#------------------------------------------------------------------------------
#$Date: 2017-03-05 07:00:10 +0200 (Sun, 05 Mar 2017) $
#$Revision: 193763 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/73/7227348.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7227348
loop_
_publ_author_name
'Parra, Nicole'
'Belmar, Julio B.'
'Jiménez, Claudio A.'
'Pasán, Jorge'
'Ruiz-Pérez, Catalina'
_publ_section_title
;
 Crystal structure analysis of supramolecular arrangements in
 bis(1-isoquinolinecarboxamide)alkanes and their Ag(i) complexes
;
_journal_issue                   7
_journal_name_full               CrystEngComm
_journal_page_first              1076
_journal_paper_doi               10.1039/C6CE02393B
_journal_volume                  19
_journal_year                    2017
_chemical_formula_moiety
'2(C24 H22 N4 O2 Ag), 2(Cl O4), (C2 H6 O), 2(H2 O)'
_chemical_formula_sum            'C50 H54 Ag2 Cl2 N8 O15'
_chemical_formula_weight         1293.62
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2016-09-23 deposited with the CCDC.
2017-01-04 downloaded from the CCDC.
;
_cell_angle_alpha                100.674(3)
_cell_angle_beta                 101.046(4)
_cell_angle_gamma                91.916(3)
_cell_formula_units_Z            1
_cell_length_a                   9.2783(3)
_cell_length_b                   11.1478(4)
_cell_length_c                   13.0263(6)
_cell_measurement_reflns_used    6200
_cell_measurement_temperature    175.00(10)
_cell_measurement_theta_max      72.9420
_cell_measurement_theta_min      3.4780
_cell_volume                     1296.18(9)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      175.00(10)
_diffrn_detector_area_resol_mean 10.5953
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.959
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0300
_diffrn_reflns_av_unetI/netI     0.0407
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.959
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            9995
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.959
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         73.708
_diffrn_reflns_theta_min         3.525
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    7.665
_exptl_absorpt_correction_T_max  0.860
_exptl_absorpt_correction_T_min  0.467
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Numerical absorption correction based on gaussian integration over
            a multifaceted crystal model
;
_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    1.652
_exptl_crystal_description       needle
_exptl_crystal_F_000             654
_exptl_crystal_size_max          0.1739
_exptl_crystal_size_mid          0.0749
_exptl_crystal_size_min          0.0362
_refine_diff_density_max         0.471
_refine_diff_density_min         -0.480
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         5033
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0334
_refine_ls_R_factor_gt           0.0297
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0263P)²+1.0319P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0700
_refine_ls_wR_factor_ref         0.0732
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4676
_reflns_number_total             5033
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6ce02393b2.cif
_cod_data_source_block           compound_I4-Ag
_cod_depositor_comments
'Adding full bibliography for 7227343--7227351.cif.'
_cod_database_code               7227348
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2013-4
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.26362(2) 0.55003(2) 0.48839(2) 0.02824(7) Uani 1 1 d . . . . .
C1 C 0.3610(3) 0.3116(2) 0.37153(19) 0.0201(5) Uani 1 1 d . . . . .
C2 C 0.4167(3) 0.4100(2) 0.3200(2) 0.0212(5) Uani 1 1 d . . . . .
C3 C 0.4843(3) 0.3840(2) 0.2298(2) 0.0233(5) Uani 1 1 d . . . . .
C4 C 0.4941(3) 0.2645(3) 0.1720(2) 0.0305(6) Uani 1 1 d . . . . .
H4 H 0.4536 0.1969 0.1917 0.037 Uiso 1 1 calc R U . . .
C5 C 0.5630(4) 0.2491(3) 0.0873(3) 0.0399(7) Uani 1 1 d . . . . .
H5 H 0.5690 0.1706 0.0496 0.048 Uiso 1 1 calc R U . . .
C6 C 0.6252(4) 0.3497(3) 0.0560(3) 0.0404(7) Uani 1 1 d . . . . .
H6 H 0.6740 0.3369 -0.0007 0.049 Uiso 1 1 calc R U . . .
C7 C 0.6146(3) 0.4657(3) 0.1081(3) 0.0368(7) Uani 1 1 d . . . . .
H7 H 0.6553 0.5317 0.0862 0.044 Uiso 1 1 calc R U . . .
C8 C 0.5419(3) 0.4868(3) 0.1953(2) 0.0276(6) Uani 1 1 d . . . . .
C9 C 0.5194(3) 0.6045(3) 0.2463(2) 0.0318(6) Uani 1 1 d . . . . .
H9 H 0.5560 0.6725 0.2249 0.038 Uiso 1 1 calc R U . . .
C10 C 0.4441(3) 0.6195(2) 0.3272(2) 0.0296(6) Uani 1 1 d . . . . .
H10 H 0.4255 0.6982 0.3575 0.036 Uiso 1 1 calc R U . . .
C11 C 0.4038(3) 0.1324(2) 0.4478(2) 0.0234(5) Uani 1 1 d . . . . .
H11A H 0.3169 0.0853 0.4033 0.028 Uiso 1 1 calc R U . . .
H11B H 0.3781 0.1711 0.5143 0.028 Uiso 1 1 calc R U . . .
C12 C 0.5248(3) 0.0476(2) 0.4705(2) 0.0251(5) Uani 1 1 d . . . . .
H12A H 0.6126 0.0947 0.5135 0.030 Uiso 1 1 calc R U . . .
H12B H 0.5486 0.0068 0.4039 0.030 Uiso 1 1 calc R U . . .
C13 C 0.1358(3) 0.7394(2) 0.6508(2) 0.0208(5) Uani 1 1 d . . . . .
C14 C 0.0967(3) 0.6151(2) 0.6750(2) 0.0205(5) Uani 1 1 d . . . . .
C15 C 0.0234(3) 0.5976(2) 0.7576(2) 0.0212(5) Uani 1 1 d . . . . .
C16 C -0.0061(3) 0.6938(3) 0.8376(2) 0.0289(6) Uani 1 1 d . . . . .
H16 H 0.0266 0.7741 0.8394 0.035 Uiso 1 1 calc R U . . .
C17 C -0.0822(4) 0.6686(3) 0.9117(2) 0.0365(7) Uani 1 1 d . . . . .
H17 H -0.1022 0.7322 0.9631 0.044 Uiso 1 1 calc R U . . .
C18 C -0.1309(4) 0.5476(3) 0.9115(2) 0.0387(7) Uani 1 1 d . . . . .
H18 H -0.1851 0.5323 0.9614 0.046 Uiso 1 1 calc R U . . .
C19 C -0.0996(3) 0.4529(3) 0.8391(3) 0.0356(7) Uani 1 1 d . . . . .
H19 H -0.1304 0.3732 0.8409 0.043 Uiso 1 1 calc R U . . .
C20 C -0.0203(3) 0.4750(2) 0.7611(2) 0.0265(5) Uani 1 1 d . . . . .
C21 C 0.0177(3) 0.3795(2) 0.6866(2) 0.0303(6) Uani 1 1 d . . . . .
H21 H -0.0106 0.2987 0.6868 0.036 Uiso 1 1 calc R U . . .
C22 C 0.0963(3) 0.4056(2) 0.6141(2) 0.0299(6) Uani 1 1 d . . . . .
H22 H 0.1252 0.3412 0.5678 0.036 Uiso 1 1 calc R U . . .
C23 C 0.0549(3) 0.9414(2) 0.6316(2) 0.0265(6) Uani 1 1 d . . . . .
H23A H 0.1581 0.9702 0.6503 0.032 Uiso 1 1 calc R U . . .
H23B H 0.0013 0.9995 0.6721 0.032 Uiso 1 1 calc R U . . .
C24 C -0.0012(3) 0.9363(2) 0.5134(2) 0.0249(5) Uani 1 1 d . . . . .
H24A H -0.1010 0.8990 0.4929 0.030 Uiso 1 1 calc R U . . .
H24B H 0.0598 0.8856 0.4730 0.030 Uiso 1 1 calc R U . . .
N1 N 0.4502(2) 0.22644(19) 0.39393(18) 0.0228(4) Uani 1 1 d . . . . .
H1 H 0.5353 0.2262 0.3769 0.027 Uiso 1 1 calc R U . . .
N2 N 0.3950(2) 0.52342(19) 0.36528(18) 0.0232(4) Uani 1 1 d . . . . .
N3 N 0.0380(2) 0.82199(19) 0.66069(18) 0.0236(5) Uani 1 1 d . . . . .
H3 H -0.0384 0.8049 0.6851 0.028 Uiso 1 1 calc R U . . .
N4 N 0.1342(2) 0.52269(19) 0.60717(17) 0.0234(4) Uani 1 1 d . . . . .
O1 O 0.23830(19) 0.31750(17) 0.39610(16) 0.0263(4) Uani 1 1 d . . . . .
O2 O 0.2503(2) 0.75673(17) 0.61889(17) 0.0304(4) Uani 1 1 d . . . . .
Cl1 Cl 0.24968(9) 0.92542(7) 0.18245(6) 0.04236(18) Uani 1 1 d . . . . .
O3 O 0.2343(4) 0.8679(2) 0.2695(2) 0.0701(9) Uani 1 1 d . . . . .
O4 O 0.1871(4) 1.0412(2) 0.1974(2) 0.0617(8) Uani 1 1 d . . . . .
O5 O 0.4008(4) 0.9477(4) 0.1810(4) 0.1015(13) Uani 1 1 d . . . . .
O6 O 0.1783(5) 0.8499(3) 0.0854(3) 0.0840(11) Uani 1 1 d . . . . .
C25 C 0.7692(8) 0.8576(6) 0.1243(5) 0.0400(14) Uani 0.5 1 d D . P A 1
H25A H 0.7483 0.7887 0.0647 0.048 Uiso 0.5 1 calc R U P A 1
H25B H 0.8667 0.8499 0.1646 0.048 Uiso 0.5 1 calc R U P A 1
C26 C 0.774(2) 0.9712(11) 0.0807(15) 0.119(9) Uani 0.5 1 d D . P A 1
H26A H 0.8472 0.9674 0.0374 0.179 Uiso 0.5 1 calc R U P A 1
H26B H 0.7983 1.0405 0.1384 0.179 Uiso 0.5 1 calc R U P A 1
H26C H 0.6794 0.9791 0.0381 0.179 Uiso 0.5 1 calc R U P A 1
O7 O 0.6747(11) 0.8476(9) 0.1856(9) 0.120(4) Uani 0.5 1 d . . P A 1
H7A H 0.5911 0.8516 0.1523 0.180 Uiso 0.5 1 calc R U P A 1
O2W O 0.8601(13) 0.9716(12) 0.0843(10) 0.102(4) Uani 0.5 1 d . . P B 2
O1W O 0.7674(9) 0.7673(7) 0.1537(7) 0.086(2) Uani 0.5 1 d . . P C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N4 164.35(8) . .
O1 C1 N1 122.7(2) . .
O1 C1 C2 119.5(2) . .
N1 C1 C2 117.6(2) . .
N2 C2 C3 122.7(2) . .
N2 C2 C1 114.2(2) . .
C3 C2 C1 123.1(2) . .
C4 C3 C2 124.3(2) . .
C4 C3 C8 119.1(2) . .
C2 C3 C8 116.6(2) . .
C5 C4 C3 119.7(3) . .
C5 C4 H4 120.1 . .
C3 C4 H4 120.1 . .
C4 C5 C6 121.2(3) . .
C4 C5 H5 119.4 . .
C6 C5 H5 119.4 . .
C7 C6 C5 120.5(3) . .
C7 C6 H6 119.7 . .
C5 C6 H6 119.7 . .
C6 C7 C8 120.5(3) . .
C6 C7 H7 119.8 . .
C8 C7 H7 119.8 . .
C9 C8 C7 122.4(3) . .
C9 C8 C3 118.7(3) . .
C7 C8 C3 118.8(3) . .
C10 C9 C8 120.0(2) . .
C10 C9 H9 120.0 . .
C8 C9 H9 120.0 . .
N2 C10 C9 122.4(3) . .
N2 C10 H10 118.8 . .
C9 C10 H10 118.8 . .
N1 C11 C12 111.0(2) . .
N1 C11 H11A 109.4 . .
C12 C11 H11A 109.4 . .
N1 C11 H11B 109.4 . .
C12 C11 H11B 109.4 . .
H11A C11 H11B 108.0 . .
C11 C12 C12 110.0(3) . 2_656
C11 C12 H12A 109.7 . .
C12 C12 H12A 109.7 2_656 .
C11 C12 H12B 109.7 . .
C12 C12 H12B 109.7 2_656 .
H12A C12 H12B 108.2 . .
O2 C13 N3 123.4(2) . .
O2 C13 C14 120.1(2) . .
N3 C13 C14 116.4(2) . .
N4 C14 C15 122.8(2) . .
N4 C14 C13 112.5(2) . .
C15 C14 C13 124.6(2) . .
C14 C15 C20 117.1(2) . .
C14 C15 C16 124.3(2) . .
C20 C15 C16 118.5(2) . .
C17 C16 C15 120.1(3) . .
C17 C16 H16 119.9 . .
C15 C16 H16 119.9 . .
C16 C17 C18 120.8(3) . .
C16 C17 H17 119.6 . .
C18 C17 H17 119.6 . .
C19 C18 C17 120.7(3) . .
C19 C18 H18 119.6 . .
C17 C18 H18 119.6 . .
C18 C19 C20 120.2(3) . .
C18 C19 H19 119.9 . .
C20 C19 H19 119.9 . .
C21 C20 C19 122.0(3) . .
C21 C20 C15 118.6(2) . .
C19 C20 C15 119.4(3) . .
C22 C21 C20 119.7(2) . .
C22 C21 H21 120.1 . .
C20 C21 H21 120.1 . .
C21 C22 N4 122.4(3) . .
C21 C22 H22 118.8 . .
N4 C22 H22 118.8 . .
N3 C23 C24 112.1(2) . .
N3 C23 H23A 109.2 . .
C24 C23 H23A 109.2 . .
N3 C23 H23B 109.2 . .
C24 C23 H23B 109.2 . .
H23A C23 H23B 107.9 . .
C23 C24 C24 111.4(3) . 2_576
C23 C24 H24A 109.4 . .
C24 C24 H24A 109.4 2_576 .
C23 C24 H24B 109.4 . .
C24 C24 H24B 109.4 2_576 .
H24A C24 H24B 108.0 . .
C1 N1 C11 119.7(2) . .
C1 N1 H1 120.2 . .
C11 N1 H1 120.2 . .
C2 N2 C10 119.2(2) . .
C2 N2 Ag1 119.15(16) . .
C10 N2 Ag1 121.35(18) . .
C13 N3 C23 122.4(2) . .
C13 N3 H3 118.8 . .
C23 N3 H3 118.8 . .
C14 N4 C22 119.1(2) . .
C14 N4 Ag1 122.66(17) . .
C22 N4 Ag1 118.15(18) . .
O6 Cl1 O5 109.7(3) . .
O6 Cl1 O3 109.8(2) . .
O5 Cl1 O3 110.4(3) . .
O6 Cl1 O4 110.9(2) . .
O5 Cl1 O4 107.6(2) . .
O3 Cl1 O4 108.44(18) . .
O7 C25 C26 117.5(11) . .
O7 C25 H25A 107.9 . .
C26 C25 H25A 107.9 . .
O7 C25 H25B 107.9 . .
C26 C25 H25B 107.9 . .
H25A C25 H25B 107.2 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C25 O7 H7A 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.178(2) .
Ag1 N4 2.189(2) .
C1 O1 1.241(3) .
C1 N1 1.316(3) .
C1 C2 1.514(3) .
C2 N2 1.332(3) .
C2 C3 1.423(4) .
C3 C4 1.419(4) .
C3 C8 1.429(4) .
C4 C5 1.365(4) .
C4 H4 0.9300 .
C5 C6 1.404(5) .
C5 H5 0.9300 .
C6 C7 1.361(5) .
C6 H6 0.9300 .
C7 C8 1.416(4) .
C7 H7 0.9300 .
C8 C9 1.398(4) .
C9 C10 1.361(4) .
C9 H9 0.9300 .
C10 N2 1.360(3) .
C10 H10 0.9300 .
C11 N1 1.462(3) .
C11 C12 1.512(3) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 C12 1.529(5) 2_656
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 O2 1.235(3) .
C13 N3 1.321(3) .
C13 C14 1.524(3) .
C14 N4 1.330(3) .
C14 C15 1.417(3) .
C15 C20 1.423(4) .
C15 C16 1.424(4) .
C16 C17 1.363(4) .
C16 H16 0.9300 .
C17 C18 1.408(4) .
C17 H17 0.9300 .
C18 C19 1.358(5) .
C18 H18 0.9300 .
C19 C20 1.416(4) .
C19 H19 0.9300 .
C20 C21 1.405(4) .
C21 C22 1.364(4) .
C21 H21 0.9300 .
C22 N4 1.364(3) .
C22 H22 0.9300 .
C23 N3 1.462(3) .
C23 C24 1.517(4) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 C24 1.525(5) 2_576
C24 H24A 0.9700 .
C24 H24B 0.9700 .
N1 H1 0.8600 .
N3 H3 0.8600 .
Cl1 O6 1.412(3) .
Cl1 O5 1.420(4) .
Cl1 O3 1.429(3) .
Cl1 O4 1.429(3) .
C25 O7 1.309(12) .
C25 C26 1.484(12) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
O7 H7A 0.8200 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
O1 C1 C2 N2 44.1(3) .
N1 C1 C2 N2 -132.1(2) .
O1 C1 C2 C3 -135.0(3) .
N1 C1 C2 C3 48.9(4) .
N2 C2 C3 C4 -172.4(3) .
C1 C2 C3 C4 6.5(4) .
N2 C2 C3 C8 5.9(4) .
C1 C2 C3 C8 -175.1(2) .
C2 C3 C4 C5 -179.1(3) .
C8 C3 C4 C5 2.6(4) .
C3 C4 C5 C6 0.1(5) .
C4 C5 C6 C7 -1.8(5) .
C5 C6 C7 C8 0.6(5) .
C6 C7 C8 C9 -175.5(3) .
C6 C7 C8 C3 2.1(5) .
C4 C3 C8 C9 174.0(3) .
C2 C3 C8 C9 -4.4(4) .
C4 C3 C8 C7 -3.6(4) .
C2 C3 C8 C7 177.9(3) .
C7 C8 C9 C10 177.6(3) .
C3 C8 C9 C10 0.0(4) .
C8 C9 C10 N2 3.5(5) .
N1 C11 C12 C12 178.4(3) 2_656
O2 C13 C14 N4 -36.9(4) .
N3 C13 C14 N4 139.6(2) .
O2 C13 C14 C15 145.4(3) .
N3 C13 C14 C15 -38.0(4) .
N4 C14 C15 C20 -4.8(4) .
C13 C14 C15 C20 172.7(2) .
N4 C14 C15 C16 173.9(3) .
C13 C14 C15 C16 -8.7(4) .
C14 C15 C16 C17 177.6(3) .
C20 C15 C16 C17 -3.8(4) .
C15 C16 C17 C18 0.9(5) .
C16 C17 C18 C19 1.8(5) .
C17 C18 C19 C20 -1.5(5) .
C18 C19 C20 C21 178.3(3) .
C18 C19 C20 C15 -1.4(4) .
C14 C15 C20 C21 3.0(4) .
C16 C15 C20 C21 -175.7(3) .
C14 C15 C20 C19 -177.2(3) .
C16 C15 C20 C19 4.0(4) .
C19 C20 C21 C22 -178.9(3) .
C15 C20 C21 C22 0.8(4) .
C20 C21 C22 N4 -3.3(5) .
N3 C23 C24 C24 173.6(3) 2_576
O1 C1 N1 C11 1.4(4) .
C2 C1 N1 C11 177.4(2) .
C12 C11 N1 C1 -177.3(2) .
C3 C2 N2 C10 -2.6(4) .
C1 C2 N2 C10 178.3(2) .
C3 C2 N2 Ag1 171.56(19) .
C1 C2 N2 Ag1 -7.5(3) .
C9 C10 N2 C2 -2.3(4) .
C9 C10 N2 Ag1 -176.3(2) .
O2 C13 N3 C23 1.7(4) .
C14 C13 N3 C23 -174.8(2) .
C24 C23 N3 C13 84.2(3) .
C15 C14 N4 C22 2.5(4) .
C13 C14 N4 C22 -175.3(2) .
C15 C14 N4 Ag1 -174.72(18) .
C13 C14 N4 Ag1 7.6(3) .
C21 C22 N4 C14 1.7(4) .
C21 C22 N4 Ag1 179.1(2) .
