#------------------------------------------------------------------------------
#$Date: 2019-08-30 10:12:50 +0300 (Fri, 30 Aug 2019) $
#$Revision: 217872 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/35/7233583.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7233583
loop_
_publ_author_name
'Xiao-Peng Zhang'
'Tao Wu'
'Jian Liu'
'Jing-Xuan Zhang'
'Cheng-Hui Li'
'Xiao-Zeng You'
_publ_section_title
;
 Vapor-induced chiroptical switching in chiral cyclometalated platinum(II)
 complexes with pinene functionalized CNN ligands
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              184
_journal_page_last               194
_journal_paper_doi               10.1039/C3TC31997K
_journal_volume                  2
_journal_year                    2014
_chemical_absolute_configuration unk
_chemical_formula_moiety         'C31 H26 N2 Pt'
_chemical_formula_sum            'C31 H26 N2 Pt'
_chemical_formula_weight         621.63
_space_group_IT_number           19
_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   6.0349(4)
_cell_length_b                   15.7571(11)
_cell_length_c                   25.3332(18)
_cell_measurement_reflns_used    7577
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.825
_cell_measurement_theta_min      2.585
_cell_volume                     2409.0(3)
_computing_cell_refinement       SMART
_computing_data_collection       SMART,(Bruker,2000)
_computing_data_reduction        SAINT(Bruker,2000)
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL(Bruker,2000) '
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker Smart Aepex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0295
_diffrn_reflns_av_sigmaI/netI    0.0378
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            16468
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         1.52
_exptl_absorpt_coefficient_mu    5.847
_exptl_absorpt_correction_T_max  0.4547
_exptl_absorpt_correction_T_min  0.2644
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS;Bruker,2000
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.714
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1216
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.704
_refine_diff_density_min         -0.502
_refine_diff_density_rms         0.062
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.005(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.990
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     309
_refine_ls_number_reflns         5513
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.990
_refine_ls_R_factor_all          0.0248
_refine_ls_R_factor_gt           0.0213
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0425
_refine_ls_wR_factor_ref         0.0435
_reflns_number_gt                5102
_reflns_number_total             5513
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            1000002.cif
_cod_data_source_block           PCOD1000002
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Orthorhombic' was changed
to 'orthorhombic' in accordance with the built-in table derived from
the CIF Core dictionary named 'cif_core.dic' version 2.4.5 last
updated on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      'P2(1)2(1)2(1) '
_cod_database_code               7233583
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8070(7) 0.4686(2) 0.89665(14) 0.0543(9) Uani 1 1 d . . .
C2 C 0.8796(6) 0.4933(2) 0.77992(14) 0.0501(9) Uani 1 1 d . . .
C3 C 0.9945(9) 0.5168(2) 0.90784(17) 0.0641(11) Uani 1 1 d . . .
H3 H 1.0791 0.5378 0.8801 0.077 Uiso 1 1 calc R . .
C4 C 1.0589(9) 0.5344(3) 0.9596(2) 0.0795(15) Uani 1 1 d . . .
H4 H 1.1850 0.5667 0.9661 0.095 Uiso 1 1 calc R . .
C5 C 0.9354(10) 0.5038(3) 1.00083(18) 0.0867(16) Uani 1 1 d . . .
H5 H 0.9786 0.5157 1.0353 0.104 Uiso 1 1 calc R . .
C6 C 0.7489(8) 0.4559(3) 0.99212(17) 0.0767(13) Uani 1 1 d . . .
H6 H 0.6666 0.4361 1.0206 0.092 Uiso 1 1 calc R . .
C7 C 0.6818(7) 0.4368(2) 0.94033(13) 0.0588(9) Uani 1 1 d . . .
C8 C 0.4877(8) 0.3855(2) 0.92788(15) 0.0578(10) Uani 1 1 d . . .
C9 C 0.3364(10) 0.3468(3) 0.96061(17) 0.0725(12) Uani 1 1 d . . .
H9 H 0.3535 0.3503 0.9970 0.087 Uiso 1 1 calc R . .
C10 C 0.1592(10) 0.3028(3) 0.93959(18) 0.0760(13) Uani 1 1 d . . .
H10 H 0.0577 0.2770 0.9621 0.091 Uiso 1 1 calc R . .
C11 C 0.1309(7) 0.2966(2) 0.88588(17) 0.0648(11) Uani 1 1 d . . .
H11 H 0.0104 0.2677 0.8717 0.078 Uiso 1 1 calc R . .
C12 C 0.2860(6) 0.3346(2) 0.85346(15) 0.0524(9) Uani 1 1 d . . .
C13 C 0.2873(6) 0.3345(2) 0.79535(14) 0.0468(8) Uani 1 1 d . . .
C14 C 0.1345(6) 0.2918(2) 0.76454(15) 0.0548(9) Uani 1 1 d . . .
H14 H 0.0189 0.2626 0.7806 0.066 Uiso 1 1 calc R . .
C15 C 0.1514(7) 0.2919(2) 0.71021(16) 0.0517(9) Uani 1 1 d . . .
C16 C 0.3242(7) 0.3392(2) 0.68732(13) 0.0511(8) Uani 1 1 d . . .
C17 C 0.4704(7) 0.3809(2) 0.71989(14) 0.0491(8) Uani 1 1 d . . .
H17 H 0.5846 0.4119 0.7045 0.059 Uiso 1 1 calc R . .
C18 C 0.0016(6) 0.2433(2) 0.67427(18) 0.0664(10) Uani 1 1 d . . .
H18A H -0.1505 0.2607 0.6802 0.080 Uiso 1 1 calc R . .
H18B H 0.0127 0.1832 0.6822 0.080 Uiso 1 1 calc R . .
C19 C 0.0621(8) 0.2581(3) 0.6164(2) 0.0691(13) Uani 1 1 d . . .
H19 H -0.0340 0.2299 0.5907 0.083 Uiso 1 1 calc R . .
C20 C 0.0969(9) 0.3541(3) 0.6076(2) 0.0886(17) Uani 1 1 d . . .
H20A H 0.0066 0.3901 0.6301 0.106 Uiso 1 1 calc R . .
H20B H 0.0890 0.3717 0.5710 0.106 Uiso 1 1 calc R . .
C21 C 0.3377(8) 0.3392(2) 0.62850(14) 0.0602(10) Uani 1 1 d . . .
H21 H 0.4547 0.3739 0.6127 0.072 Uiso 1 1 calc R . .
C22 C 0.3157(8) 0.2457(2) 0.60759(15) 0.0579(9) Uani 1 1 d . . .
C23 C 0.4310(6) 0.1757(2) 0.63690(17) 0.0649(11) Uani 1 1 d . . .
H23A H 0.3858 0.1219 0.6228 0.097 Uiso 1 1 calc R . .
H23B H 0.3926 0.1786 0.6736 0.097 Uiso 1 1 calc R . .
H23C H 0.5884 0.1819 0.6330 0.097 Uiso 1 1 calc R . .
C24 C 0.3758(10) 0.2399(3) 0.54919(17) 0.0946(17) Uani 1 1 d . . .
H24A H 0.5337 0.2437 0.5452 0.142 Uiso 1 1 calc R . .
H24B H 0.3066 0.2857 0.5304 0.142 Uiso 1 1 calc R . .
H24C H 0.3248 0.1867 0.5352 0.142 Uiso 1 1 calc R . .
C25 C 0.9958(7) 0.5268(2) 0.74890(14) 0.0486(8) Uani 1 1 d . . .
C26 C 1.1408(6) 0.5639(2) 0.71003(13) 0.0459(7) Uani 1 1 d . . .
C27 C 1.0796(7) 0.5700(3) 0.65754(14) 0.0622(10) Uani 1 1 d . . .
H27 H 0.9401 0.5516 0.6469 0.075 Uiso 1 1 calc R . .
C28 C 1.2262(10) 0.6034(4) 0.6206(2) 0.0852(17) Uani 1 1 d . . .
H28 H 1.1840 0.6070 0.5854 0.102 Uiso 1 1 calc R . .
C29 C 1.4304(10) 0.6309(3) 0.6355(2) 0.0866(16) Uani 1 1 d . . .
H29 H 1.5272 0.6533 0.6105 0.104 Uiso 1 1 calc R . .
C30 C 1.4920(8) 0.6257(3) 0.6865(2) 0.0781(14) Uani 1 1 d . . .
H30 H 1.6318 0.6446 0.6966 0.094 Uiso 1 1 calc R . .
C31 C 1.3511(8) 0.5928(2) 0.72385(17) 0.0592(10) Uani 1 1 d . . .
H31 H 1.3968 0.5897 0.7589 0.071 Uiso 1 1 calc R . .
N1 N 0.4563(6) 0.37705(18) 0.87515(11) 0.0481(7) Uani 1 1 d . . .
N2 N 0.4565(5) 0.37906(17) 0.77287(11) 0.0453(7) Uani 1 1 d . . .
Pt1 Pt 0.67244(2) 0.434694(7) 0.828055(5) 0.04421(4) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C3 C1 C7 117.6(4) . .
C3 C1 Pt1 131.0(3) . .
C7 C1 Pt1 111.5(3) . .
C25 C2 Pt1 176.3(3) . .
C1 C3 C4 121.8(5) . .
C1 C3 H3 119.1 . .
C4 C3 H3 119.1 . .
C5 C4 C3 119.6(5) . .
C5 C4 H4 120.2 . .
C3 C4 H4 120.2 . .
C4 C5 C6 121.1(4) . .
C4 C5 H5 119.4 . .
C6 C5 H5 119.4 . .
C5 C6 C7 120.3(4) . .
C5 C6 H6 119.9 . .
C7 C6 H6 119.9 . .
C6 C7 C1 119.7(4) . .
C6 C7 C8 123.5(4) . .
C1 C7 C8 116.8(3) . .
N1 C8 C9 117.2(4) . .
N1 C8 C7 112.3(3) . .
C9 C8 C7 130.4(4) . .
C8 C9 C10 120.2(4) . .
C8 C9 H9 119.9 . .
C10 C9 H9 119.9 . .
C11 C10 C9 120.9(4) . .
C11 C10 H10 119.5 . .
C9 C10 H10 119.5 . .
C10 C11 C12 118.3(4) . .
C10 C11 H11 120.9 . .
C12 C11 H11 120.9 . .
N1 C12 C11 119.4(4) . .
N1 C12 C13 113.9(3) . .
C11 C12 C13 126.7(4) . .
N2 C13 C14 120.9(3) . .
N2 C13 C12 114.9(3) . .
C14 C13 C12 124.2(4) . .
C15 C14 C13 120.9(4) . .
C15 C14 H14 119.6 . .
C13 C14 H14 119.6 . .
C14 C15 C16 117.8(3) . .
C14 C15 C18 124.2(4) . .
C16 C15 C18 118.0(3) . .
C17 C16 C15 118.8(3) . .
C17 C16 C21 124.3(4) . .
C15 C16 C21 116.9(3) . .
N2 C17 C16 123.3(3) . .
N2 C17 H17 118.4 . .
C16 C17 H17 118.4 . .
C15 C18 C19 111.2(3) . .
C15 C18 H18A 109.4 . .
C19 C18 H18A 109.4 . .
C15 C18 H18B 109.4 . .
C19 C18 H18B 109.4 . .
H18A C18 H18B 108.0 . .
C18 C19 C20 108.7(4) . .
C18 C19 C22 110.7(4) . .
C20 C19 C22 88.2(4) . .
C18 C19 H19 115.4 . .
C20 C19 H19 115.4 . .
C22 C19 H19 115.4 . .
C19 C20 C21 86.0(3) . .
C19 C20 H20A 114.3 . .
C21 C20 H20A 114.3 . .
C19 C20 H20B 114.3 . .
C21 C20 H20B 114.3 . .
H20A C20 H20B 111.5 . .
C16 C21 C20 106.7(4) . .
C16 C21 C22 109.4(3) . .
C20 C21 C22 87.1(3) . .
C16 C21 H21 116.6 . .
C20 C21 H21 116.6 . .
C22 C21 H21 116.6 . .
C23 C22 C24 109.0(4) . .
C23 C22 C19 118.4(4) . .
C24 C22 C19 112.3(4) . .
C23 C22 C21 118.9(3) . .
C24 C22 C21 111.3(3) . .
C19 C22 C21 85.3(4) . .
C22 C23 H23A 109.5 . .
C22 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C22 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C22 C24 H24A 109.5 . .
C22 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C22 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C2 C25 C26 177.3(4) . .
C27 C26 C31 117.5(4) . .
C27 C26 C25 121.5(3) . .
C31 C26 C25 120.9(3) . .
C26 C27 C28 120.2(4) . .
C26 C27 H27 119.9 . .
C28 C27 H27 119.9 . .
C29 C28 C27 120.7(5) . .
C29 C28 H28 119.6 . .
C27 C28 H28 119.6 . .
C30 C29 C28 119.8(5) . .
C30 C29 H29 120.1 . .
C28 C29 H29 120.1 . .
C29 C30 C31 120.9(5) . .
C29 C30 H30 119.6 . .
C31 C30 H30 119.6 . .
C30 C31 C26 120.9(4) . .
C30 C31 H31 119.5 . .
C26 C31 H31 119.5 . .
C12 N1 C8 124.0(3) . .
C12 N1 Pt1 118.9(2) . .
C8 N1 Pt1 117.1(3) . .
C17 N2 C13 118.3(3) . .
C17 N2 Pt1 128.0(2) . .
C13 N2 Pt1 113.6(2) . .
C2 Pt1 N1 178.23(15) . .
C2 Pt1 C1 98.95(17) . .
N1 Pt1 C1 82.31(15) . .
C2 Pt1 N2 100.16(13) . .
N1 Pt1 N2 78.57(11) . .
C1 Pt1 N2 160.88(15) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C3 1.392(6) .
C1 C7 1.430(5) .
C1 Pt1 1.991(4) .
C2 C25 1.178(5) .
C2 Pt1 1.975(4) .
C3 C4 1.396(6) .
C3 H3 0.9300 .
C4 C5 1.370(7) .
C4 H4 0.9300 .
C5 C6 1.373(7) .
C5 H5 0.9300 .
C6 C7 1.406(5) .
C6 H6 0.9300 .
C7 C8 1.458(6) .
C8 N1 1.356(5) .
C8 C9 1.376(6) .
C9 C10 1.381(7) .
C9 H9 0.9300 .
C10 C11 1.375(6) .
C10 H10 0.9300 .
C11 C12 1.382(5) .
C11 H11 0.9300 .
C12 N1 1.344(5) .
C12 C13 1.472(5) .
C13 N2 1.364(4) .
C13 C14 1.383(5) .
C14 C15 1.380(5) .
C14 H14 0.9300 .
C15 C16 1.407(6) .
C15 C18 1.494(5) .
C16 C17 1.375(5) .
C16 C21 1.492(5) .
C17 N2 1.345(4) .
C17 H17 0.9300 .
C18 C19 1.528(6) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C20 1.544(6) .
C19 C22 1.559(6) .
C19 H19 0.9800 .
C20 C21 1.564(7) .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 C22 1.570(5) .
C21 H21 0.9800 .
C22 C23 1.500(6) .
C22 C24 1.526(6) .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 C26 1.441(5) .
C26 C27 1.383(5) .
C26 C31 1.393(6) .
C27 C28 1.392(6) .
C27 H27 0.9300 .
C28 C29 1.359(7) .
C28 H28 0.9300 .
C29 C30 1.348(7) .
C29 H29 0.9300 .
C30 C31 1.374(6) .
C30 H30 0.9300 .
C31 H31 0.9300 .
N1 Pt1 1.988(3) .
N2 Pt1 2.103(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C7 C1 C3 C4 -0.4(6) . . . .
Pt1 C1 C3 C4 179.0(3) . . . .
C1 C3 C4 C5 -0.1(6) . . . .
C3 C4 C5 C6 0.1(7) . . . .
C4 C5 C6 C7 0.4(7) . . . .
C5 C6 C7 C1 -1.0(6) . . . .
C5 C6 C7 C8 179.2(4) . . . .
C3 C1 C7 C6 0.9(5) . . . .
Pt1 C1 C7 C6 -178.6(3) . . . .
C3 C1 C7 C8 -179.2(3) . . . .
Pt1 C1 C7 C8 1.3(4) . . . .
C6 C7 C8 N1 179.2(4) . . . .
C1 C7 C8 N1 -0.7(5) . . . .
C6 C7 C8 C9 0.0(7) . . . .
C1 C7 C8 C9 -179.8(4) . . . .
N1 C8 C9 C10 -1.1(6) . . . .
C7 C8 C9 C10 178.0(4) . . . .
C8 C9 C10 C11 0.2(7) . . . .
C9 C10 C11 C12 0.9(6) . . . .
C10 C11 C12 N1 -1.0(5) . . . .
C10 C11 C12 C13 179.3(4) . . . .
N1 C12 C13 N2 -1.6(4) . . . .
C11 C12 C13 N2 178.1(3) . . . .
N1 C12 C13 C14 177.0(3) . . . .
C11 C12 C13 C14 -3.2(6) . . . .
N2 C13 C14 C15 1.2(5) . . . .
C12 C13 C14 C15 -177.4(4) . . . .
C13 C14 C15 C16 -2.1(5) . . . .
C13 C14 C15 C18 176.2(4) . . . .
C14 C15 C16 C17 1.6(5) . . . .
C18 C15 C16 C17 -176.8(4) . . . .
C14 C15 C16 C21 -179.3(4) . . . .
C18 C15 C16 C21 2.3(5) . . . .
C15 C16 C17 N2 -0.2(6) . . . .
C21 C16 C17 N2 -179.1(4) . . . .
C14 C15 C18 C19 179.1(4) . . . .
C16 C15 C18 C19 -2.6(5) . . . .
C15 C18 C19 C20 -46.0(5) . . . .
C15 C18 C19 C22 49.2(5) . . . .
C18 C19 C20 C21 83.8(4) . . . .
C22 C19 C20 C21 -27.5(4) . . . .
C17 C16 C21 C20 -135.6(4) . . . .
C15 C16 C21 C20 45.4(4) . . . .
C17 C16 C21 C22 131.6(4) . . . .
C15 C16 C21 C22 -47.4(5) . . . .
C19 C20 C21 C16 -82.1(4) . . . .
C19 C20 C21 C22 27.3(4) . . . .
C18 C19 C22 C23 38.5(5) . . . .
C20 C19 C22 C23 147.8(4) . . . .
C18 C19 C22 C24 167.0(3) . . . .
C20 C19 C22 C24 -83.7(4) . . . .
C18 C19 C22 C21 -81.9(4) . . . .
C20 C19 C22 C21 27.4(3) . . . .
C16 C21 C22 C23 -40.3(6) . . . .
C20 C21 C22 C23 -147.0(4) . . . .
C16 C21 C22 C24 -168.3(4) . . . .
C20 C21 C22 C24 85.1(5) . . . .
C16 C21 C22 C19 79.6(4) . . . .
C20 C21 C22 C19 -27.0(4) . . . .
Pt1 C2 C25 C26 -67(12) . . . .
C2 C25 C26 C27 77(9) . . . .
C2 C25 C26 C31 -101(9) . . . .
C31 C26 C27 C28 0.4(6) . . . .
C25 C26 C27 C28 -177.8(4) . . . .
C26 C27 C28 C29 -0.3(8) . . . .
C27 C28 C29 C30 0.1(9) . . . .
C28 C29 C30 C31 0.1(8) . . . .
C29 C30 C31 C26 0.0(7) . . . .
C27 C26 C31 C30 -0.3(6) . . . .
C25 C26 C31 C30 177.9(4) . . . .
C11 C12 N1 C8 0.1(5) . . . .
C13 C12 N1 C8 179.8(3) . . . .
C11 C12 N1 Pt1 -177.9(3) . . . .
C13 C12 N1 Pt1 1.9(4) . . . .
C9 C8 N1 C12 1.0(5) . . . .
C7 C8 N1 C12 -178.3(3) . . . .
C9 C8 N1 Pt1 179.0(3) . . . .
C7 C8 N1 Pt1 -0.3(4) . . . .
C16 C17 N2 C13 -0.8(5) . . . .
C16 C17 N2 Pt1 177.2(3) . . . .
C14 C13 N2 C17 0.4(5) . . . .
C12 C13 N2 C17 179.1(3) . . . .
C14 C13 N2 Pt1 -178.0(3) . . . .
C12 C13 N2 Pt1 0.7(4) . . . .
C25 C2 Pt1 N1 -40(8) . . . .
C25 C2 Pt1 C1 -175(5) . . . .
C25 C2 Pt1 N2 4(5) . . . .
C12 N1 Pt1 C2 43(4) . . . .
C8 N1 Pt1 C2 -135(4) . . . .
C12 N1 Pt1 C1 178.9(3) . . . .
C8 N1 Pt1 C1 0.8(3) . . . .
C12 N1 Pt1 N2 -1.2(2) . . . .
C8 N1 Pt1 N2 -179.3(3) . . . .
C3 C1 Pt1 C2 -1.8(4) . . . .
C7 C1 Pt1 C2 177.7(3) . . . .
C3 C1 Pt1 N1 179.5(4) . . . .
C7 C1 Pt1 N1 -1.1(3) . . . .
C3 C1 Pt1 N2 179.3(3) . . . .
C7 C1 Pt1 N2 -1.3(6) . . . .
C17 N2 Pt1 C2 3.3(3) . . . .
C13 N2 Pt1 C2 -178.6(2) . . . .
C17 N2 Pt1 N1 -178.0(3) . . . .
C13 N2 Pt1 N1 0.2(2) . . . .
C17 N2 Pt1 C1 -177.8(4) . . . .
C13 N2 Pt1 C1 0.3(5) . . . .
