 N P'
_chemical_formula_weight         744.09
_chemical_name_common            '5d in manuscript'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-03-11 deposited with the CCDC.
2016-04-05 downloaded from the CCDC.
;
_cell_angle_alpha                86.4666(8)
_cell_angle_beta                 70.5144(7)
_cell_angle_gamma                67.9291(7)
_cell_formula_units_Z            2
_cell_length_a                   9.35580(10)
_cell_length_b                   11.4552(2)
_cell_length_c                   13.9422(2)
_cell_measurement_reflns_used    9950
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      29.96
_cell_measurement_theta_min      2.38
_cell_volume                     1301.94(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II Quazar area detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0403
_diffrn_reflns_av_unetI/netI     0.0345
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            34799
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.095
_diffrn_reflns_theta_min         1.553
_diffrn_source                   'ImuS microsource'
_exptl_absorpt_coefficient_mu    5.964
_exptl_absorpt_correction_T_max  0.8762
_exptl_absorpt_correction_T_min  0.7088
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Sheldrick, G. M. (2008). SADABS. University of Göttingen, Germany.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.898
_exptl_crystal_description       plate
_exptl_crystal_F_000             716
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.020
_refine_diff_density_max         0.757
_refine_diff_density_min         -0.701
_refine_diff_density_rms         0.101
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     339
_refine_ls_number_reflns         7654
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0297
_refine_ls_R_factor_gt           0.0246
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0239P)²+0.1662P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0515
_refine_ls_wR_factor_ref         0.0529
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6838
_reflns_number_total             7654
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6cc02199a2.cif
_cod_data_source_block           lh5
_cod_database_code               7119089
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.587
_shelx_estimated_absorpt_t_max   0.890
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.46996(2) 0.37052(2) 0.61524(2) 0.02359(4) Uani 0.9930(5) 1 d . . P A 1
Cl1 Cl 0.70739(8) 0.40802(7) 0.52771(5) 0.03330(15) Uani 1 1 d . . . A 1
P1 P 0.23748(8) 0.33393(6) 0.69622(5) 0.02260(13) Uani 1 1 d . . . A 1
C11 C 0.2323(3) 0.2489(2) 0.59397(19) 0.0258(5) Uani 1 1 d . . . A 1
C12 C 0.0985(4) 0.2213(3) 0.5984(2) 0.0329(6) Uani 1 1 d . . . A 1
H12 H -0.0003 0.2551 0.6545 0.040 Uiso 1 1 calc R U . A 1
C13 C 0.1073(4) 0.1444(3) 0.5210(2) 0.0389(7) Uani 1 1 d . . . A 1
H13 H 0.0140 0.1273 0.5243 0.047 Uiso 1 1 calc R U . A 1
C14 C 0.2490(4) 0.0936(3) 0.4408(2) 0.0367(7) Uani 1 1 d . . . A 1
H14 H 0.2546 0.0391 0.3898 0.044 Uiso 1 1 calc R U . A 1
C15 C 0.3872(4) 0.1207(2) 0.4326(2) 0.0287(6) Uani 1 1 d . . . A 1
C16 C 0.5364(4) 0.0717(3) 0.3499(2) 0.0337(6) Uani 1 1 d . . . A 1
H16 H 0.5459 0.0187 0.2964 0.040 Uiso 1 1 calc R U . A 1
C17 C 0.6655(4) 0.1007(3) 0.3472(2) 0.0357(7) Uani 1 1 d . . . A 1
H17 H 0.7669 0.0661 0.2932 0.043 Uiso 1 1 calc R U . A 1
C18 C 0.6476(3) 0.1820(3) 0.4251(2) 0.0310(6) Uani 1 1 d . . . A 1
H18 H 0.7389 0.2015 0.4226 0.037 Uiso 1 1 calc R U . A 1
N19 N 0.5090(3) 0.2329(2) 0.50191(16) 0.0247(4) Uani 1 1 d . . . A 1
C20 C 0.3780(3) 0.2006(2) 0.50931(19) 0.0236(5) Uani 1 1 d . . . A 1
C21 C 0.0489(3) 0.4677(3) 0.7418(2) 0.0343(6) Uani 1 1 d . . . A 1
C22 C -0.0261(4) 0.5329(4) 0.6740(3) 0.0624(11) Uani 1 1 d . . . A 1
H22 H 0.0170 0.5043 0.6039 0.075 Uiso 1 1 calc R U . A 1
C23 C -0.1658(5) 0.6414(4) 0.7106(5) 0.098(2) Uani 1 1 d . . . A 1
H23 H -0.2186 0.6869 0.6646 0.118 Uiso 1 1 calc R U . A 1
C24 C -0.2289(6) 0.6842(4) 0.8102(6) 0.100(2) Uani 1 1 d . . . A 1
H24 H -0.3238 0.7594 0.8333 0.120 Uiso 1 1 calc R U . A 1
C25 C -0.1554(5) 0.6188(4) 0.8771(4) 0.0863(17) Uani 1 1 d . . . A 1
H25 H -0.2005 0.6482 0.9471 0.104 Uiso 1 1 calc R U . A 1
C26 C -0.0150(4) 0.5094(3) 0.8439(3) 0.0555(10) Uani 1 1 d . . . A 1
H26 H 0.0361 0.4642 0.8907 0.067 Uiso 1 1 calc R U . A 1
C31 C 0.2511(3) 0.2346(2) 0.80011(19) 0.0250(5) Uani 1 1 d . . . A 1
C32 C 0.1241(4) 0.1936(3) 0.8475(2) 0.0379(7) Uani 1 1 d . . . A 1
H32 H 0.0326 0.2174 0.8247 0.045 Uiso 1 1 calc R U . A 1
C33 C 0.1318(4) 0.1175(3) 0.9284(2) 0.0441(8) Uani 1 1 d . . . A 1
H33 H 0.0467 0.0871 0.9596 0.053 Uiso 1 1 calc R U . A 1
C34 C 0.2601(4) 0.0857(3) 0.9639(2) 0.0388(7) Uani 1 1 d . . . A 1
H34 H 0.2616 0.0364 1.0211 0.047 Uiso 1 1 calc R U . A 1
C35 C 0.3882(4) 0.1252(3) 0.9164(2) 0.0372(7) Uani 1 1 d . . . A 1
H35 H 0.4785 0.1017 0.9403 0.045 Uiso 1 1 calc R U . A 1
C36 C 0.3844(3) 0.2001(3) 0.8330(2) 0.0303(6) Uani 1 1 d . . . A 1
H36 H 0.4723 0.2268 0.7995 0.036 Uiso 1 1 calc R U . A 1
C41 C 0.4219(3) 0.4926(2) 0.7316(2) 0.0269(5) Uani 1 1 d . . . A 1
C42 C 0.2912(4) 0.6073(3) 0.7544(2) 0.0337(6) Uani 1 1 d . . . A 1
H42 H 0.2209 0.6316 0.7147 0.040 Uiso 1 1 calc R U . A 1
C43 C 0.2623(4) 0.6876(3) 0.8358(2) 0.0388(7) Uani 1 1 d . . . A 1
H43 H 0.1730 0.7668 0.8519 0.047 Uiso 1 1 calc R U . A 1
C44 C 0.3658(4) 0.6500(3) 0.8924(2) 0.0398(7) Uani 1 1 d . . . A 1
C45 C 0.4971(4) 0.5373(3) 0.8696(2) 0.0384(7) Uani 1 1 d . . . A 1
H45 H 0.5679 0.5142 0.9089 0.046 Uiso 1 1 calc R U . A 1
C46 C 0.5261(4) 0.4572(3) 0.7889(2) 0.0342(6) Uani 1 1 d . . . A 1
H46 H 0.6166 0.3787 0.7727 0.041 Uiso 1 1 calc R U . A 1
Cl2 Cl 0.32747(13) 0.74854(8) 0.99629(7) 0.0591(3) Uani 1 1 d . . . A 1
Au1B Au 0.4073(15) 0.1156(12) 0.8453(10) 0.015(4) Uiso 0.0070(5) 1 d . . P A 2
B1 B 0.8666(4) 0.0198(4) 0.7533(3) 0.0391(8) Uani 1 1 d . . . . .
F1 F 0.7999(3) 0.1418(2) 0.7341(3) 0.1270(14) Uani 1 1 d . . . . .
F2 F 0.9454(3) 0.0082(3) 0.82307(17) 0.0909(9) Uani 1 1 d . . . . .
F3 F 0.9785(2) -0.0490(2) 0.66515(15) 0.0581(6) Uani 1 1 d . . . . .
F4 F 0.7420(2) -0.02499(19) 0.79236(15) 0.0512(5) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C41 Au1 N19 174.89(9) . .
C41 Au1 P1 91.72(8) . .
N19 Au1 P1 83.79(6) . .
C41 Au1 Cl1 89.53(8) . .
N19 Au1 Cl1 95.00(6) . .
P1 Au1 Cl1 178.38(2) . .
C21 P1 C31 107.28(13) . .
C21 P1 C11 108.83(14) . .
C31 P1 C11 109.15(12) . .
C21 P1 Au1 117.86(9) . .
C31 P1 Au1 113.48(9) . .
C11 P1 Au1 99.75(9) . .
C12 C11 C20 119.5(2) . .
C12 C11 P1 123.2(2) . .
C20 C11 P1 117.07(19) . .
C11 C12 C13 120.6(3) . .
C11 C12 H12 119.7 . .
C13 C12 H12 119.7 . .
C14 C13 C12 120.4(3) . .
C14 C13 H13 119.8 . .
C12 C13 H13 119.8 . .
C13 C14 C15 120.8(3) . .
C13 C14 H14 119.6 . .
C15 C14 H14 119.6 . .
C14 C15 C20 119.1(3) . .
C14 C15 C16 122.9(2) . .
C20 C15 C16 118.0(2) . .
C17 C16 C15 119.9(2) . .
C17 C16 H16 120.1 . .
C15 C16 H16 120.1 . .
C16 C17 C18 119.3(3) . .
C16 C17 H17 120.4 . .
C18 C17 H17 120.4 . .
N19 C18 C17 122.8(3) . .
N19 C18 H18 118.6 . .
C17 C18 H18 118.6 . .
C18 N19 C20 119.3(2) . .
C18 N19 Au1 123.90(18) . .
C20 N19 Au1 116.74(16) . .
N19 C20 C15 120.6(2) . .
N19 C20 C11 119.9(2) . .
C15 C20 C11 119.5(2) . .
C22 C21 C26 120.5(3) . .
C22 C21 P1 119.9(3) . .
C26 C21 P1 119.5(3) . .
C21 C22 C23 118.4(4) . .
C21 C22 H22 120.8 . .
C23 C22 H22 120.8 . .
C24 C23 C22 121.7(5) . .
C24 C23 H23 119.1 . .
C22 C23 H23 119.1 . .
C23 C24 C25 119.7(4) . .
C23 C24 H24 120.2 . .
C25 C24 H24 120.2 . .
C24 C25 C26 120.7(5) . .
C24 C25 H25 119.7 . .
C26 C25 H25 119.7 . .
C21 C26 C25 119.0(4) . .
C21 C26 H26 120.5 . .
C25 C26 H26 120.5 . .
C36 C31 C32 120.5(3) . .
C36 C31 P1 120.9(2) . .
C32 C31 P1 118.6(2) . .
C33 C32 C31 119.4(3) . .
C33 C32 H32 120.3 . .
C31 C32 H32 120.3 . .
C34 C33 C32 120.8(3) . .
C34 C33 H33 119.6 . .
C32 C33 H33 119.6 . .
C33 C34 C35 120.1(3) . .
C33 C34 H34 120.0 . .
C35 C34 H34 120.0 . .
C34 C35 C36 119.9(3) . .
C34 C35 H35 120.0 . .
C36 C35 H35 120.0 . .
C31 C36 C35 119.2(3) . .
C31 C36 H36 120.4 . .
C35 C36 H36 120.4 . .
C42 C41 C46 120.2(2) . .
C42 C41 Au1 122.2(2) . .
C46 C41 Au1 117.6(2) . .
C41 C42 C43 120.0(3) . .
C41 C42 H42 120.0 . .
C43 C42 H42 120.0 . .
C44 C43 C42 118.8(3) . .
C44 C43 H43 120.6 . .
C42 C43 H43 120.6 . .
C45 C44 C43 121.7(3) . .
C45 C44 Cl2 119.3(2) . .
C43 C44 Cl2 119.0(2) . .
C44 C45 C46 119.7(3) . .
C44 C45 H45 120.2 . .
C46 C45 H45 120.2 . .
C45 C46 C41 119.6(3) . .
C45 C46 H46 120.2 . .
C41 C46 H46 120.2 . .
F1 B1 F3 109.7(3) . .
F1 B1 F2 111.1(3) . .
F3 B1 F2 108.2(3) . .
F1 B1 F4 108.2(3) . .
F3 B1 F4 110.5(3) . .
F2 B1 F4 109.1(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C41 2.027(2) .
Au1 N19 2.146(2) .
Au1 P1 2.2737(7) .
Au1 Cl1 2.3350(6) .
P1 C21 1.790(3) .
P1 C31 1.794(3) .
P1 C11 1.799(3) .
C11 C12 1.384(4) .
C11 C20 1.413(4) .
C12 C13 1.396(4) .
C12 H12 0.9500 .
C13 C14 1.363(4) .
C13 H13 0.9500 .
C14 C15 1.407(4) .
C14 H14 0.9500 .
C15 C20 1.411(3) .
C15 C16 1.418(4) .
C16 C17 1.357(4) .
C16 H16 0.9500 .
C17 C18 1.401(4) .
C17 H17 0.9500 .
C18 N19 1.323(3) .
C18 H18 0.9500 .
N19 C20 1.379(3) .
C21 C22 1.381(5) .
C21 C26 1.384(5) .
C22 C23 1.388(6) .
C22 H22 0.9500 .
C23 C24 1.356(8) .
C23 H23 0.9500 .
C24 C25 1.363(8) .
C24 H24 0.9500 .
C25 C26 1.392(5) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C31 C36 1.382(4) .
C31 C32 1.388(4) .
C32 C33 1.387(4) .
C32 H32 0.9500 .
C33 C34 1.364(4) .
C33 H33 0.9500 .
C34 C35 1.387(4) .
C34 H34 0.9500 .
C35 C36 1.404(4) .
C35 H35 0.9500 .
C36 H36 0.9500 .
C41 C42 1.382(4) .
C41 C46 1.392(4) .
C42 C43 1.393(4) .
C42 H42 0.9500 .
C43 C44 1.379(4) .
C43 H43 0.9500 .
C44 C45 1.369(4) .
C44 Cl2 1.747(3) .
C45 C46 1.385(4) .
C45 H45 0.9500 .
C46 H46 0.9500 .
B1 F1 1.350(5) .
B1 F3 1.367(4) .
B1 F2 1.377(4) .
B1 F4 1.382(4) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C21 P1 C11 C12 -45.2(3) . . . .
C31 P1 C11 C12 71.6(3) . . . .
Au1 P1 C11 C12 -169.2(2) . . . .
C21 P1 C11 C20 139.8(2) . . . .
C31 P1 C11 C20 -103.5(2) . . . .
Au1 P1 C11 C20 15.7(2) . . . .
C20 C11 C12 C13 1.3(4) . . . .
P1 C11 C12 C13 -173.6(2) . . . .
C11 C12 C13 C14 1.1(5) . . . .
C12 C13 C14 C15 -2.1(5) . . . .
C13 C14 C15 C20 0.7(4) . . . .
C13 C14 C15 C16 -179.1(3) . . . .
C14 C15 C16 C17 -179.3(3) . . . .
C20 C15 C16 C17 1.0(4) . . . .
C15 C16 C17 C18 -1.9(4) . . . .
C16 C17 C18 N19 -0.2(5) . . . .
C17 C18 N19 C20 3.2(4) . . . .
C17 C18 N19 Au1 -174.3(2) . . . .
C18 N19 C20 C15 -4.1(4) . . . .
Au1 N19 C20 C15 173.60(18) . . . .
C18 N19 C20 C11 176.5(2) . . . .
Au1 N19 C20 C11 -5.8(3) . . . .
C14 C15 C20 N19 -177.7(2) . . . .
C16 C15 C20 N19 2.0(4) . . . .
C14 C15 C20 C11 1.7(4) . . . .
C16 C15 C20 C11 -178.6(2) . . . .
C12 C11 C20 N19 176.7(2) . . . .
P1 C11 C20 N19 -8.0(3) . . . .
C12 C11 C20 C15 -2.7(4) . . . .
P1 C11 C20 C15 172.58(19) . . . .
C31 P1 C21 C22 -154.6(3) . . . .
C11 P1 C21 C22 -36.6(3) . . . .
Au1 P1 C21 C22 75.9(3) . . . .
C31 P1 C21 C26 29.4(3) . . . .
C11 P1 C21 C26 147.4(3) . . . .
Au1 P1 C21 C26 -100.1(3) . . . .
C26 C21 C22 C23 0.5(6) . . . .
P1 C21 C22 C23 -175.5(3) . . . .
C21 C22 C23 C24 0.2(7) . . . .
C22 C23 C24 C25 -0.9(8) . . . .
C23 C24 C25 C26 0.8(7) . . . .
C22 C21 C26 C25 -0.5(5) . . . .
P1 C21 C26 C25 175.5(3) . . . .
C24 C25 C26 C21 -0.1(6) . . . .
C21 P1 C31 C36 -124.0(2) . . . .
C11 P1 C31 C36 118.2(2) . . . .
Au1 P1 C31 C36 7.9(2) . . . .
C21 P1 C31 C32 55.5(3) . . . .
C11 P1 C31 C32 -62.2(3) . . . .
Au1 P1 C31 C32 -172.5(2) . . . .
C36 C31 C32 C33 0.0(4) . . . .
P1 C31 C32 C33 -179.5(2) . . . .
C31 C32 C33 C34 2.0(5) . . . .
C32 C33 C34 C35 -2.6(5) . . . .
C33 C34 C35 C36 1.2(5) . . . .
C32 C31 C36 C35 -1.4(4) . . . .
P1 C31 C36 C35 178.2(2) . . . .
C34 C35 C36 C31 0.7(4) . . . .
C46 C41 C42 C43 -0.7(4) . . . .
Au1 C41 C42 C43 179.4(2) . . . .
C41 C42 C43 C44 -0.2(4) . . . .
C42 C43 C44 C45 1.2(5) . . . .
C42 C43 C44 Cl2 -178.5(2) . . . .
C43 C44 C45 C46 -1.2(5) . . . .
Cl2 C44 C45 C46 178.5(2) . . . .
C44 C45 C46 C41 0.3(5) . . . .
C42 C41 C46 C45 0.6(4) . . . .
Au1 C41 C46 C45 -179.5(2) . . . .
