Crystallography Open Database

Information card for entry 7121760

Preview

Coordinates	7121760.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C76 H72 Cl4 P4 Rh4 S4
Calculated formula	C76 H72 Cl4 P4 Rh4 S4
Title of publication	Synthesis of Rh(iii) thiophosphinito pincer hydrido complexes by base-free C-H bond activation at room temperature.
Authors of publication	Vlahopoulou, G.; Möller, S; Haak, J.; Hasche, P.; Drexler, H.-J.; Heller, D.; Beweries, T.
Journal of publication	Chemical communications (Cambridge, England)
Year of publication	2018
Journal volume	54
Journal issue	49
Pages of publication	6292 - 6295
a	10.7617 ± 0.0013 Å
b	17.854 ± 0.002 Å
c	19.459 ± 0.002 Å
α	78.973 ± 0.002°
β	84.819 ± 0.002°
γ	78.382 ± 0.002°
Cell volume	3589.4 ± 0.7 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0545
Residual factor for significantly intense reflections	0.0347
Weighted residual factors for significantly intense reflections	0.0752
Weighted residual factors for all reflections included in the refinement	0.0857
Goodness-of-fit parameter for all reflections included in the refinement	1.019
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
228491 (current)	2019-11-17	cif/ Updating files of 7121756, 7121757, 7121758, 7121759, 7121760 Original log message: Adding full bibliography for 7121756--7121760.cif.	7121760.cif
207972	2018-05-25	cif/ Adding structures of 7121756, 7121757, 7121758, 7121759, 7121760 via cif-deposit CGI script.	7121760.cif