#------------------------------------------------------------------------------
#$Date: 2016-09-28 09:33:09 +0300 (Wed, 28 Sep 2016) $
#$Revision: 186820 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/66/7226669.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7226669
loop_
_publ_author_name
'Liu, Xiangyu'
'Cen, Peipei'
'Li, Feifei'
'Ma, Xiaohui'
'Zhou, Huiliang'
'Chen, Xiaoyan'
'Song, Weiming'
'Xie, Gang'
'Chen, Sanping'
_publ_section_title
;
 A unusual two-dimensional azido-Cu(II) network with benzoate derivative
 as coligand exhibiting ferromagnetic order and slow magnetic relaxation
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C6RA20830D
_journal_year                    2016
_chemical_formula_sum            'C32 H16 Cu4 F12 N9 O9'
_chemical_formula_weight         1152.70
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2013-09-28 deposited with the CCDC.
2016-09-27 downloaded from the CCDC.
;
_cell_angle_alpha                91.257(9)
_cell_angle_beta                 90.449(9)
_cell_angle_gamma                98.596(9)
_cell_formula_units_Z            2
_cell_length_a                   8.134(4)
_cell_length_b                   13.499(7)
_cell_length_c                   18.020(9)
_cell_measurement_reflns_used    903
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      20.83
_cell_measurement_theta_min      2.26
_cell_volume                     1955.8(17)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.944
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0611
_diffrn_reflns_av_sigmaI/netI    0.1829
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            11001
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         26.89
_diffrn_reflns_theta_min         1.13
_exptl_absorpt_coefficient_mu    2.269
_exptl_absorpt_correction_T_max  0.728
_exptl_absorpt_correction_T_min  0.586
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.957
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       flakiness
_exptl_crystal_F_000             1134
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.061
_refine_diff_density_min         -1.219
_refine_diff_density_rms         0.250
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.996
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     595
_refine_ls_number_reflns         7970
_refine_ls_number_restraints     10
_refine_ls_restrained_S_all      0.998
_refine_ls_R_factor_all          0.1912
_refine_ls_R_factor_gt           0.0821
_refine_ls_shift/su_max          0.057
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+1.5000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1861
_refine_ls_wR_factor_ref         0.2489
_reflns_number_gt                3451
_reflns_number_total             7970
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6ra20830d2.cif
_cod_data_source_block           xb6799_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 
;
_cod_original_cell_volume        1955.7(17)
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               7226669
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.31099(12) 0.02792(7) 0.49013(6) 0.0327(3) Uani 1 1 d .
Cu2 Cu 0.27495(12) 0.26908(7) 0.47184(6) 0.0354(3) Uani 1 1 d .
Cu3 Cu 0.30975(13) 0.51586(7) 0.44914(6) 0.0406(3) Uani 1 1 d .
O9 O 0.4083(6) 0.1635(4) 0.4709(3) 0.0349(15) Uani 1 1 d .
O5 O 0.1725(7) 0.0635(4) 0.5684(3) 0.0411(16) Uani 1 1 d .
O7 O 0.3241(8) 0.5533(4) 0.5515(3) 0.0514(18) Uani 1 1 d .
N4 N 0.2156(8) -0.1136(5) 0.4978(4) 0.0356(18) Uani 1 1 d .
O1 O 0.4625(7) -0.0047(4) 0.4159(3) 0.0417(16) Uani 1 1 d .
O6 O 0.1848(7) 0.2286(4) 0.5682(3) 0.0432(16) Uani 1 1 d .
O3 O 0.3477(7) 0.2985(4) 0.3734(3) 0.0429(16) Uani 1 1 d .
N1 N 0.1712(8) 0.3908(5) 0.4774(4) 0.0396(19) Uani 1 1 d .
N5 N 0.1018(8) -0.1347(4) 0.5403(4) 0.0367(19) Uani 1 1 d .
N3 N -0.0309(9) 0.4114(6) 0.5682(4) 0.054(2) Uani 1 1 d .
O4 O 0.3317(8) 0.4631(4) 0.3517(3) 0.0477(18) Uani 1 1 d .
C2 C 0.5393(11) -0.0441(6) 0.2957(5) 0.041(2) Uani 1 1 d .
N2 N 0.0697(9) 0.4000(5) 0.5247(4) 0.042(2) Uani 1 1 d .
C9 C 0.3407(10) 0.3740(6) 0.3304(5) 0.038(2) Uani 1 1 d .
N6 N -0.0056(9) -0.1528(5) 0.5795(4) 0.049(2) Uani 1 1 d .
C26 C 0.0536(10) 0.1459(6) 0.6666(5) 0.039(2) Uani 1 1 d .
C17 C 0.2751(10) 0.6258(7) 0.5875(5) 0.046(3) Uani 1 1 d U
C18 C 0.2233(11) 0.6095(6) 0.6644(5) 0.042(2) Uani 1 1 d .
C25 C 0.1422(9) 0.1465(6) 0.5961(4) 0.030(2) Uani 1 1 d .
C24 C 0.2540(13) 0.5266(7) 0.6962(5) 0.059(3) Uani 1 1 d .
H12 H 0.3060 0.4811 0.6690 0.071 Uiso 1 1 calc R
C8 C 0.5971(14) 0.0637(7) 0.2792(5) 0.062(3) Uani 1 1 d .
H4 H 0.5853 0.1145 0.3135 0.074 Uiso 1 1 calc R
C11 C 0.3431(13) 0.2569(8) 0.2211(6) 0.067(3) Uani 1 1 d .
H5 H 0.3269 0.2021 0.2520 0.080 Uiso 1 1 calc R
C19 C 0.1411(12) 0.6763(6) 0.7037(5) 0.050(3) Uani 1 1 d .
H9 H 0.1126 0.7317 0.6796 0.061 Uiso 1 1 calc R
C10 C 0.3516(11) 0.3566(6) 0.2502(5) 0.044(3) Uani 1 1 d .
C20 C 0.1015(13) 0.6636(8) 0.7750(6) 0.067(3) Uani 1 1 d .
H10 H 0.0532 0.7120 0.8009 0.081 Uiso 1 1 calc R
C16 C 0.3575(13) 0.4272(7) 0.2015(5) 0.059(3) Uani 1 1 d .
H8 H 0.3524 0.4918 0.2195 0.070 Uiso 1 1 calc R
O8 O 0.2649(7) 0.7111(4) 0.5575(3) 0.0418(16) Uani 1 1 d U
F9 F 0.0270(12) 0.6248(7) 0.9223(4) 0.141(4) Uani 1 1 d .
F11 F -0.2768(10) 0.0539(7) 0.8919(4) 0.132(3) Uani 1 1 d U
F12 F -0.2847(11) 0.2218(7) 0.8793(5) 0.161(4) Uani 1 1 d .
C15 C 0.3704(13) 0.4145(8) 0.1261(6) 0.066(3) Uani 1 1 d .
H7 H 0.3800 0.4687 0.0946 0.079 Uiso 1 1 calc R
C21 C 0.1332(12) 0.5769(8) 0.8108(6) 0.063(3) Uani 1 1 d .
C23 C 0.2092(13) 0.5054(8) 0.7714(6) 0.073(4) Uani 1 1 d .
H11 H 0.2295 0.4466 0.7933 0.087 Uiso 1 1 calc R
C4 C 0.6429(13) -0.0784(7) 0.1728(5) 0.064(3) Uani 1 1 d .
H2 H 0.6567 -0.1243 0.1350 0.077 Uiso 1 1 calc R
C5 C 0.6910(14) 0.0151(7) 0.1617(6) 0.067(3) Uani 1 1 d .
C27 C 0.0309(13) 0.2340(7) 0.7017(5) 0.062(3) Uani 1 1 d .
H13 H 0.0696 0.2946 0.6797 0.074 Uiso 1 1 calc R
C32 C -0.0067(12) 0.0596(7) 0.6978(5) 0.058(3) Uani 1 1 d .
H16 H 0.0046 -0.0010 0.6743 0.070 Uiso 1 1 calc R
C29 C -0.1055(13) 0.1527(9) 0.7995(6) 0.068(3) Uani 1 1 d .
C28 C -0.0471(14) 0.2341(7) 0.7683(6) 0.069(3) Uani 1 1 d .
H14 H -0.0581 0.2950 0.7915 0.083 Uiso 1 1 calc R
C31 C -0.0836(14) 0.0608(8) 0.7630(7) 0.081(4) Uani 1 1 d .
H15 H -0.1236 0.0005 0.7850 0.097 Uiso 1 1 calc R
C13 C 0.3687(13) 0.3162(9) 0.0983(6) 0.067(3) Uani 1 1 d .
C6 C 0.776(2) 0.0528(12) 0.0886(7) 0.121(6) Uani 1 1 d .
C14 C 0.390(2) 0.3004(11) 0.0162(6) 0.113(5) Uani 1 1 d U
F6 F 0.7998(17) -0.0154(7) 0.0469(5) 0.215(5) Uani 1 1 d .
F1 F 0.449(2) 0.3833(8) -0.0207(4) 0.228(7) Uani 1 1 d U
F5 F 0.9166(15) 0.1016(9) 0.1003(5) 0.222(6) Uani 1 1 d .
F4 F 0.7024(15) 0.1154(8) 0.0578(5) 0.215(5) Uani 1 1 d .
F3 F 0.4573(16) 0.2261(10) 0.0006(5) 0.261(6) Uani 1 1 d U
F2 F 0.2503(15) 0.2714(13) -0.0129(5) 0.287(9) Uani 1 1 d .
C7 C 0.6642(16) 0.0832(7) 0.2153(6) 0.085(4) Uani 1 1 d .
H3 H 0.6974 0.1504 0.2050 0.102 Uiso 1 1 calc R
C12 C 0.3602(17) 0.2443(9) 0.1430(7) 0.094(5) Uani 1 1 d .
H6 H 0.3653 0.1803 0.1238 0.112 Uiso 1 1 calc R
F7 F -0.0244(12) 0.4771(6) 0.8961(5) 0.148(4) Uani 1 1 d .
F8 F 0.2116(12) 0.5304(9) 0.9283(4) 0.174(4) Uani 1 1 d .
C22 C 0.0948(18) 0.5548(12) 0.8898(7) 0.107(5) Uani 1 1 d .
C30 C -0.1826(18) 0.1525(14) 0.8736(7) 0.119(6) Uani 1 1 d U
F10 F -0.0697(11) 0.1657(10) 0.9274(4) 0.189(6) Uani 1 1 d .
Cu4 Cu 0.34112(13) 0.77280(7) 0.46585(6) 0.0372(3) Uani 1 1 d .
N8 N 0.4756(10) 0.6558(5) 0.3590(5) 0.060(2) Uani 1 1 d U
N7 N 0.4216(9) 0.6481(5) 0.4251(4) 0.052(2) Uani 1 1 d .
N9 N 0.5326(14) 0.6628(6) 0.2985(6) 0.095(4) Uani 1 1 d .
O2 O 0.4063(7) -0.1616(4) 0.3738(3) 0.0424(16) Uani 1 1 d .
C1 C 0.4634(11) -0.0725(6) 0.3656(4) 0.037(2) Uani 1 1 d .
C3 C 0.5661(13) -0.1167(8) 0.2434(6) 0.064(3) Uani 1 1 d .
H1 H 0.5381 -0.1848 0.2519 0.077 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Cu1 O1 176.2(2) . .
O5 Cu1 O9 94.9(2) . .
O1 Cu1 O9 83.6(2) . .
O5 Cu1 N4 90.7(2) . .
O1 Cu1 N4 91.0(2) . .
O9 Cu1 N4 173.5(3) . .
O3 Cu2 O9 88.0(2) . .
O3 Cu2 O6 174.4(2) . .
O9 Cu2 O6 91.2(2) . .
O3 Cu2 N1 91.1(3) . .
O9 Cu2 N1 170.9(3) . .
O6 Cu2 N1 90.6(3) . .
O4 Cu3 O7 168.1(3) . .
O4 Cu3 N7 93.5(3) . .
O7 Cu3 N7 89.5(3) . .
O4 Cu3 N1 90.6(3) . .
O7 Cu3 N1 87.7(3) . .
N7 Cu3 N1 172.3(3) . .
Cu2 O9 Cu1 120.7(3) . .
Cu2 O9 Cu4 106.5(2) . 2_666
Cu1 O9 Cu4 117.4(2) . 2_666
C25 O5 Cu1 134.1(5) . .
C17 O7 Cu3 131.8(6) . .
N5 N4 Cu1 117.9(5) . .
N5 N4 Cu4 116.5(5) . 1_545
Cu1 N4 Cu4 122.5(3) . 1_545
C1 O1 Cu1 136.4(5) . .
C25 O6 Cu2 133.1(5) . .
C9 O3 Cu2 133.5(5) . .
N2 N1 Cu2 119.9(5) . .
N2 N1 Cu3 115.1(5) . .
Cu2 N1 Cu3 116.5(3) . .
N6 N5 N4 178.6(8) . .
C9 O4 Cu3 129.6(5) . .
C3 C2 C1 120.4(8) . .
C3 C2 C8 118.6(8) . .
C1 C2 C8 121.0(7) . .
N3 N2 N1 177.2(9) . .
O4 C9 O3 125.8(8) . .
O4 C9 C10 116.4(8) . .
O3 C9 C10 117.7(8) . .
C32 C26 C27 118.7(8) . .
C32 C26 C25 120.5(8) . .
C27 C26 C25 120.8(7) . .
O7 C17 O8 122.2(8) . .
O7 C17 C18 118.1(8) . .
O8 C17 C18 119.6(8) . .
C24 C18 C19 119.6(8) . .
C24 C18 C17 118.1(8) . .
C19 C18 C17 122.3(8) . .
O6 C25 O5 124.4(7) . .
O6 C25 C26 116.9(7) . .
O5 C25 C26 118.7(7) . .
C18 C24 C23 121.7(9) . .
C18 C24 H12 119.2 . .
C23 C24 H12 119.2 . .
C7 C8 C2 117.4(9) . .
C7 C8 H4 121.3 . .
C2 C8 H4 121.3 . .
C10 C11 C12 117.5(9) . .
C10 C11 H5 121.2 . .
C12 C11 H5 121.2 . .
C20 C19 C18 122.1(9) . .
C20 C19 H9 119.0 . .
C18 C19 H9 119.0 . .
C16 C10 C11 116.3(9) . .
C16 C10 C9 123.8(9) . .
C11 C10 C9 119.8(8) . .
C19 C20 C21 119.7(10) . .
C19 C20 H10 120.2 . .
C21 C20 H10 120.2 . .
C10 C16 C15 125.7(10) . .
C10 C16 H8 117.2 . .
C15 C16 H8 117.2 . .
C17 O8 Cu4 134.6(6) . .
C16 C15 C13 117.4(10) . .
C16 C15 H7 121.3 . .
C13 C15 H7 121.3 . .
C23 C21 C20 119.5(10) . .
C23 C21 C22 116.0(11) . .
C20 C21 C22 124.5(11) . .
C21 C23 C24 117.3(10) . .
C21 C23 H11 121.4 . .
C24 C23 H11 121.4 . .
C5 C4 C3 123.1(9) . .
C5 C4 H2 118.4 . .
C3 C4 H2 118.4 . .
C4 C5 C7 118.9(10) . .
C4 C5 C6 122.2(11) . .
C7 C5 C6 119.0(10) . .
C28 C27 C26 121.1(8) . .
C28 C27 H13 119.4 . .
C26 C27 H13 119.4 . .
C26 C32 C31 119.6(10) . .
C26 C32 H16 120.2 . .
C31 C32 H16 120.2 . .
C28 C29 C31 117.7(10) . .
C28 C29 C30 121.6(12) . .
C31 C29 C30 120.6(12) . .
C29 C28 C27 121.5(10) . .
C29 C28 H14 119.3 . .
C27 C28 H14 119.3 . .
C32 C31 C29 121.4(10) . .
C32 C31 H15 119.3 . .
C29 C31 H15 119.3 . .
C12 C13 C15 119.6(10) . .
C12 C13 C14 121.7(12) . .
C15 C13 C14 118.5(10) . .
F6 C6 F4 112.7(13) . .
F6 C6 F5 104.6(14) . .
F4 C6 F5 101.9(14) . .
F6 C6 C5 112.6(13) . .
F4 C6 C5 112.4(13) . .
F5 C6 C5 112.0(12) . .
F3 C14 F2 98.6(13) . .
F3 C14 F1 114.9(14) . .
F2 C14 F1 104.1(14) . .
F3 C14 C13 113.5(12) . .
F2 C14 C13 108.7(13) . .
F1 C14 C13 115.0(11) . .
C8 C7 C5 126.4(10) . .
C8 C7 H3 116.8 . .
C5 C7 H3 116.8 . .
C13 C12 C11 123.2(11) . .
C13 C12 H6 118.4 . .
C11 C12 H6 118.4 . .
F8 C22 F9 111.8(13) . .
F8 C22 F7 103.0(12) . .
F9 C22 F7 100.9(11) . .
F8 C22 C21 116.0(11) . .
F9 C22 C21 112.1(12) . .
F7 C22 C21 111.8(12) . .
F10 C30 F12 110.4(13) . .
F10 C30 F11 101.4(13) . .
F12 C30 F11 108.6(11) . .
F10 C30 C29 111.8(12) . .
F12 C30 C29 111.4(13) . .
F11 C30 C29 112.8(11) . .
O8 Cu4 O2 176.7(3) . 1_565
O8 Cu4 N7 93.7(3) . .
O2 Cu4 N7 88.8(3) 1_565 .
O8 Cu4 N4 85.7(2) . 1_565
O2 Cu4 N4 91.4(3) 1_565 1_565
N7 Cu4 N4 168.6(3) . 1_565
O8 Cu4 O9 87.4(2) . 2_666
O2 Cu4 O9 94.5(2) 1_565 2_666
N7 Cu4 O9 95.5(3) . 2_666
N4 Cu4 O9 95.8(2) 1_565 2_666
N9 N8 N7 177.2(10) . .
N8 N7 Cu3 114.6(5) . .
N8 N7 Cu4 114.1(6) . .
Cu3 N7 Cu4 121.0(4) . .
C1 O2 Cu4 127.4(5) . 1_545
O2 C1 O1 123.8(8) . .
O2 C1 C2 118.1(7) . .
O1 C1 C2 118.1(7) . .
C2 C3 C4 115.6(9) . .
C2 C3 H1 122.2 . .
C4 C3 H1 122.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O5 1.909(5) .
Cu1 O1 1.915(6) .
Cu1 O9 1.923(5) .
Cu1 N4 1.959(6) .
Cu2 O3 1.906(6) .
Cu2 O9 1.916(5) .
Cu2 O6 1.947(6) .
Cu2 N1 1.958(7) .
Cu3 O4 1.899(6) .
Cu3 O7 1.900(6) .
Cu3 N7 1.938(7) .
Cu3 N1 1.964(6) .
O9 Cu4 2.364(5) 2_666
O5 C25 1.275(9) .
O7 C17 1.277(10) .
N4 N5 1.210(9) .
N4 Cu4 2.041(6) 1_545
O1 C1 1.275(9) .
O6 C25 1.230(9) .
O3 C9 1.302(10) .
N1 N2 1.208(9) .
N5 N6 1.130(9) .
N3 N2 1.162(10) .
O4 C9 1.268(10) .
C2 C3 1.387(12) .
C2 C1 1.441(11) .
C2 C8 1.497(12) .
C9 C10 1.464(12) .
C26 C32 1.333(12) .
C26 C27 1.372(12) .
C26 C25 1.464(11) .
C17 O8 1.297(10) .
C17 C18 1.462(12) .
C18 C24 1.324(12) .
C18 C19 1.387(12) .
C24 C23 1.429(14) .
C24 H12 0.9300 .
C8 C7 1.294(13) .
C8 H4 0.9300 .
C11 C10 1.425(12) .
C11 C12 1.425(15) .
C11 H5 0.9300 .
C19 C20 1.336(13) .
C19 H9 0.9300 .
C10 C16 1.306(12) .
C20 C21 1.405(14) .
C20 H10 0.9300 .
C16 C15 1.373(13) .
C16 H8 0.9300 .
O8 Cu4 1.930(5) .
F9 C22 1.294(16) .
F11 C30 1.479(18) .
F12 C30 1.342(19) .
C15 C13 1.406(15) .
C15 H7 0.9300 .
C21 C23 1.404(15) .
C21 C22 1.488(15) .
C23 H11 0.9300 .
C4 C5 1.284(13) .
C4 C3 1.491(13) .
C4 H2 0.9300 .
C5 C7 1.361(14) .
C5 C6 1.552(15) .
C27 C28 1.361(13) .
C27 H13 0.9300 .
C32 C31 1.337(14) .
C32 H16 0.9300 .
C29 C28 1.276(14) .
C29 C31 1.426(15) .
C29 C30 1.479(16) .
C28 H14 0.9300 .
C31 H15 0.9300 .
C13 C12 1.269(15) .
C13 C14 1.504(15) .
C6 F6 1.216(16) .
C6 F4 1.243(18) .
C6 F5 1.246(18) .
C14 F3 1.240(17) .
C14 F2 1.254(17) .
C14 F1 1.343(16) .
C7 H3 0.9300 .
C12 H6 0.9300 .
F7 C22 1.325(16) .
F8 C22 1.259(16) .
C30 F10 1.321(15) .
Cu4 O2 1.937(6) 1_565
Cu4 N7 2.021(7) .
Cu4 N4 2.041(6) 1_565
Cu4 O9 2.364(5) 2_666
N8 N9 1.188(12) .
N8 N7 1.274(11) .
O2 C1 1.235(9) .
O2 Cu4 1.937(6) 1_545
C3 H1 0.9300 .
