Crystallography Open Database

Information card for entry 7121756

Preview

Coordinates	7121756.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C34 H56 Cl2 P2 Rh2 S2
Calculated formula	C34 H56 Cl2 P2 Rh2 S2
Title of publication	Synthesis of Rh(iii) thiophosphinito pincer hydrido complexes by base-free C-H bond activation at room temperature.
Authors of publication	Vlahopoulou, G.; Möller, S; Haak, J.; Hasche, P.; Drexler, H.-J.; Heller, D.; Beweries, T.
Journal of publication	Chemical communications (Cambridge, England)
Year of publication	2018
Journal volume	54
Journal issue	49
Pages of publication	6292 - 6295
a	14.121 ± 0.0005 Å
b	14.5253 ± 0.0005 Å
c	18.8086 ± 0.0006 Å
α	90°
β	90°
γ	90°
Cell volume	3857.9 ± 0.2 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	6
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for all reflections	0.0369
Residual factor for significantly intense reflections	0.0357
Weighted residual factors for significantly intense reflections	0.0947
Weighted residual factors for all reflections included in the refinement	0.0958
Goodness-of-fit parameter for all reflections included in the refinement	1.011
Diffraction radiation wavelength	1.54178 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
228491 (current)	2019-11-17	cif/ Updating files of 7121756, 7121757, 7121758, 7121759, 7121760 Original log message: Adding full bibliography for 7121756--7121760.cif.	7121756.cif
207972	2018-05-25	cif/ Adding structures of 7121756, 7121757, 7121758, 7121759, 7121760 via cif-deposit CGI script.	7121756.cif