Crystallography Open Database

Information card for entry 7134145

Preview

Coordinates	7134145.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	5,10,15,20-tetrakis(para-dipivaloyloxyphenyl)Cobalt Porphyrin
Formula	C64 H60 Co N4 O8
Calculated formula	C64 H60 Co N4 O8
Title of publication	The steric hindrance effect of Co porphyrins promoting two-electron oxygen reduction reaction selectivity.
Authors of publication	Mou, Yonghong; Zhang, Jieling; Qin, Haonan; Li, Xinyue; Zeng, Zequan; Zhang, Rong; Liang, Zuozhong; Cao, Rui
Journal of publication	Chemical communications (Cambridge, England)
Year of publication	2025
Journal volume	61
Journal issue	9
Pages of publication	1878 - 1881
a	9.8827 ± 0.0018 Å
b	16.038 ± 0.003 Å
c	19.204 ± 0.003 Å
α	77.886 ± 0.007°
β	86.561 ± 0.007°
γ	82.747 ± 0.007°
Cell volume	2950.5 ± 0.9 Å³
Cell temperature	190 ± 0.1 K
Ambient diffraction temperature	190 ± 0.1 K
Number of distinct elements	5
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.1841
Residual factor for significantly intense reflections	0.1003
Weighted residual factors for significantly intense reflections	0.2677
Weighted residual factors for all reflections included in the refinement	0.3331
Goodness-of-fit parameter for all reflections included in the refinement	1.04
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.34139 Å
Diffraction radiation type	GaKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
298057 (current)	2025-03-04	cif/ Updating files of 7134144, 7134145 Original log message: Adding full bibliography for 7134144--7134145.cif.	7134145.cif
297195	2025-01-08	cif/ Adding structures of 7134144, 7134145 via cif-deposit CGI script.	7134145.cif