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Information card for entry 7123051
Preview
| Coordinates | 7123051.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C28 H47 N3 O Si3 |
|---|---|
| Calculated formula | C28 H47 N3 O Si3 |
| Title of publication | Silylene induced cooperative B‒H bond activation and unprecedented aldehyde C‒H bond splitting with amidinate ring expansion |
| Authors of publication | Roesky, Herbert W.; Swamy, V S. V. S. N.; Vanka, Kumar; Raj, K. Vipin; Sen, Sakya Singha |
| Journal of publication | Chemical Communications |
| Year of publication | 2019 |
| a | 10.8132 ± 0.0014 Å |
| b | 10.9099 ± 0.0013 Å |
| c | 13.5038 ± 0.0017 Å |
| α | 80.743 ± 0.003° |
| β | 78.036 ± 0.003° |
| γ | 79.717 ± 0.003° |
| Cell volume | 1520.7 ± 0.3 Å3 |
| Cell temperature | 296 ± 2 K |
| Ambient diffraction temperature | 296 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.1084 |
| Residual factor for significantly intense reflections | 0.0535 |
| Weighted residual factors for significantly intense reflections | 0.088 |
| Weighted residual factors for all reflections included in the refinement | 0.1049 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.026 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 213838 (current) | 2019-02-26 | cif/ Adding structures of 7123049, 7123050, 7123051, 7123052 via cif-deposit CGI script. |
7123051.cif |
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Users of the data should acknowledge the original authors of the
structural data.