Crystallography Open Database

Information card for entry 7122428

Preview

Coordinates	7122428.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C48 H107 Ge4 K1.09 N8 O18 Rb1.91 Zn
Calculated formula	C48 H107 Ge4 K1.09 N8 O18 Rb1.91 Zn
Title of publication	[(μ<sub>2</sub>-H)(η<sup>2</sup>-Ge<sub>4</sub>)ZnPh<sub>2</sub>]<sup>3-</sup>, an edge-on protonated E<sub>4</sub> cluster establishing the first three-center two-electron Ge-H-Ge bond.
Authors of publication	Henneberger, Thomas; Klein, Wilhelm; Dums, Jasmin V.; Fässler, Thomas F
Journal of publication	Chemical communications (Cambridge, England)
Year of publication	2018
Journal volume	54
Journal issue	87
Pages of publication	12381 - 12384
a	12.8668 ± 0.0005 Å
b	28.2571 ± 0.0009 Å
c	20.0883 ± 0.0006 Å
α	90°
β	90°
γ	90°
Cell volume	7303.7 ± 0.4 Å³
Cell temperature	120 ± 2 K
Ambient diffraction temperature	120 ± 2 K
Number of distinct elements	8
Space group number	60
Hermann-Mauguin space group symbol	P b c n
Hall space group symbol	-P 2n 2ab
Residual factor for all reflections	0.0694
Residual factor for significantly intense reflections	0.0345
Weighted residual factors for significantly intense reflections	0.0707
Weighted residual factors for all reflections included in the refinement	0.0757
Goodness-of-fit parameter for all reflections included in the refinement	0.866
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
228614 (current)	2019-11-17	cif/ Updating files of 7122428, 7122429 Original log message: Adding full bibliography for 7122428--7122429.cif.	7122428.cif
211367	2018-10-11	cif/ Adding structures of 7122428, 7122429 via cif-deposit CGI script.	7122428.cif