Crystallography Open Database

Information card for entry 7228646

Preview

Coordinates	7228646.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C31 H31 Cl3 F6 N4 Rh Sb
Calculated formula	C31 H31 Cl3 F6 N4 Rh Sb
Title of publication	Syntheses, characterisation, and catalytic role of (η5-C5Me5)Rh(iii) guanidinato complexes in transfer hydrogenation (TH) and TH‒etherification
Authors of publication	Kumar, Robin; Thirupathi, Natesan
Journal of publication	RSC Adv.
Year of publication	2017
Journal volume	7
Journal issue	54
Pages of publication	33890
a	8.556 ± 0.004 Å
b	13.968 ± 0.006 Å
c	15.438 ± 0.007 Å
α	88.234 ± 0.012°
β	82.724 ± 0.016°
γ	86.156 ± 0.014°
Cell volume	1825.6 ± 1.4 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0904
Residual factor for significantly intense reflections	0.0828
Weighted residual factors for significantly intense reflections	0.2107
Weighted residual factors for all reflections included in the refinement	0.2189
Goodness-of-fit parameter for all reflections included in the refinement	1.072
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
198507 (current)	2017-07-06	cif/ Adding structures of 7228643, 7228644, 7228645, 7228646, 7228647, 7228648, 7228649, 7228650, 7228651, 7228652, 7228653 via cif-deposit CGI script.	7228646.cif