#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:25:55 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180434 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/03/7210384.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7210384
loop_
_publ_author_name
'Li, Bing'
'Liao, Jian-Hong'
'Li, Yi-Juan'
'Liu, C. W.'
_publ_section_title
;
 Dihalogen-templated synthesis of dodecanuclear silver
 dichalcogenophosphate clusters
;
_journal_issue                   31
_journal_name_full               CrystEngComm
_journal_page_first              6140
_journal_paper_doi               10.1039/c3ce40829a
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'C40 H100 Ag12 Br2 O20 P10 S20'
_chemical_formula_weight         3306.36
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.130(4)
_cell_angle_beta                 103.059(5)
_cell_angle_gamma                110.356(3)
_cell_formula_units_Z            1
_cell_length_a                   12.685(3)
_cell_length_b                   13.348(3)
_cell_length_c                   16.747(5)
_cell_measurement_reflns_used    9355
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.91
_cell_measurement_theta_min      2.26
_cell_volume                     2487.2(11)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0406
_diffrn_reflns_av_sigmaI/netI    0.0567
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            20056
_diffrn_reflns_theta_full        26.11
_diffrn_reflns_theta_max         26.11
_diffrn_reflns_theta_min         1.69
_exptl_absorpt_coefficient_mu    3.741
_exptl_absorpt_correction_T_max  0.4548
_exptl_absorpt_correction_T_min  0.3807
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.207
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1604
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.25
_refine_diff_density_max         1.818
_refine_diff_density_min         -1.427
_refine_diff_density_rms         0.165
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     466
_refine_ls_number_reflns         9594
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.043
_refine_ls_R_factor_all          0.0859
_refine_ls_R_factor_gt           0.0555
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0475P)²+21.3857P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1316
_refine_ls_wR_factor_ref         0.1545
_reflns_number_gt                6715
_reflns_number_total             9594
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce40829a.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        2487.1(10)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7210384
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.48964(6) 0.79654(6) 0.15564(5) 0.0549(2) Uani 1 1 d .
Ag2 Ag 0.71133(9) 0.77847(8) 0.28390(7) 0.0786(3) Uani 1 1 d .
Ag3 Ag 0.54759(7) 0.56748(7) 0.32603(5) 0.0596(2) Uani 1 1 d .
Ag4 Ag 0.66781(7) 0.46361(7) 0.20747(5) 0.0575(2) Uani 1 1 d .
Ag5 Ag 0.36036(7) 0.54609(6) 0.15401(5) 0.0544(2) Uani 1 1 d .
Ag6 Ag 0.55744(8) 0.68312(9) -0.00915(6) 0.0751(3) Uani 1 1 d .
Br1 Br 0.58178(8) 0.60203(7) 0.12724(6) 0.0443(2) Uani 1 1 d .
C1 C 0.9127(14) 1.0332(12) 0.0840(10) 0.099(5) Uani 1 1 d .
H1A H 0.8474 0.9773 0.0364 0.119 Uiso 1 1 calc R
H1B H 0.9651 0.9996 0.1065 0.119 Uiso 1 1 calc R
C2 C 0.9768(15) 1.1270(12) 0.0552(11) 0.115(6) Uani 1 1 d .
H2A H 0.9235 1.1576 0.0304 0.172 Uiso 1 1 calc R
H2B H 1.0094 1.1017 0.0133 0.172 Uiso 1 1 calc R
H2C H 1.0396 1.1831 0.1030 0.172 Uiso 1 1 calc R
C3 C 0.7042(11) 1.1356(10) 0.2420(7) 0.067(3) Uani 1 1 d .
H3A H 0.6226 1.0977 0.2399 0.081 Uiso 1 1 calc R
H3B H 0.7047 1.1517 0.1878 0.081 Uiso 1 1 calc R
C4 C 0.7623(16) 1.2385(13) 0.3112(8) 0.109(6) Uani 1 1 d .
H4A H 0.7496 1.2233 0.3630 0.163 Uiso 1 1 calc R
H4B H 0.7299 1.2908 0.2974 0.163 Uiso 1 1 calc R
H4C H 0.8456 1.2692 0.3187 0.163 Uiso 1 1 calc R
C5 C 0.2055(14) 0.7693(16) 0.3068(11) 0.109(4) Uani 1 1 d .
H5A H 0.2061 0.7499 0.3601 0.131 Uiso 1 1 calc R
H5B H 0.1551 0.7030 0.2601 0.131 Uiso 1 1 calc R
C6 C 0.1604(12) 0.8556(12) 0.3029(10) 0.093(4) Uani 1 1 d .
H6A H 0.2083 0.9195 0.3510 0.140 Uiso 1 1 calc R
H6B H 0.0802 0.8279 0.3040 0.140 Uiso 1 1 calc R
H6C H 0.1630 0.8764 0.2511 0.140 Uiso 1 1 calc R
C7 C 0.5238(15) 0.8195(16) 0.5060(10) 0.109(4) Uani 1 1 d U
H7A H 0.5995 0.8639 0.5008 0.131 Uiso 1 1 calc R
H7B H 0.5200 0.7450 0.5031 0.131 Uiso 1 1 calc R
C8 C 0.5152(17) 0.8689(13) 0.5903(9) 0.119(6) Uani 1 1 d U
H8A H 0.5159 0.9415 0.5926 0.178 Uiso 1 1 calc R
H8B H 0.5813 0.8748 0.6352 0.178 Uiso 1 1 calc R
H8C H 0.4430 0.8220 0.5974 0.178 Uiso 1 1 calc R
C9 C 0.2588(12) 0.2801(13) 0.3295(8) 0.091(4) Uani 1 1 d .
H9A H 0.3221 0.2565 0.3486 0.109 Uiso 1 1 calc R
H9B H 0.2733 0.3473 0.3716 0.109 Uiso 1 1 calc R
C10 C 0.1541(17) 0.199(2) 0.3231(12) 0.187(13) Uani 1 1 d .
H10A H 0.0922 0.2248 0.3083 0.281 Uiso 1 1 calc R
H10B H 0.1580 0.1824 0.3768 0.281 Uiso 1 1 calc R
H10C H 0.1380 0.1338 0.2797 0.281 Uiso 1 1 calc R
C11 C 0.3814(13) 0.1126(10) 0.1426(9) 0.081(4) Uani 1 1 d .
H11A H 0.4645 0.1503 0.1758 0.097 Uiso 1 1 calc R
H11B H 0.3737 0.1197 0.0852 0.097 Uiso 1 1 calc R
C12 C 0.3389(14) -0.0069(11) 0.1400(11) 0.107(5) Uani 1 1 d .
H12A H 0.3518 -0.0138 0.1971 0.161 Uiso 1 1 calc R
H12B H 0.3814 -0.0406 0.1120 0.161 Uiso 1 1 calc R
H12C H 0.2559 -0.0437 0.1091 0.161 Uiso 1 1 calc R
C13 C 0.9248(9) 0.3663(11) 0.1589(6) 0.065(3) Uani 1 1 d .
H13A H 0.9056 0.2942 0.1701 0.078 Uiso 1 1 calc R
H13B H 0.8899 0.4067 0.1907 0.078 Uiso 1 1 calc R
C14 C 1.0529(10) 0.4278(11) 0.1870(7) 0.079(4) Uani 1 1 d .
H14A H 1.0874 0.3866 0.1567 0.119 Uiso 1 1 calc R
H14B H 1.0838 0.4382 0.2471 0.119 Uiso 1 1 calc R
H14C H 1.0717 0.4989 0.1757 0.119 Uiso 1 1 calc R
C15 C 0.9030(9) 0.5831(9) 0.0471(7) 0.063(3) Uani 1 1 d .
H15A H 0.9719 0.5658 0.0619 0.075 Uiso 1 1 calc R
H15B H 0.8816 0.5784 -0.0133 0.075 Uiso 1 1 calc R
C16 C 0.9287(12) 0.6952(9) 0.0981(7) 0.078(4) Uani 1 1 d .
H16A H 0.8598 0.7112 0.0830 0.117 Uiso 1 1 calc R
H16B H 0.9931 0.7488 0.0870 0.117 Uiso 1 1 calc R
H16C H 0.9500 0.6988 0.1576 0.117 Uiso 1 1 calc R
C17 C 1.0316(15) 0.8564(11) 0.5181(11) 0.124(4) Uani 1 1 d DU
H17A H 0.9760 0.8904 0.5045 0.148 Uiso 1 1 calc R
H17B H 1.0307 0.8403 0.5722 0.148 Uiso 1 1 calc R
C18 C 1.1440(13) 0.9331(13) 0.5279(9) 0.110(5) Uani 1 1 d U
H18A H 1.1913 0.8945 0.5133 0.164 Uiso 1 1 calc R
H18B H 1.1802 0.9779 0.5862 0.164 Uiso 1 1 calc R
H18C H 1.1383 0.9799 0.4911 0.164 Uiso 1 1 calc R
C19 C 0.7922(14) 0.4916(12) 0.4773(13) 0.124(4) Uani 1 1 d DU
H19A H 0.7660 0.4422 0.4202 0.148 Uiso 1 1 calc R
H19B H 0.7241 0.5022 0.4877 0.148 Uiso 1 1 calc R
C20 C 0.8336(16) 0.4385(15) 0.5375(10) 0.111(5) Uani 1 1 d U
H20A H 0.8992 0.4249 0.5265 0.167 Uiso 1 1 calc R
H20B H 0.7709 0.3691 0.5318 0.167 Uiso 1 1 calc R
H20C H 0.8584 0.4859 0.5944 0.167 Uiso 1 1 calc R
O1 O 0.8683(6) 1.0732(6) 0.1495(5) 0.0621(18) Uani 1 1 d .
O2 O 0.7680(5) 1.0655(5) 0.2576(4) 0.0489(15) Uani 1 1 d .
O3 O 0.3194(7) 0.8094(8) 0.3013(7) 0.092(3) Uani 1 1 d .
O4 O 0.4353(9) 0.8148(9) 0.4402(6) 0.106(3) Uani 1 1 d .
O5 O 0.2593(6) 0.3041(6) 0.2473(5) 0.0629(19) Uani 1 1 d .
O6 O 0.3167(6) 0.1629(5) 0.1790(5) 0.0619(18) Uani 1 1 d .
O7 O 0.8765(5) 0.3514(6) 0.0686(4) 0.0503(15) Uani 1 1 d .
O8 O 0.8036(5) 0.5044(5) 0.0664(4) 0.0506(15) Uani 1 1 d .
O9 O 0.9919(7) 0.7556(8) 0.4552(7) 0.117(4) Uani 1 1 d DU
O10 O 0.8764(11) 0.5949(9) 0.4801(7) 0.124(4) Uani 1 1 d D
P1 P 0.7819(2) 0.98569(19) 0.18368(16) 0.0464(5) Uani 1 1 d .
P2 P 0.4232(2) 0.7728(2) 0.34632(18) 0.0585(7) Uani 1 1 d .
P3 P 0.3507(2) 0.29190(19) 0.20107(15) 0.0438(5) Uani 1 1 d .
P4 P 0.76396(18) 0.37566(19) 0.03265(14) 0.0401(5) Uani 1 1 d .
P5 P 0.8671(2) 0.6575(2) 0.41264(17) 0.0547(6) Uani 1 1 d .
S1 S 0.8644(2) 0.9011(2) 0.2353(2) 0.0659(7) Uani 1 1 d .
S2 S 0.6277(2) 0.9055(2) 0.08876(16) 0.0538(6) Uani 1 1 d .
S3 S 0.5593(2) 0.8677(2) 0.31706(16) 0.0528(6) Uani 1 1 d .
S4 S 0.3658(2) 0.6062(2) 0.31081(16) 0.0516(6) Uani 1 1 d .
S5 S 0.5167(2) 0.3687(2) 0.28175(16) 0.0489(5) Uani 1 1 d .
S6 S 0.30759(18) 0.33790(18) 0.09588(14) 0.0435(5) Uani 1 1 d .
S7 S 0.63690(18) 0.30444(19) 0.08156(14) 0.0442(5) Uani 1 1 d .
S8 S 0.26988(18) 0.67336(19) 0.09317(14) 0.0427(5) Uani 1 1 d .
S9 S 0.7408(2) 0.7153(2) 0.41820(16) 0.0567(6) Uani 1 1 d .
S10 S 0.8714(2) 0.5881(3) 0.3016(2) 0.0769(9) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
S2 Ag1 S3 113.25(8) . .
S2 Ag1 S8 129.94(8) . .
S3 Ag1 S8 113.40(8) . .
S2 Ag1 Ag5 138.84(7) . .
S3 Ag1 Ag5 93.78(6) . .
S8 Ag1 Ag5 52.52(5) . .
S2 Ag1 Ag2 88.87(7) . .
S3 Ag1 Ag2 54.11(6) . .
S8 Ag1 Ag2 134.00(6) . .
Ag5 Ag1 Ag2 82.47(3) . .
S2 Ag1 Ag6 56.17(6) . .
S3 Ag1 Ag6 142.89(7) . .
S8 Ag1 Ag6 94.11(6) . .
Ag5 Ag1 Ag6 83.39(3) . .
Ag2 Ag1 Ag6 88.94(4) . .
S1 Ag2 S9 127.64(10) . .
S1 Ag2 S3 112.42(9) . .
S9 Ag2 S3 95.46(9) . .
S1 Ag2 Br1 99.04(9) . .
S9 Ag2 Br1 115.17(7) . .
S3 Ag2 Br1 106.02(6) . .
S1 Ag2 Ag3 161.99(8) . .
S9 Ag2 Ag3 50.01(6) . .
S3 Ag2 Ag3 85.24(6) . .
Br1 Ag2 Ag3 71.45(4) . .
S1 Ag2 Ag1 95.74(7) . .
S9 Ag2 Ag1 134.41(7) . .
S3 Ag2 Ag1 49.48(6) . .
Br1 Ag2 Ag1 62.75(3) . .
Ag3 Ag2 Ag1 93.28(3) . .
S9 Ag3 S5 122.19(9) . .
S9 Ag3 S4 118.82(9) . .
S5 Ag3 S4 116.69(8) . .
S9 Ag3 Ag2 51.56(7) . .
S5 Ag3 Ag2 130.66(7) . .
S4 Ag3 Ag2 99.63(7) . .
S9 Ag3 Ag4 92.15(7) . .
S5 Ag3 Ag4 53.07(6) . .
S4 Ag3 Ag4 138.48(7) . .
Ag2 Ag3 Ag4 77.60(3) . .
S9 Ag3 Ag5 133.68(7) . .
S5 Ag3 Ag5 93.19(6) . .
S4 Ag3 Ag5 52.36(6) . .
Ag2 Ag3 Ag5 83.21(3) . .
Ag4 Ag3 Ag5 86.46(4) . .
S10 Ag4 S7 119.67(9) . .
S10 Ag4 S5 116.70(10) . .
S7 Ag4 S5 103.66(8) . .
S10 Ag4 Br1 105.19(10) . .
S7 Ag4 Br1 103.32(6) . .
S5 Ag4 Br1 106.95(6) . .
S10 Ag4 Ag3 93.27(8) . .
S7 Ag4 Ag3 146.24(6) . .
S5 Ag4 Ag3 49.90(6) . .
Br1 Ag4 Ag3 72.02(3) . .
S6 Ag5 S8 130.32(8) . .
S6 Ag5 S4 114.48(8) . .
S8 Ag5 S4 99.08(8) . .
S6 Ag5 Br1 91.36(6) . .
S8 Ag5 Br1 106.52(6) . .
S4 Ag5 Br1 115.54(6) . .
S6 Ag5 Ag1 151.10(6) . .
S8 Ag5 Ag1 51.29(5) . .
S4 Ag5 Ag1 91.34(6) . .
Br1 Ag5 Ag1 64.60(3) . .
S6 Ag5 Ag3 92.88(6) . .
S8 Ag5 Ag3 136.54(6) . .
S4 Ag5 Ag3 50.04(6) . .
Br1 Ag5 Ag3 72.08(3) . .
Ag1 Ag5 Ag3 94.40(3) . .
S6 Ag6 S7 119.49(8) 2_665 2_665
S6 Ag6 Br1 113.78(6) 2_665 .
S7 Ag6 Br1 121.34(6) 2_665 .
S6 Ag6 S2 113.47(8) 2_665 .
S7 Ag6 S2 85.73(8) 2_665 .
Br1 Ag6 S2 94.71(6) . .
S6 Ag6 Ag1 155.64(7) 2_665 .
S7 Ag6 Ag1 77.07(6) 2_665 .
Br1 Ag6 Ag1 63.04(3) . .
S2 Ag6 Ag1 46.33(5) . .
Ag6 Br1 Ag5 103.70(4) . .
Ag6 Br1 Ag4 146.34(4) . .
Ag5 Br1 Ag4 101.17(4) . .
Ag6 Br1 Ag2 111.42(5) . .
Ag5 Br1 Ag2 95.77(4) . .
Ag4 Br1 Ag2 88.04(4) . .
O1 C1 C2 108.9(12) . .
O1 C1 H1A 109.9 . .
C2 C1 H1A 109.9 . .
O1 C1 H1B 109.9 . .
C2 C1 H1B 109.9 . .
H1A C1 H1B 108.3 . .
C1 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C1 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
O2 C3 C4 108.2(10) . .
O2 C3 H3A 110.1 . .
C4 C3 H3A 110.1 . .
O2 C3 H3B 110.1 . .
C4 C3 H3B 110.1 . .
H3A C3 H3B 108.4 . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
O3 C5 C6 108.5(14) . .
O3 C5 H5A 110.0 . .
C6 C5 H5A 110.0 . .
O3 C5 H5B 110.0 . .
C6 C5 H5B 110.0 . .
H5A C5 H5B 108.4 . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
O4 C7 C8 111.6(13) . .
O4 C7 H7A 109.3 . .
C8 C7 H7A 109.3 . .
O4 C7 H7B 109.3 . .
C8 C7 H7B 109.3 . .
H7A C7 H7B 108.0 . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C10 C9 O5 111.3(13) . .
C10 C9 H9A 109.4 . .
O5 C9 H9A 109.4 . .
C10 C9 H9B 109.4 . .
O5 C9 H9B 109.4 . .
H9A C9 H9B 108.0 . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
O6 C11 C12 110.9(11) . .
O6 C11 H11A 109.5 . .
C12 C11 H11A 109.5 . .
O6 C11 H11B 109.5 . .
C12 C11 H11B 109.5 . .
H11A C11 H11B 108.0 . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
O7 C13 C14 110.2(9) . .
O7 C13 H13A 109.6 . .
C14 C13 H13A 109.6 . .
O7 C13 H13B 109.6 . .
C14 C13 H13B 109.6 . .
H13A C13 H13B 108.1 . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 O8 107.1(8) . .
C16 C15 H15A 110.3 . .
O8 C15 H15A 110.3 . .
C16 C15 H15B 110.3 . .
O8 C15 H15B 110.3 . .
H15A C15 H15B 108.5 . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 O9 115.5(15) . .
C18 C17 H17A 108.4 . .
O9 C17 H17A 108.4 . .
C18 C17 H17B 108.4 . .
O9 C17 H17B 108.4 . .
H17A C17 H17B 107.5 . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
O10 C19 C20 114.7(14) . .
O10 C19 H19A 108.6 . .
C20 C19 H19A 108.6 . .
O10 C19 H19B 108.6 . .
C20 C19 H19B 108.6 . .
H19A C19 H19B 107.6 . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C1 O1 P1 119.0(8) . .
C3 O2 P1 122.8(6) . .
C5 O3 P2 124.2(10) . .
C7 O4 P2 123.9(10) . .
C9 O5 P3 123.1(7) . .
C11 O6 P3 123.0(7) . .
C13 O7 P4 121.1(6) . .
C15 O8 P4 120.9(6) . .
C17 O9 P5 132.1(10) . .
C19 O10 P5 126.0(12) . .
O2 P1 O1 100.8(4) . .
O2 P1 S1 107.9(3) . .
O1 P1 S1 109.3(3) . .
O2 P1 S2 110.2(3) . .
O1 P1 S2 106.8(3) . .
S1 P1 S2 120.12(16) . .
O4 P2 O3 100.4(6) . .
O4 P2 S3 111.3(4) . .
O3 P2 S3 101.4(4) . .
O4 P2 S4 110.6(5) . .
O3 P2 S4 109.9(4) . .
S3 P2 S4 120.81(16) . .
O5 P3 O6 102.0(4) . .
O5 P3 S6 103.9(3) . .
O6 P3 S6 110.9(3) . .
O5 P3 S5 111.0(3) . .
O6 P3 S5 108.0(3) . .
S6 P3 S5 119.69(14) . .
O8 P4 O7 106.3(4) . .
O8 P4 S8 111.9(3) . 2_665
O7 P4 S8 102.9(3) . 2_665
O8 P4 S7 106.6(3) . .
O7 P4 S7 110.5(3) . .
S8 P4 S7 118.05(14) 2_665 .
O10 P5 O9 96.6(7) . .
O10 P5 S10 116.3(5) . .
O9 P5 S10 104.5(5) . .
O10 P5 S9 108.2(5) . .
O9 P5 S9 109.4(4) . .
S10 P5 S9 119.15(17) . .
P1 S1 Ag2 101.30(13) . .
P1 S2 Ag1 104.33(12) . .
P1 S2 Ag6 121.61(14) . .
Ag1 S2 Ag6 77.50(7) . .
P2 S3 Ag1 101.90(12) . .
P2 S3 Ag2 116.84(14) . .
Ag1 S3 Ag2 76.41(7) . .
P2 S4 Ag3 105.80(12) . .
P2 S4 Ag5 107.79(13) . .
Ag3 S4 Ag5 77.60(7) . .
P3 S5 Ag3 104.20(12) . .
P3 S5 Ag4 112.18(12) . .
Ag3 S5 Ag4 77.04(7) . .
P3 S6 Ag6 108.53(12) . 2_665
P3 S6 Ag5 103.06(12) . .
Ag6 S6 Ag5 108.24(8) 2_665 .
P4 S7 Ag6 111.66(12) . 2_665
P4 S7 Ag4 102.85(11) . .
Ag6 S7 Ag4 87.37(8) 2_665 .
P4 S8 Ag1 106.52(11) 2_665 .
P4 S8 Ag5 105.65(11) 2_665 .
Ag1 S8 Ag5 76.18(7) . .
P5 S9 Ag3 108.09(13) . .
P5 S9 Ag2 102.37(14) . .
Ag3 S9 Ag2 78.43(8) . .
P5 S10 Ag4 110.09(15) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 S2 2.475(3) .
Ag1 S3 2.535(3) .
Ag1 S8 2.541(2) .
Ag1 Ag5 3.1622(12) .
Ag1 Ag2 3.2409(13) .
Ag1 Ag6 3.3402(14) .
Ag2 S1 2.467(3) .
Ag2 S9 2.533(3) .
Ag2 S3 2.701(3) .
Ag2 Br1 2.8836(15) .
Ag2 Ag3 3.1678(13) .
Ag3 S9 2.477(3) .
Ag3 S5 2.489(3) .
Ag3 S4 2.503(3) .
Ag3 Ag4 3.1718(12) .
Ag3 Ag5 3.1888(13) .
Ag4 S10 2.484(3) .
Ag4 S7 2.566(2) .
Ag4 S5 2.602(2) .
Ag4 Br1 2.8324(13) .
Ag5 S6 2.565(2) .
Ag5 S8 2.584(2) .
Ag5 S4 2.585(3) .
Ag5 Br1 2.8063(13) .
Ag6 S6 2.536(2) 2_665
Ag6 S7 2.565(2) 2_665
Ag6 Br1 2.6959(14) .
Ag6 S2 2.842(3) .
C1 O1 1.445(14) .
C1 C2 1.463(19) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 H2A 0.9600 .
C2 H2B 0.9600 .
C2 H2C 0.9600 .
C3 O2 1.454(11) .
C3 C4 1.457(17) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 H4A 0.9600 .
C4 H4B 0.9600 .
C4 H4C 0.9600 .
C5 O3 1.386(17) .
C5 C6 1.46(2) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 O4 1.358(17) .
C7 C8 1.49(2) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 C10 1.35(2) .
C9 O5 1.467(14) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 O6 1.402(13) .
C11 C12 1.484(17) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 O7 1.448(11) .
C13 C14 1.458(15) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 C16 1.470(15) .
C15 O8 1.476(11) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 C18 1.39(2) .
C17 O9 1.401(9) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 O10 1.405(9) .
C19 C20 1.44(2) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
O1 P1 1.587(7) .
O2 P1 1.569(6) .
O3 P2 1.634(9) .
O4 P2 1.527(8) .
O5 P3 1.570(7) .
O6 P3 1.573(7) .
O7 P4 1.583(6) .
O8 P4 1.567(6) .
O9 P5 1.565(9) .
O10 P5 1.527(10) .
P1 S1 1.968(4) .
P1 S2 2.010(4) .
P2 S3 1.976(4) .
P2 S4 2.010(4) .
P3 S6 1.989(3) .
P3 S5 2.009(3) .
P4 S8 1.991(3) 2_665
P4 S7 1.994(3) .
P5 S10 1.948(4) .
P5 S9 2.018(4) .
S6 Ag6 2.536(2) 2_665
S7 Ag6 2.565(2) 2_665
S8 P4 1.991(3) 2_665
