Crystallography Open Database

Information card for entry 7211950

7211949 << 7211950 >> 7211951

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Coordinates	7211950.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C24 H19 Au I P
Calculated formula	C24 H19 Au I P
SMILES	c1(c(c2ccccc2)cccc1)[P](c1ccccc1)(c1ccccc1)[Au]I
Title of publication	Can the solid state structures of the dihalogen adducts R3EX2 (E = P, As; R = alkyl, aryl; X = Br, I) with the molecular spoke geometry be considered good mimics of the gold(i) systems [(R3E)AuX] (E = As, P; R = alkyl, aryl; X = Cl, Br, I)?
Authors of publication	Barnes, Nicholas A.; Flower, Kevin R.; Fyyaz, Saad A.; Godfrey, Stephen M.; McGown, Alan T.; Miles, Philip J.; Pritchard, Robin G.; Warren, John E.
Journal of publication	CrystEngComm
Year of publication	2010
Journal volume	12
Journal issue	3
Pages of publication	784
a	9.5207 ± 0.0003 Å
b	9.85 ± 0.0004 Å
c	12.1301 ± 0.0004 Å
α	74.346 ± 0.002°
β	74.294 ± 0.002°
γ	87.987 ± 0.002°
Cell volume	1053.57 ± 0.07 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	5
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0978
Residual factor for significantly intense reflections	0.0656
Weighted residual factors for significantly intense reflections	0.1423
Weighted residual factors for all reflections included in the refinement	0.1643
Goodness-of-fit parameter for all reflections included in the refinement	1.189
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176432 (current)	2016-02-14	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries.	7211950.cif
92500	2014-01-12	cif/ Adding structures of 7211947, 7211948, 7211949, 7211950, 7211951, 7211952 via cif-deposit CGI script.	7211950.cif