Crystallography Open Database

Information card for entry 7128124

Preview

Coordinates	7128124.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C62 H178 Eu Ge18 O2 Si24
Calculated formula	C62 H178 Eu Ge18 O2 Si24
SMILES	[Eu]12([Ge]345[Ge]67[Ge]813[Ge]17([Ge]37[Ge]46([Ge]47[Ge]58([Ge]134)[Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)[Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)[Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)([Ge]134[Ge]56[Ge]721[Ge]13([Ge]23[Ge]67([Ge]62[Ge]45([Ge]136)[Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)[Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)[Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)([O]1CCCC1)[O]1CCCC1
Title of publication	(thf)<sub>2</sub>Ln(Ge<sub>9</sub>{Si(SiMe<sub>3</sub>)<sub>3</sub>}<sub>3</sub>)<sub>2</sub> (Ln = Eu, Sm): the first coordination of metalloid germanium clusters to lanthanides.
Authors of publication	Klementyeva, Svetlana V.; Schrenk, Claudio; Zhang, Minghui; Khusniyarov, Marat M.; Schnepf, Andreas
Journal of publication	Chemical communications (Cambridge, England)
Year of publication	2021
Journal volume	57
Journal issue	38
Pages of publication	4730 - 4733
a	22.778 ± 0.003 Å
b	24.085 ± 0.003 Å
c	29.746 ± 0.004 Å
α	90°
β	112.419 ± 0.002°
γ	90°
Cell volume	15086 ± 3 Å³
Cell temperature	150 K
Ambient diffraction temperature	150 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.1435
Residual factor for significantly intense reflections	0.0602
Weighted residual factors for significantly intense reflections	0.1345
Weighted residual factors for all reflections included in the refinement	0.1789
Goodness-of-fit parameter for all reflections included in the refinement	1.017
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
265903 (current)	2021-06-05	cif/ Updating files of 7128123, 7128124 Original log message: Adding full bibliography for 7128123--7128124.cif.	7128124.cif
263536	2021-04-02	cif/ Adding structures of 7128123, 7128124 via cif-deposit CGI script.	7128124.cif