#------------------------------------------------------------------------------
#$Date: 2019-09-24 10:58:49 +0300 (Tue, 24 Sep 2019) $
#$Revision: 218763 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/40/7234098.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7234098
loop_
_publ_author_name
'Hui Xu'
'Jianzhe Wang'
'Ying Wei'
'Guohua Xie'
'Qin Xue'
'Zhaopeng Deng'
'Wei Huang'
_publ_section_title
;
 A unique white electroluminescent one-dimensional europium(iii)
 coordination polymer
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              1893
_journal_page_last               1903
_journal_paper_doi               10.1039/C4TC02604G
_journal_volume                  3
_journal_year                    2015
_chemical_formula_moiety         'C94 H69 Eu O8 P2'
_chemical_formula_sum            'C94 H69 Eu O8 P2'
_chemical_formula_weight         1540.39
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 113.292(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   52.7880(17)
_cell_length_b                   12.4054(3)
_cell_length_c                   25.0467(8)
_cell_measurement_reflns_used    8917
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.00
_cell_measurement_theta_min      3.09
_cell_volume                     15065.3(9)
_computing_cell_refinement
;
CrysAlis Pro (Agilent, 2013)
;
_computing_data_collection
;
CrysAlis Pro (Agilent, 2013)
;
_computing_data_reduction
;
CrysAlis Pro (Agilent, 2013)
;
_computing_molecular_graphics    '(K. Brandenburg, Diamond 3.1, 2009)'
_computing_publication_material  '(K. Brandenburg, Diamond 3.1, 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 16.1954
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0279
_diffrn_reflns_av_sigmaI/netI    0.0457
_diffrn_reflns_limit_h_max       60
_diffrn_reflns_limit_h_min       -64
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            30650
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         3.06
_exptl_absorpt_coefficient_mu    0.935
_exptl_absorpt_correction_T_max  0.8279
_exptl_absorpt_correction_T_min  0.7668
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
CrysAlis Pro (Agilent, 2013)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm. 
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.358
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             6320
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.21
_refine_diff_density_max         0.811
_refine_diff_density_min         -0.709
_refine_diff_density_rms         0.061
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     946
_refine_ls_number_reflns         14786
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0620
_refine_ls_R_factor_gt           0.0367
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0343P)²+1.3602P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0771
_refine_ls_wR_factor_ref         0.0853
_reflns_number_gt                10649
_reflns_number_total             14786
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            J-Mater-Chem-C-2015-3-1893.cif
_cod_data_source_block           c
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        15065.3(8)
_cod_original_sg_symbol_H-M      'C 2/C'
_cod_database_code               7234098
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.127751(3) 0.754598(10) 0.267004(6) 0.03378(5) Uani 1 1 d . . .
P1 P 0.161894(16) 0.97153(6) 0.21062(4) 0.04081(19) Uani 1 1 d . . .
P2 P 0.141581(16) 0.52292(6) 0.37627(3) 0.03544(18) Uani 1 1 d . . .
O1 O 0.09195(4) 0.88634(15) 0.24073(9) 0.0459(5) Uani 1 1 d . . .
O2 O 0.14281(4) 0.60772(14) 0.33571(8) 0.0430(5) Uani 1 1 d . . .
O3 O 0.08874(4) 0.67523(16) 0.27311(10) 0.0557(6) Uani 1 1 d . . .
O4 O 0.14462(4) 0.88729(16) 0.22178(9) 0.0516(6) Uani 1 1 d . . .
O5 O 0.09918(5) 0.73810(16) 0.16287(10) 0.0545(6) Uani 1 1 d . . .
O6 O 0.17778(4) 0.76741(15) 0.32021(9) 0.0469(5) Uani 1 1 d . . .
O7 O 0.13799(4) 0.86406(16) 0.35020(9) 0.0499(5) Uani 1 1 d . . .
O8 O 0.14506(5) 0.62236(16) 0.22341(9) 0.0515(6) Uani 1 1 d . . .
C1 C 0.17155(10) 1.0516(3) 0.46648(17) 0.0845(13) Uani 1 1 d . . .
H1A H 0.1892 1.0540 0.4665 0.101 Uiso 1 1 calc R . .
C2 C 0.02000(9) 1.1341(3) 0.2016(2) 0.0953(15) Uani 1 1 d . . .
H2A H 0.0071 1.1659 0.2135 0.114 Uiso 1 1 calc R . .
C3 C 0.02620(9) 1.1818(3) 0.15954(19) 0.0806(12) Uani 1 1 d . . .
H3A H 0.0176 1.2457 0.1425 0.097 Uiso 1 1 calc R . .
C4 C 0.22497(8) 0.8181(4) 0.1521(2) 0.0824(13) Uani 1 1 d . . .
H4A H 0.2386 0.7871 0.1422 0.099 Uiso 1 1 calc R . .
C5 C 0.03744(13) 1.4712(4) 0.0918(3) 0.1027(19) Uani 1 1 d . . .
H5A H 0.0263 1.5108 0.1055 0.123 Uiso 1 1 calc R . .
C6 C 0.04413(9) 0.8579(4) 0.0063(2) 0.0904(14) Uani 1 1 d . . .
H6A H 0.0312 0.9093 0.0056 0.108 Uiso 1 1 calc R . .
C7 C 0.06324(8) 0.8190(3) 0.05884(17) 0.0686(10) Uani 1 1 d . . .
H7A H 0.0627 0.8441 0.0934 0.082 Uiso 1 1 calc R . .
C8 C 0.08254(10) 0.7078(4) 0.00906(17) 0.0914(14) Uani 1 1 d . . .
H8A H 0.0956 0.6571 0.0093 0.110 Uiso 1 1 calc R . .
C9 C 0.22398(8) 0.4808(3) 0.43710(18) 0.0772(11) Uani 1 1 d . . .
H9A H 0.2379 0.5020 0.4254 0.093 Uiso 1 1 calc R . .
C10 C 0.18491(10) 0.4871(4) 0.2249(2) 0.1045(17) Uani 1 1 d . . .
H10A H 0.1811 0.4981 0.2577 0.125 Uiso 1 1 calc R . .
C11 C 0.06544(12) 1.4866(3) 0.1168(2) 0.0873(15) Uani 1 1 d . . .
H11A H 0.0730 1.5360 0.1469 0.105 Uiso 1 1 calc R . .
C12 C 0.20972(9) 0.3901(3) 0.50324(18) 0.0891(14) Uani 1 1 d . . .
H12A H 0.2140 0.3483 0.5365 0.107 Uiso 1 1 calc R . .
C13 C 0.27209(9) 0.7839(4) 0.4510(2) 0.0827(13) Uani 1 1 d . . .
H13A H 0.2858 0.8081 0.4855 0.099 Uiso 1 1 calc R . .
C14 C 0.03270(8) 1.0382(3) 0.22722(18) 0.0732(11) Uani 1 1 d . . .
H14A H 0.0280 1.0056 0.2555 0.088 Uiso 1 1 calc R . .
C15 C 0.03223(7) 0.6475(3) 0.31589(16) 0.0673(10) Uani 1 1 d . . .
H15A H 0.0292 0.7195 0.3219 0.081 Uiso 1 1 calc R . .
C16 C 0.22486(9) 1.1011(3) 0.34941(18) 0.0821(12) Uani 1 1 d . . .
H16A H 0.2439 1.0929 0.3678 0.099 Uiso 1 1 calc R . .
C17 C 0.01056(9) 1.2185(5) -0.0562(2) 0.0981(16) Uani 1 1 d . . .
H17A H -0.0058 1.2432 -0.0547 0.118 Uiso 1 1 calc R . .
C18 C 0.21165(11) 1.1714(3) 0.37120(18) 0.0836(13) Uani 1 1 d . . .
H18A H 0.2216 1.2142 0.4031 0.100 Uiso 1 1 calc R . .
C19 C 0.19626(8) 0.9677(3) 0.14987(18) 0.0751(12) Uani 1 1 d . . .
H19A H 0.1901 1.0371 0.1374 0.090 Uiso 1 1 calc R . .
C20 C 0.18282(8) 0.4225(3) 0.47207(15) 0.0701(11) Uani 1 1 d . . .
H20A H 0.1691 0.4033 0.4847 0.084 Uiso 1 1 calc R . .
C21 C 0.08237(9) 1.4278(3) 0.09707(16) 0.0618(10) Uani 1 1 d . . .
H21A H 0.1014 1.4377 0.1138 0.074 Uiso 1 1 calc R . .
C22 C 0.17414(10) 0.5140(3) 0.1260(2) 0.0887(14) Uani 1 1 d . . .
H22A H 0.1628 0.5427 0.0902 0.106 Uiso 1 1 calc R . .
C23 C 0.27868(9) 0.7171(4) 0.4156(2) 0.0854(13) Uani 1 1 d . . .
H23A H 0.2969 0.6957 0.4258 0.103 Uiso 1 1 calc R . .
C24 C 0.08276(8) 0.7448(2) 0.06098(14) 0.0535(9) Uani 1 1 d . . .
C25 C 0.21569(10) 0.9205(4) 0.1335(2) 0.0915(15) Uani 1 1 d . . .
H25A H 0.2225 0.9579 0.1099 0.110 Uiso 1 1 calc R . .
C26 C 0.10925(9) 0.2212(3) 0.3382(2) 0.0746(12) Uani 1 1 d . . .
H26A H 0.1066 0.1617 0.3580 0.090 Uiso 1 1 calc R . .
C27 C 0.25831(8) 0.6808(3) 0.3643(2) 0.0777(12) Uani 1 1 d . . .
H27A H 0.2628 0.6359 0.3396 0.093 Uiso 1 1 calc R . .
C28 C 0.05950(8) 1.1463(3) -0.06187(14) 0.0629(10) Uani 1 1 d . . .
H28A H 0.0757 1.1233 -0.0645 0.075 Uiso 1 1 calc R . .
C29 C 0.15263(8) 0.9776(2) 0.43154(14) 0.0527(8) Uani 1 1 d . . .
C30 C 0.03406(12) 1.1061(3) -0.09921(18) 0.0939(15) Uani 1 1 d . . .
H30A H 0.0332 1.0544 -0.1268 0.113 Uiso 1 1 calc R . .
C31 C 0.24492(7) 0.8161(3) 0.43577(16) 0.0640(10) Uani 1 1 d . . .
H31A H 0.2407 0.8634 0.4599 0.077 Uiso 1 1 calc R . .
C32 C 0.05440(7) 0.8076(3) 0.25444(14) 0.0513(8) Uani 1 1 d . . .
H32A H 0.0371 0.8218 0.2543 0.062 Uiso 1 1 calc R . .
C33 C 0.04495(8) 1.1360(3) 0.14265(16) 0.0681(10) Uani 1 1 d . . .
H33A H 0.0491 1.1678 0.1135 0.082 Uiso 1 1 calc R . .
C34 C 0.16868(9) 1.1168(3) 0.29732(16) 0.0779(12) Uani 1 1 d . . .
H34A H 0.1495 1.1213 0.2809 0.093 Uiso 1 1 calc R . .
C35 C 0.23001(9) 0.4193(3) 0.4853(2) 0.0837(13) Uani 1 1 d . . .
H35A H 0.2481 0.3969 0.5062 0.100 Uiso 1 1 calc R . .
C36 C 0.19489(8) 0.8090(3) 0.20108(17) 0.0645(10) Uani 1 1 d . . .
H36A H 0.1877 0.7700 0.2236 0.077 Uiso 1 1 calc R . .
C37 C 0.04973(6) 0.6209(3) 0.28885(14) 0.0496(8) Uani 1 1 d . . .
C38 C 0.04471(11) 0.8194(5) -0.0443(2) 0.1047(17) Uani 1 1 d . . .
H38A H 0.0321 0.8450 -0.0798 0.126 Uiso 1 1 calc R . .
C39 C 0.04070(9) 0.4338(3) 0.29818(19) 0.0838(13) Uani 1 1 d . . .
H39A H 0.0435 0.3617 0.2921 0.101 Uiso 1 1 calc R . .
C40 C 0.02537(10) 1.4001(4) 0.0477(2) 0.0899(15) Uani 1 1 d . . .
H40A H 0.0063 1.3914 0.0312 0.108 Uiso 1 1 calc R . .
C41 C 0.03571(7) 1.2590(3) -0.01809(17) 0.0613(10) Uani 1 1 d . . .
C42 C 0.12677(9) 0.9786(3) 0.43206(18) 0.0744(12) Uani 1 1 d . . .
H42A H 0.1135 0.9314 0.4080 0.089 Uiso 1 1 calc R . .
C43 C 0.23137(8) 0.7119(3) 0.35036(18) 0.0639(10) Uani 1 1 d . . .
H43A H 0.2177 0.6864 0.3161 0.077 Uiso 1 1 calc R . .
C44 C 0.16835(8) 0.5336(3) 0.17415(16) 0.0577(9) Uani 1 1 d . . .
C45 C 0.14542(7) 0.6048(2) 0.17395(14) 0.0469(8) Uani 1 1 d . . .
C46 C 0.10507(8) 0.3043(3) 0.24966(17) 0.0740(11) Uani 1 1 d . . .
H46A H 0.0996 0.3012 0.2095 0.089 Uiso 1 1 calc R . .
C47 C 0.12116(7) 0.3125(2) 0.36839(15) 0.0543(9) Uani 1 1 d . . .
H47A H 0.1267 0.3146 0.4085 0.065 Uiso 1 1 calc R . .
C48 C 0.12954(7) 1.2391(2) 0.11147(13) 0.0466(8) Uani 1 1 d . . .
H48A H 0.1345 1.3105 0.1095 0.056 Uiso 1 1 calc R . .
C49 C 0.09046(6) 1.4303(2) -0.03810(13) 0.0449(8) Uani 1 1 d . . .
H49A H 0.0753 1.4634 -0.0351 0.054 Uiso 1 1 calc R . .
C50 C 0.05369(7) 0.5136(3) 0.27961(17) 0.0649(10) Uani 1 1 d . . .
H50A H 0.0651 0.4949 0.2608 0.078 Uiso 1 1 calc R . .
C51 C 0.21030(7) 1.0417(3) 0.30033(16) 0.0625(10) Uani 1 1 d . . .
H51A H 0.2198 0.9961 0.2851 0.075 Uiso 1 1 calc R . .
C52 C 0.18576(7) 0.8724(2) 0.40345(14) 0.0538(8) Uani 1 1 d . . .
H52A H 0.1995 0.8990 0.4373 0.065 Uiso 1 1 calc R . .
C53 C 0.22401(7) 0.7793(2) 0.38546(15) 0.0474(8) Uani 1 1 d . . .
C54 C 0.10349(7) 0.7094(3) 0.11944(14) 0.0494(8) Uani 1 1 d . . .
C55 C 0.04240(8) 1.3401(3) 0.02744(17) 0.0607(10) Uani 1 1 d . . .
C56 C 0.19706(7) 0.5119(3) 0.40544(15) 0.0564(9) Uani 1 1 d . . .
H56A H 0.1930 0.5530 0.3720 0.068 Uiso 1 1 calc R . .
C57 C 0.05799(7) 1.0422(2) 0.16841(14) 0.0509(8) Uani 1 1 d . . .
H57A H 0.0711 1.0123 0.1567 0.061 Uiso 1 1 calc R . .
C58 C 0.06544(7) 0.7049(3) 0.27137(14) 0.0477(8) Uani 1 1 d . . .
C59 C 0.05994(7) 1.2212(2) -0.02105(14) 0.0480(8) Uani 1 1 d . . .
C60 C 0.12645(7) 0.6485(3) 0.12263(14) 0.0539(9) Uani 1 1 d . . .
H60A H 0.1291 0.6368 0.0885 0.065 Uiso 1 1 calc R . .
C61 C 0.18593(6) 0.9128(2) 0.18457(13) 0.0440(7) Uani 1 1 d . . .
C62 C 0.12324(7) 1.2888(3) -0.01344(14) 0.0518(9) Uani 1 1 d . . .
H62A H 0.1303 1.2247 0.0060 0.062 Uiso 1 1 calc R . .
C63 C 0.11716(7) 0.3973(3) 0.27979(14) 0.0549(9) Uani 1 1 d . . .
H63A H 0.1199 0.4563 0.2598 0.066 Uiso 1 1 calc R . .
C64 C 0.05216(6) 0.9914(2) 0.21102(13) 0.0396(7) Uani 1 1 d . . .
C65 C 0.10249(6) 1.4768(2) -0.07258(13) 0.0440(7) Uani 1 1 d . . .
C66 C 0.19396(6) 0.8071(2) 0.36790(14) 0.0429(7) Uani 1 1 d . . .
C67 C 0.02367(10) 0.4613(4) 0.3254(2) 0.0962(16) Uani 1 1 d . . .
H67A H 0.0151 0.4077 0.3381 0.115 Uiso 1 1 calc R . .
C69 C 0.10434(6) 1.2018(2) 0.07141(12) 0.0367(7) Uani 1 1 d . . .
C70 C 0.07094(7) 1.3548(2) 0.05253(14) 0.0457(8) Uani 1 1 d . . .
C71 C 0.20723(12) 0.4240(5) 0.2296(3) 0.152(3) Uani 1 1 d . . .
H71A H 0.2180 0.3917 0.2648 0.183 Uiso 1 1 calc R . .
C72 C 0.18214(7) 1.0487(2) 0.27350(13) 0.0442(7) Uani 1 1 d . . .
C73 C 0.10050(6) 1.3355(2) -0.00797(12) 0.0375(7) Uani 1 1 d . . .
C74 C 0.14745(7) 1.1733(2) 0.15408(13) 0.0481(8) Uani 1 1 d . . .
H74A H 0.1641 1.2005 0.1805 0.058 Uiso 1 1 calc R . .
C75 C 0.12505(6) 0.4026(2) 0.33910(12) 0.0392(7) Uani 1 1 d . . .
C77 C 0.15879(7) 0.9006(2) 0.39232(14) 0.0468(8) Uani 1 1 d . . .
C78 C 0.14051(6) 1.0653(2) 0.15741(12) 0.0382(7) Uani 1 1 d . . .
C79 C 0.06758(6) 0.8904(2) 0.23773(12) 0.0392(7) Uani 1 1 d . . .
C80 C 0.11525(6) 1.0283(2) 0.11783(13) 0.0440(7) Uani 1 1 d . . .
H80A H 0.1102 0.9570 0.1198 0.053 Uiso 1 1 calc R . .
C81 C 0.21428(10) 0.7627(3) 0.1846(2) 0.0824(13) Uani 1 1 d . . .
H81A H 0.2201 0.6925 0.1960 0.099 Uiso 1 1 calc R . .
C82 C 0.09755(6) 1.0952(2) 0.07564(13) 0.0420(7) Uani 1 1 d . . .
H82A H 0.0808 1.0684 0.0496 0.050 Uiso 1 1 calc R . .
C83 C 0.08498(6) 1.2784(2) 0.02444(13) 0.0394(7) Uani 1 1 d . . .
C84 C 0.18371(11) 1.1785(4) 0.34581(19) 0.0928(15) Uani 1 1 d . . .
H84A H 0.1745 1.2253 0.3611 0.111 Uiso 1 1 calc R . .
C85 C 0.17627(6) 0.4835(2) 0.42218(12) 0.0393(7) Uani 1 1 d . . .
C86 C 0.21327(12) 0.4099(5) 0.1815(3) 0.135(2) Uani 1 1 d . . .
H86A H 0.2289 0.3712 0.1844 0.162 Uiso 1 1 calc R . .
C87 C 0.19668(14) 0.4517(4) 0.1306(3) 0.123(2) Uani 1 1 d . . .
H87A H 0.2003 0.4389 0.0977 0.148 Uiso 1 1 calc R . .
C88 C 0.01007(11) 1.1421(5) -0.0958(2) 0.112(2) Uani 1 1 d . . .
H88A H -0.0068 1.1138 -0.1209 0.134 Uiso 1 1 calc R . .
C89 C 0.16453(13) 1.1225(4) 0.5017(2) 0.1020(16) Uani 1 1 d . . .
H89A H 0.1774 1.1725 0.5246 0.122 Uiso 1 1 calc R . .
C90 C 0.06345(14) 0.7443(4) -0.0431(2) 0.117(2) Uani 1 1 d . . .
H90A H 0.0634 0.7172 -0.0778 0.140 Uiso 1 1 calc R . .
C91 C 0.10129(9) 0.2170(3) 0.2793(2) 0.0796(12) Uani 1 1 d . . .
H91A H 0.0933 0.1546 0.2591 0.096 Uiso 1 1 calc R . .
C92 C 0.11996(11) 1.0486(3) 0.4678(2) 0.0969(16) Uani 1 1 d . . .
H92A H 0.1024 1.0472 0.4680 0.116 Uiso 1 1 calc R . .
C93 C 0.13910(14) 1.1186(4) 0.5023(2) 0.0974(17) Uani 1 1 d . . .
H93A H 0.1347 1.1645 0.5267 0.117 Uiso 1 1 calc R . .
C94 C 0.01931(9) 0.5673(4) 0.33394(18) 0.0874(13) Uani 1 1 d . . .
H94A H 0.0075 0.5855 0.3520 0.105 Uiso 1 1 calc R . .
H65A H 0.0952 1.5417 -0.0940 0.105 Uiso 1 1 d R . .
H68A H 0.1521 0.6981 0.4498 0.105 Uiso 1 1 d R . .
C68A C 0.13555(7) 0.6643(2) 0.45289(15) 0.0525(9) Uani 1 1 d . . .
C76A C 0.12525(6) 0.5692(2) 0.42286(12) 0.0362(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Eu1 O8 104.52(8) . .
O3 Eu1 O4 146.32(7) . .
O8 Eu1 O4 88.51(8) . .
O3 Eu1 O7 94.85(8) . .
O8 Eu1 O7 144.72(8) . .
O4 Eu1 O7 91.39(7) . .
O3 Eu1 O1 71.63(7) . .
O8 Eu1 O1 139.66(7) . .
O4 Eu1 O1 78.35(7) . .
O7 Eu1 O1 74.32(7) . .
O3 Eu1 O2 71.72(7) . .
O8 Eu1 O2 74.04(7) . .
O4 Eu1 O2 141.90(7) . .
O7 Eu1 O2 84.79(7) . .
O1 Eu1 O2 135.65(7) . .
O3 Eu1 O6 141.18(7) . .
O8 Eu1 O6 76.34(7) . .
O4 Eu1 O6 71.69(7) . .
O7 Eu1 O6 70.21(7) . .
O1 Eu1 O6 132.23(7) . .
O2 Eu1 O6 71.38(7) . .
O3 Eu1 O5 81.22(8) . .
O8 Eu1 O5 68.63(7) . .
O4 Eu1 O5 74.81(7) . .
O7 Eu1 O5 144.68(7) . .
O1 Eu1 O5 71.14(7) . .
O2 Eu1 O5 125.87(7) . .
O6 Eu1 O5 131.46(7) . .
O4 P1 C72 114.07(14) . .
O4 P1 C78 110.10(13) . .
C72 P1 C78 106.75(14) . .
O4 P1 C61 110.99(13) . .
C72 P1 C61 105.95(14) . .
C78 P1 C61 108.73(14) . .
O2 P2 C75 112.30(12) . .
O2 P2 C76A 112.38(12) . .
C75 P2 C76A 110.08(13) . .
O2 P2 C85 108.73(13) . .
C75 P2 C85 105.57(13) . .
C76A P2 C85 107.43(13) . .
C79 O1 Eu1 136.29(18) . .
P2 O2 Eu1 158.91(12) . .
C58 O3 Eu1 137.9(2) . .
P1 O4 Eu1 163.09(14) . .
C54 O5 Eu1 134.7(2) . .
C66 O6 Eu1 136.16(19) . .
C77 O7 Eu1 139.4(2) . .
C45 O8 Eu1 137.3(2) . .
C29 C1 C89 120.8(5) . .
C29 C1 H1A 119.6 . .
C89 C1 H1A 119.6 . .
C3 C2 C14 120.7(4) . .
C3 C2 H2A 119.7 . .
C14 C2 H2A 119.7 . .
C33 C3 C2 119.6(4) . .
C33 C3 H3A 120.2 . .
C2 C3 H3A 120.2 . .
C81 C4 C25 119.8(4) . .
C81 C4 H4A 120.1 . .
C25 C4 H4A 120.1 . .
C40 C5 C11 122.4(5) . .
C40 C5 H5A 118.8 . .
C11 C5 H5A 118.8 . .
C38 C6 C7 118.8(5) . .
C38 C6 H6A 120.6 . .
C7 C6 H6A 120.6 . .
C24 C7 C6 121.7(4) . .
C24 C7 H7A 119.2 . .
C6 C7 H7A 119.2 . .
C24 C8 C90 121.2(5) . .
C24 C8 H8A 119.4 . .
C90 C8 H8A 119.4 . .
C35 C9 C56 119.7(4) . .
C35 C9 H9A 120.2 . .
C56 C9 H9A 120.2 . .
C44 C10 C71 122.3(5) . .
C44 C10 H10A 118.9 . .
C71 C10 H10A 118.9 . .
C5 C11 C21 119.6(5) . .
C5 C11 H11A 120.2 . .
C21 C11 H11A 120.2 . .
C35 C12 C20 120.1(4) . .
C35 C12 H12A 120.0 . .
C20 C12 H12A 120.0 . .
C23 C13 C31 120.0(4) . .
C23 C13 H13A 120.0 . .
C31 C13 H13A 120.0 . .
C64 C14 C2 120.4(3) . .
C64 C14 H14A 119.8 . .
C2 C14 H14A 119.8 . .
C94 C15 C37 120.0(4) . .
C94 C15 H15A 120.0 . .
C37 C15 H15A 120.0 . .
C18 C16 C51 120.6(4) . .
C18 C16 H16A 119.7 . .
C51 C16 H16A 119.7 . .
C88 C17 C41 119.3(5) . .
C88 C17 H17A 120.4 . .
C41 C17 H17A 120.4 . .
C16 C18 C84 119.2(4) . .
C16 C18 H18A 120.4 . .
C84 C18 H18A 120.4 . .
C61 C19 C25 120.4(4) . .
C61 C19 H19A 119.8 . .
C25 C19 H19A 119.8 . .
C85 C20 C12 120.3(4) . .
C85 C20 H20A 119.9 . .
C12 C20 H20A 119.9 . .
C70 C21 C11 119.8(4) . .
C70 C21 H21A 120.1 . .
C11 C21 H21A 120.1 . .
C44 C22 C87 120.4(5) . .
C44 C22 H22A 119.8 . .
C87 C22 H22A 119.8 . .
C13 C23 C27 120.0(4) . .
C13 C23 H23A 120.0 . .
C27 C23 H23A 120.0 . .
C7 C24 C8 117.6(4) . .
C7 C24 C54 118.8(3) . .
C8 C24 C54 123.6(4) . .
C4 C25 C19 120.0(4) . .
C4 C25 H25A 120.0 . .
C19 C25 H25A 120.0 . .
C91 C26 C47 120.4(4) . .
C91 C26 H26A 119.8 . .
C47 C26 H26A 119.8 . .
C43 C27 C23 119.3(4) . .
C43 C27 H27A 120.4 . .
C23 C27 H27A 120.4 . .
C59 C28 C30 118.1(4) . .
C59 C28 H28A 121.0 . .
C30 C28 H28A 121.0 . .
C42 C29 C1 117.5(3) . .
C42 C29 C77 119.2(3) . .
C1 C29 C77 123.3(3) . .
C88 C30 C28 120.6(5) . .
C88 C30 H30A 119.7 . .
C28 C30 H30A 119.7 . .
C53 C31 C13 121.3(4) . .
C53 C31 H31A 119.3 . .
C13 C31 H31A 119.3 . .
C58 C32 C79 124.5(3) . .
C58 C32 H32A 117.8 . .
C79 C32 H32A 117.8 . .
C3 C33 C57 120.2(3) . .
C3 C33 H33A 119.9 . .
C57 C33 H33A 119.9 . .
C72 C34 C84 120.1(4) . .
C72 C34 H34A 120.0 . .
C84 C34 H34A 120.0 . .
C9 C35 C12 120.3(4) . .
C9 C35 H35A 119.8 . .
C12 C35 H35A 119.8 . .
C81 C36 C61 120.7(4) . .
C81 C36 H36A 119.7 . .
C61 C36 H36A 119.7 . .
C50 C37 C15 119.1(3) . .
C50 C37 C58 118.8(3) . .
C15 C37 C58 122.0(3) . .
C90 C38 C6 120.4(5) . .
C90 C38 H38A 119.8 . .
C6 C38 H38A 119.8 . .
C67 C39 C50 120.0(4) . .
C67 C39 H39A 120.0 . .
C50 C39 H39A 120.0 . .
C5 C40 C55 118.4(5) . .
C5 C40 H40A 120.8 . .
C55 C40 H40A 120.8 . .
C17 C41 C59 119.5(4) . .
C17 C41 C55 131.2(4) . .
C59 C41 C55 109.4(3) . .
C29 C42 C92 121.5(4) . .
C29 C42 H42A 119.2 . .
C92 C42 H42A 119.2 . .
C53 C43 C27 122.1(4) . .
C53 C43 H43A 118.9 . .
C27 C43 H43A 118.9 . .
C10 C44 C22 117.5(4) . .
C10 C44 C45 118.4(3) . .
C22 C44 C45 124.1(4) . .
O8 C45 C60 123.7(3) . .
O8 C45 C44 115.0(3) . .
C60 C45 C44 121.3(3) . .
C91 C46 C63 119.8(4) . .
C91 C46 H46A 120.1 . .
C63 C46 H46A 120.1 . .
C26 C47 C75 120.2(3) . .
C26 C47 H47A 119.9 . .
C75 C47 H47A 119.9 . .
C74 C48 C69 121.9(3) . .
C74 C48 H48A 119.0 . .
C69 C48 H48A 119.0 . .
C73 C49 C65 121.6(3) . .
C73 C49 H49A 119.2 . .
C65 C49 H49A 119.2 . .
C39 C50 C37 120.3(4) . .
C39 C50 H50A 119.9 . .
C37 C50 H50A 119.9 . .
C72 C51 C16 121.2(3) . .
C72 C51 H51A 119.4 . .
C16 C51 H51A 119.4 . .
C77 C52 C66 125.0(3) . .
C77 C52 H52A 117.5 . .
C66 C52 H52A 117.5 . .
C43 C53 C31 117.2(3) . .
C43 C53 C66 118.8(3) . .
C31 C53 C66 123.9(3) . .
O5 C54 C60 123.7(3) . .
O5 C54 C24 116.8(3) . .
C60 C54 C24 119.5(3) . .
C70 C55 C40 119.9(4) . .
C70 C55 C41 109.1(3) . .
C40 C55 C41 131.0(4) . .
C85 C56 C9 121.4(3) . .
C85 C56 H56A 119.3 . .
C9 C56 H56A 119.3 . .
C64 C57 C33 121.8(3) . .
C64 C57 H57A 119.1 . .
C33 C57 H57A 119.1 . .
O3 C58 C32 124.0(3) . .
O3 C58 C37 115.4(3) . .
C32 C58 C37 120.6(3) . .
C28 C59 C41 121.4(3) . .
C28 C59 C83 128.4(3) . .
C41 C59 C83 110.1(3) . .
C45 C60 C54 123.6(3) . .
C45 C60 H60A 118.2 . .
C54 C60 H60A 118.2 . .
C19 C61 C36 118.5(3) . .
C19 C61 P1 122.9(3) . .
C36 C61 P1 118.6(2) . .
C68A C62 C73 121.3(3) 6_575 .
C68A C62 H62A 119.3 6_575 .
C73 C62 H62A 119.3 . .
C75 C63 C46 120.3(3) . .
C75 C63 H63A 119.9 . .
C46 C63 H63A 119.9 . .
C57 C64 C14 117.3(3) . .
C57 C64 C79 118.7(3) . .
C14 C64 C79 124.0(3) . .
C76A C65 C49 120.6(3) 6_575 .
C76A C65 H65A 118.2 6_575 .
C49 C65 H65A 121.1 . .
O6 C66 C52 124.5(3) . .
O6 C66 C53 115.3(3) . .
C52 C66 C53 120.2(3) . .
C94 C67 C39 120.1(4) . .
C94 C67 H67A 119.9 . .
C39 C67 H67A 119.9 . .
C82 C69 C48 117.7(3) . .
C82 C69 C83 122.2(3) . .
C48 C69 C83 120.1(2) . .
C21 C70 C55 120.0(3) . .
C21 C70 C83 129.9(3) . .
C55 C70 C83 110.1(3) . .
C86 C71 C10 118.9(6) . .
C86 C71 H71A 120.5 . .
C10 C71 H71A 120.5 . .
C51 C72 C34 118.0(3) . .
C51 C72 P1 123.5(3) . .
C34 C72 P1 118.5(3) . .
C49 C73 C62 117.4(3) . .
C49 C73 C83 120.7(3) . .
C62 C73 C83 121.5(3) . .
C48 C74 C78 119.8(3) . .
C48 C74 H74A 120.1 . .
C78 C74 H74A 120.1 . .
C63 C75 C47 119.0(3) . .
C63 C75 P2 118.5(2) . .
C47 C75 P2 122.4(2) . .
O7 C77 C52 124.1(3) . .
O7 C77 C29 115.7(3) . .
C52 C77 C29 120.2(3) . .
C80 C78 C74 118.3(3) . .
C80 C78 P1 117.4(2) . .
C74 C78 P1 124.2(2) . .
O1 C79 C32 124.8(3) . .
O1 C79 C64 114.9(3) . .
C32 C79 C64 120.2(3) . .
C82 C80 C78 121.1(3) . .
C82 C80 H80A 119.5 . .
C78 C80 H80A 119.5 . .
C4 C81 C36 120.6(4) . .
C4 C81 H81A 119.7 . .
C36 C81 H81A 119.7 . .
C80 C82 C69 121.1(3) . .
C80 C82 H82A 119.4 . .
C69 C82 H82A 119.4 . .
C59 C83 C70 101.3(3) . .
C59 C83 C73 107.7(2) . .
C70 C83 C73 114.4(2) . .
C59 C83 C69 113.4(2) . .
C70 C83 C69 109.0(2) . .
C73 C83 C69 110.9(2) . .
C18 C84 C34 120.9(4) . .
C18 C84 H84A 119.6 . .
C34 C84 H84A 119.6 . .
C56 C85 C20 118.3(3) . .
C56 C85 P2 118.1(2) . .
C20 C85 P2 123.6(3) . .
C87 C86 C71 119.7(5) . .
C87 C86 H86A 120.1 . .
C71 C86 H86A 120.1 . .
C86 C87 C22 121.0(5) . .
C86 C87 H87A 119.5 . .
C22 C87 H87A 119.5 . .
C17 C88 C30 121.1(5) . .
C17 C88 H88A 119.4 . .
C30 C88 H88A 119.4 . .
C93 C89 C1 119.9(5) . .
C93 C89 H89A 120.1 . .
C1 C89 H89A 120.1 . .
C38 C90 C8 120.3(5) . .
C38 C90 H90A 119.9 . .
C8 C90 H90A 119.9 . .
C26 C91 C46 120.4(4) . .
C26 C91 H91A 119.8 . .
C46 C91 H91A 119.8 . .
C93 C92 C42 119.5(5) . .
C93 C92 H92A 120.2 . .
C42 C92 H92A 120.2 . .
C89 C93 C92 120.8(4) . .
C89 C93 H93A 119.6 . .
C92 C93 H93A 119.6 . .
C67 C94 C15 120.5(4) . .
C67 C94 H94A 119.8 . .
C15 C94 H94A 119.8 . .
C62 C68A C76A 120.7(3) 6_576 .
C62 C68A H68A 120.6 6_576 .
C76A C68A H68A 118.7 . .
C65 C76A C68A 118.4(3) 6_576 .
C65 C76A P2 125.5(2) 6_576 .
C68A C76A P2 115.9(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O3 2.341(2) .
Eu1 O8 2.3468(19) .
Eu1 O4 2.3627(18) .
Eu1 O7 2.364(2) .
Eu1 O1 2.3858(19) .
Eu1 O2 2.4148(18) .
Eu1 O6 2.448(2) .
Eu1 O5 2.451(2) .
P1 O4 1.485(2) .
P1 C72 1.791(3) .
P1 C78 1.793(3) .
P1 C61 1.794(3) .
P2 O2 1.4817(18) .
P2 C75 1.793(3) .
P2 C76A 1.797(3) .
P2 C85 1.803(3) .
O1 C79 1.260(3) .
O3 C58 1.268(3) .
O5 C54 1.248(4) .
O6 C66 1.262(4) .
O7 C77 1.268(4) .
O8 C45 1.265(3) .
C1 C29 1.383(5) .
C1 C89 1.395(5) .
C1 H1A 0.9300 .
C2 C3 1.357(5) .
C2 C14 1.392(5) .
C2 H2A 0.9300 .
C3 C33 1.346(5) .
C3 H3A 0.9300 .
C4 C81 1.349(5) .
C4 C25 1.375(5) .
C4 H4A 0.9300 .
C5 C40 1.360(6) .
C5 C11 1.372(7) .
C5 H5A 0.9300 .
C6 C38 1.368(6) .
C6 C7 1.390(5) .
C6 H6A 0.9300 .
C7 C24 1.367(5) .
C7 H7A 0.9300 .
C8 C24 1.375(5) .
C8 C90 1.374(6) .
C8 H8A 0.9300 .
C9 C35 1.354(5) .
C9 C56 1.381(5) .
C9 H9A 0.9300 .
C10 C44 1.354(5) .
C10 C71 1.380(6) .
C10 H10A 0.9300 .
C11 C21 1.388(5) .
C11 H11A 0.9300 .
C12 C35 1.365(5) .
C12 C20 1.382(5) .
C12 H12A 0.9300 .
C13 C23 1.356(6) .
C13 C31 1.389(5) .
C13 H13A 0.9300 .
C14 C64 1.374(4) .
C14 H14A 0.9300 .
C15 C94 1.379(5) .
C15 C37 1.384(4) .
C15 H15A 0.9300 .
C16 C18 1.359(5) .
C16 C51 1.377(5) .
C16 H16A 0.9300 .
C17 C88 1.365(7) .
C17 C41 1.387(6) .
C17 H17A 0.9300 .
C18 C84 1.359(6) .
C18 H18A 0.9300 .
C19 C61 1.375(4) .
C19 C25 1.377(5) .
C19 H19A 0.9300 .
C20 C85 1.382(4) .
C20 H20A 0.9300 .
C21 C70 1.377(4) .
C21 H21A 0.9300 .
C22 C44 1.379(5) .
C22 C87 1.384(6) .
C22 H22A 0.9300 .
C23 C27 1.384(6) .
C23 H23A 0.9300 .
C24 C54 1.506(5) .
C25 H25A 0.9300 .
C26 C91 1.367(6) .
C26 C47 1.369(5) .
C26 H26A 0.9300 .
C27 C43 1.378(5) .
C27 H27A 0.9300 .
C28 C59 1.374(4) .
C28 C30 1.391(5) .
C28 H28A 0.9300 .
C29 C42 1.371(5) .
C29 C77 1.496(4) .
C30 C88 1.377(7) .
C30 H30A 0.9300 .
C31 C53 1.384(5) .
C31 H31A 0.9300 .
C32 C58 1.395(4) .
C32 C79 1.395(4) .
C32 H32A 0.9300 .
C33 C57 1.376(4) .
C33 H33A 0.9300 .
C34 C72 1.382(4) .
C34 C84 1.389(5) .
C34 H34A 0.9300 .
C35 H35A 0.9300 .
C36 C81 1.371(5) .
C36 C61 1.378(4) .
C36 H36A 0.9300 .
C37 C50 1.381(4) .
C37 C58 1.501(4) .
C38 C90 1.350(7) .
C38 H38A 0.9300 .
C39 C67 1.369(6) .
C39 C50 1.385(5) .
C39 H39A 0.9300 .
C40 C55 1.407(5) .
C40 H40A 0.9300 .
C41 C59 1.392(5) .
C41 C55 1.456(5) .
C42 C92 1.393(5) .
C42 H42A 0.9300 .
C43 C53 1.376(5) .
C43 H43A 0.9300 .
C44 C45 1.497(4) .
C45 C60 1.390(4) .
C46 C91 1.371(5) .
C46 C63 1.388(4) .
C46 H46A 0.9300 .
C47 C75 1.396(4) .
C47 H47A 0.9300 .
C48 C74 1.379(4) .
C48 C69 1.391(4) .
C48 H48A 0.9300 .
C49 C73 1.384(4) .
C49 C65 1.384(4) .
C49 H49A 0.9300 .
C50 H50A 0.9300 .
C51 C72 1.371(4) .
C51 H51A 0.9300 .
C52 C77 1.383(4) .
C52 C66 1.393(4) .
C52 H52A 0.9300 .
C53 C66 1.509(4) .
C54 C60 1.403(4) .
C55 C70 1.397(5) .
C56 C85 1.367(4) .
C56 H56A 0.9300 .
C57 C64 1.375(4) .
C57 H57A 0.9300 .
C59 C83 1.536(4) .
C60 H60A 0.9300 .
C62 C68A 1.380(4) 6_575
C62 C73 1.387(4) .
C62 H62A 0.9300 .
C63 C75 1.377(4) .
C63 H63A 0.9300 .
C64 C79 1.499(4) .
C65 C76A 1.375(4) 6_575
C65 H65A 0.9600 .
C67 C94 1.367(6) .
C67 H67A 0.9300 .
C69 C82 1.385(4) .
C69 C83 1.543(4) .
C70 C83 1.535(4) .
C71 C86 1.375(7) .
C71 H71A 0.9300 .
C73 C83 1.535(4) .
C74 C78 1.399(4) .
C74 H74A 0.9300 .
C78 C80 1.388(4) .
C80 C82 1.378(4) .
C80 H80A 0.9300 .
C81 H81A 0.9300 .
C82 H82A 0.9300 .
C84 H84A 0.9300 .
C86 C87 1.334(7) .
C86 H86A 0.9300 .
C87 H87A 0.9300 .
C88 H88A 0.9300 .
C89 C93 1.349(6) .
C89 H89A 0.9300 .
C90 H90A 0.9300 .
C91 H91A 0.9300 .
C92 C93 1.353(6) .
C92 H92A 0.9300 .
C93 H93A 0.9300 .
C94 H94A 0.9300 .
C68A C62 1.380(4) 6_576
C68A C76A 1.389(4) .
C68A H68A 0.9993 .
C76A C65 1.375(4) 6_576
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O3 Eu1 O1 C79 2.3(3) . . . .
O8 Eu1 O1 C79 93.3(3) . . . .
O4 Eu1 O1 C79 166.8(3) . . . .
O7 Eu1 O1 C79 -98.4(3) . . . .
O2 Eu1 O1 C79 -33.4(3) . . . .
O6 Eu1 O1 C79 -141.5(3) . . . .
O5 Eu1 O1 C79 89.1(3) . . . .
C75 P2 O2 Eu1 81.1(3) . . . .
C76A P2 O2 Eu1 -43.6(4) . . . .
C85 P2 O2 Eu1 -162.4(3) . . . .
O3 Eu1 O2 P2 -15.7(3) . . . .
O8 Eu1 O2 P2 -127.4(3) . . . .
O4 Eu1 O2 P2 166.7(3) . . . .
O7 Eu1 O2 P2 81.2(3) . . . .
O1 Eu1 O2 P2 19.9(4) . . . .
O6 Eu1 O2 P2 152.0(3) . . . .
O5 Eu1 O2 P2 -79.8(3) . . . .
O8 Eu1 O3 C58 -148.2(3) . . . .
O4 Eu1 O3 C58 -38.3(4) . . . .
O7 Eu1 O3 C58 61.5(3) . . . .
O1 Eu1 O3 C58 -10.2(3) . . . .
O2 Eu1 O3 C58 144.4(3) . . . .
O6 Eu1 O3 C58 125.6(3) . . . .
O5 Eu1 O3 C58 -83.1(3) . . . .
C72 P1 O4 Eu1 -28.8(5) . . . .
C78 P1 O4 Eu1 -148.8(4) . . . .
C61 P1 O4 Eu1 90.7(5) . . . .
O3 Eu1 O4 P1 146.1(4) . . . .
O8 Eu1 O4 P1 -99.5(5) . . . .
O7 Eu1 O4 P1 45.2(5) . . . .
O1 Eu1 O4 P1 118.9(5) . . . .
O2 Eu1 O4 P1 -38.1(5) . . . .
O6 Eu1 O4 P1 -23.4(4) . . . .
O5 Eu1 O4 P1 -167.7(5) . . . .
O3 Eu1 O5 C54 -136.9(3) . . . .
O8 Eu1 O5 C54 -27.4(3) . . . .
O4 Eu1 O5 C54 67.0(3) . . . .
O7 Eu1 O5 C54 137.2(3) . . . .
O1 Eu1 O5 C54 149.6(3) . . . .
O2 Eu1 O5 C54 -77.1(3) . . . .
O6 Eu1 O5 C54 19.4(3) . . . .
O3 Eu1 O6 C66 -66.1(3) . . . .
O8 Eu1 O6 C66 -162.4(3) . . . .
O4 Eu1 O6 C66 104.6(3) . . . .
O7 Eu1 O6 C66 6.2(3) . . . .
O1 Eu1 O6 C66 50.6(3) . . . .
O2 Eu1 O6 C66 -84.9(3) . . . .
O5 Eu1 O6 C66 153.3(2) . . . .
O3 Eu1 O7 C77 144.3(3) . . . .
O8 Eu1 O7 C77 20.6(4) . . . .
O4 Eu1 O7 C77 -68.8(3) . . . .
O1 Eu1 O7 C77 -146.3(3) . . . .
O2 Eu1 O7 C77 73.2(3) . . . .
O6 Eu1 O7 C77 1.2(3) . . . .
O5 Eu1 O7 C77 -134.0(3) . . . .
O3 Eu1 O8 C45 104.2(3) . . . .
O4 Eu1 O8 C45 -44.3(3) . . . .
O7 Eu1 O8 C45 -134.6(3) . . . .
O1 Eu1 O8 C45 25.6(4) . . . .
O2 Eu1 O8 C45 170.0(3) . . . .
O6 Eu1 O8 C45 -115.8(3) . . . .
O5 Eu1 O8 C45 29.9(3) . . . .
C14 C2 C3 C33 -0.4(7) . . . .
C38 C6 C7 C24 1.0(6) . . . .
C40 C5 C11 C21 -0.2(7) . . . .
C3 C2 C14 C64 1.3(7) . . . .
C51 C16 C18 C84 3.4(7) . . . .
C35 C12 C20 C85 0.8(7) . . . .
C5 C11 C21 C70 0.0(6) . . . .
C31 C13 C23 C27 -0.2(7) . . . .
C6 C7 C24 C8 -1.3(6) . . . .
C6 C7 C24 C54 177.7(3) . . . .
C90 C8 C24 C7 0.2(7) . . . .
C90 C8 C24 C54 -178.8(4) . . . .
C81 C4 C25 C19 2.3(7) . . . .
C61 C19 C25 C4 -0.3(7) . . . .
C13 C23 C27 C43 -1.1(7) . . . .
C89 C1 C29 C42 1.3(6) . . . .
C89 C1 C29 C77 179.1(3) . . . .
C59 C28 C30 C88 1.1(6) . . . .
C23 C13 C31 C53 1.6(6) . . . .
C2 C3 C33 C57 -0.8(6) . . . .
C56 C9 C35 C12 -1.4(7) . . . .
C20 C12 C35 C9 0.5(7) . . . .
C94 C15 C37 C50 0.9(6) . . . .
C94 C15 C37 C58 -176.6(3) . . . .
C7 C6 C38 C90 0.4(8) . . . .
C11 C5 C40 C55 0.3(7) . . . .
C88 C17 C41 C59 0.2(6) . . . .
C88 C17 C41 C55 179.3(4) . . . .
C1 C29 C42 C92 -2.2(6) . . . .
C77 C29 C42 C92 179.9(3) . . . .
C23 C27 C43 C53 0.9(6) . . . .
C71 C10 C44 C22 1.4(7) . . . .
C71 C10 C44 C45 -177.2(5) . . . .
C87 C22 C44 C10 -2.0(7) . . . .
C87 C22 C44 C45 176.4(4) . . . .
Eu1 O8 C45 C60 -22.7(5) . . . .
Eu1 O8 C45 C44 156.4(2) . . . .
C10 C44 C45 O8 5.7(5) . . . .
C22 C44 C45 O8 -172.8(3) . . . .
C10 C44 C45 C60 -175.2(4) . . . .
C22 C44 C45 C60 6.4(5) . . . .
C91 C26 C47 C75 0.6(6) . . . .
C67 C39 C50 C37 0.5(6) . . . .
C15 C37 C50 C39 -1.2(6) . . . .
C58 C37 C50 C39 176.4(3) . . . .
C18 C16 C51 C72 -2.5(6) . . . .
C27 C43 C53 C31 0.5(5) . . . .
C27 C43 C53 C66 -178.4(3) . . . .
C13 C31 C53 C43 -1.8(5) . . . .
C13 C31 C53 C66 177.0(3) . . . .
Eu1 O5 C54 C60 18.5(5) . . . .
Eu1 O5 C54 C24 -160.46(19) . . . .
C7 C24 C54 O5 10.2(4) . . . .
C8 C24 C54 O5 -170.8(4) . . . .
C7 C24 C54 C60 -168.8(3) . . . .
C8 C24 C54 C60 10.2(5) . . . .
C5 C40 C55 C70 -0.3(5) . . . .
C5 C40 C55 C41 179.6(4) . . . .
C17 C41 C55 C70 -178.2(4) . . . .
C59 C41 C55 C70 1.1(4) . . . .
C17 C41 C55 C40 1.9(6) . . . .
C59 C41 C55 C40 -178.9(3) . . . .
C35 C9 C56 C85 1.1(6) . . . .
C3 C33 C57 C64 1.1(6) . . . .
Eu1 O3 C58 C32 11.2(5) . . . .
Eu1 O3 C58 C37 -169.0(2) . . . .
C79 C32 C58 O3 -0.4(5) . . . .
C79 C32 C58 C37 179.8(3) . . . .
C50 C37 C58 O3 -29.3(5) . . . .
C15 C37 C58 O3 148.2(3) . . . .
C50 C37 C58 C32 150.5(3) . . . .
C15 C37 C58 C32 -32.0(5) . . . .
C30 C28 C59 C41 -2.2(5) . . . .
C30 C28 C59 C83 -179.3(3) . . . .
C17 C41 C59 C28 1.6(5) . . . .
C55 C41 C59 C28 -177.7(3) . . . .
C17 C41 C59 C83 179.2(3) . . . .
C55 C41 C59 C83 -0.1(4) . . . .
O8 C45 C60 C54 -5.6(5) . . . .
C44 C45 C60 C54 175.3(3) . . . .
O5 C54 C60 C45 6.5(5) . . . .
C24 C54 C60 C45 -174.6(3) . . . .
C25 C19 C61 C36 -1.8(6) . . . .
C25 C19 C61 P1 176.8(3) . . . .
C81 C36 C61 C19 1.9(6) . . . .
C81 C36 C61 P1 -176.7(3) . . . .
O4 P1 C61 C19 153.2(3) . . . .
C72 P1 C61 C19 -82.5(3) . . . .
C78 P1 C61 C19 31.9(3) . . . .
O4 P1 C61 C36 -28.3(3) . . . .
C72 P1 C61 C36 96.1(3) . . . .
C78 P1 C61 C36 -149.5(3) . . . .
C91 C46 C63 C75 -0.8(6) . . . .
C33 C57 C64 C14 -0.1(5) . . . .
C33 C57 C64 C79 -179.0(3) . . . .
C2 C14 C64 C57 -1.0(5) . . . .
C2 C14 C64 C79 177.7(4) . . . .
C73 C49 C65 C76A -1.1(5) . . . 6_575
Eu1 O6 C66 C52 -8.5(5) . . . .
Eu1 O6 C66 C53 171.54(17) . . . .
C77 C52 C66 O6 1.7(5) . . . .
C77 C52 C66 C53 -178.3(3) . . . .
C43 C53 C66 O6 -2.1(4) . . . .
C31 C53 C66 O6 179.2(3) . . . .
C43 C53 C66 C52 177.9(3) . . . .
C31 C53 C66 C52 -0.8(5) . . . .
C50 C39 C67 C94 0.5(7) . . . .
C74 C48 C69 C82 0.2(5) . . . .
C74 C48 C69 C83 -179.9(3) . . . .
C11 C21 C70 C55 0.0(5) . . . .
C11 C21 C70 C83 -177.8(3) . . . .
C40 C55 C70 C21 0.1(5) . . . .
C41 C55 C70 C21 -179.8(3) . . . .
C40 C55 C70 C83 178.4(3) . . . .
C41 C55 C70 C83 -1.6(3) . . . .
C44 C10 C71 C86 1.6(9) . . . .
C16 C51 C72 C34 -0.3(5) . . . .
C16 C51 C72 P1 -178.5(3) . . . .
C84 C34 C72 C51 2.2(5) . . . .
C84 C34 C72 P1 -179.5(3) . . . .
O4 P1 C72 C51 110.5(3) . . . .
C78 P1 C72 C51 -127.7(3) . . . .
C61 P1 C72 C51 -11.9(3) . . . .
O4 P1 C72 C34 -67.7(3) . . . .
C78 P1 C72 C34 54.1(3) . . . .
C61 P1 C72 C34 169.9(3) . . . .
C65 C49 C73 C62 0.2(4) . . . .
C65 C49 C73 C83 -173.1(3) . . . .
C68A C62 C73 C49 0.7(5) 6_575 . . .
C68A C62 C73 C83 173.9(3) 6_575 . . .
C69 C48 C74 C78 0.6(5) . . . .
C46 C63 C75 C47 1.2(5) . . . .
C46 C63 C75 P2 178.0(3) . . . .
C26 C47 C75 C63 -1.1(5) . . . .
C26 C47 C75 P2 -177.8(3) . . . .
O2 P2 C75 C63 4.3(3) . . . .
C76A P2 C75 C63 130.3(3) . . . .
C85 P2 C75 C63 -114.0(3) . . . .
O2 P2 C75 C47 -179.0(2) . . . .
C76A P2 C75 C47 -53.0(3) . . . .
C85 P2 C75 C47 62.7(3) . . . .
Eu1 O7 C77 C52 -6.0(5) . . . .
Eu1 O7 C77 C29 174.82(19) . . . .
C66 C52 C77 O7 5.2(5) . . . .
C66 C52 C77 C29 -175.7(3) . . . .
C42 C29 C77 O7 20.1(4) . . . .
C1 C29 C77 O7 -157.6(3) . . . .
C42 C29 C77 C52 -159.1(3) . . . .
C1 C29 C77 C52 23.2(5) . . . .
C48 C74 C78 C80 -1.2(4) . . . .
C48 C74 C78 P1 -179.9(2) . . . .
O4 P1 C78 C80 -26.6(3) . . . .
C72 P1 C78 C80 -150.9(2) . . . .
C61 P1 C78 C80 95.2(2) . . . .
O4 P1 C78 C74 152.1(2) . . . .
C72 P1 C78 C74 27.8(3) . . . .
C61 P1 C78 C74 -86.1(3) . . . .
Eu1 O1 C79 C32 4.0(5) . . . .
Eu1 O1 C79 C64 -172.76(18) . . . .
C58 C32 C79 O1 -6.7(5) . . . .
C58 C32 C79 C64 169.9(3) . . . .
C57 C64 C79 O1 32.0(4) . . . .
C14 C64 C79 O1 -146.8(3) . . . .
C57 C64 C79 C32 -144.9(3) . . . .
C14 C64 C79 C32 36.3(5) . . . .
C74 C78 C80 C82 1.0(4) . . . .
P1 C78 C80 C82 179.8(2) . . . .
C25 C4 C81 C36 -2.3(7) . . . .
C61 C36 C81 C4 0.1(7) . . . .
C78 C80 C82 C69 -0.2(5) . . . .
C48 C69 C82 C80 -0.4(4) . . . .
C83 C69 C82 C80 179.7(3) . . . .
C28 C59 C83 C70 176.7(3) . . . .
C41 C59 C83 C70 -0.7(3) . . . .
C28 C59 C83 C73 56.3(4) . . . .
C41 C59 C83 C73 -121.1(3) . . . .
C28 C59 C83 C69 -66.8(4) . . . .
C41 C59 C83 C69 115.9(3) . . . .
C21 C70 C83 C59 179.4(3) . . . .
C55 C70 C83 C59 1.4(3) . . . .
C21 C70 C83 C73 -65.1(4) . . . .
C55 C70 C83 C73 116.9(3) . . . .
C21 C70 C83 C69 59.6(4) . . . .
C55 C70 C83 C69 -118.4(3) . . . .
C49 C73 C83 C59 76.0(3) . . . .
C62 C73 C83 C59 -97.0(3) . . . .
C49 C73 C83 C70 -35.7(4) . . . .
C62 C73 C83 C70 151.3(3) . . . .
C49 C73 C83 C69 -159.4(3) . . . .
C62 C73 C83 C69 27.6(4) . . . .
C82 C69 C83 C59 -7.9(4) . . . .
C48 C69 C83 C59 172.3(3) . . . .
C82 C69 C83 C70 104.1(3) . . . .
C48 C69 C83 C70 -75.7(3) . . . .
C82 C69 C83 C73 -129.2(3) . . . .
C48 C69 C83 C73 51.0(4) . . . .
C16 C18 C84 C34 -1.5(7) . . . .
C72 C34 C84 C18 -1.4(7) . . . .
C9 C56 C85 C20 0.1(5) . . . .
C9 C56 C85 P2 -177.3(3) . . . .
C12 C20 C85 C56 -1.1(5) . . . .
C12 C20 C85 P2 176.2(3) . . . .
O2 P2 C85 C56 -16.1(3) . . . .
C75 P2 C85 C56 104.6(3) . . . .
C76A P2 C85 C56 -138.0(2) . . . .
O2 P2 C85 C20 166.6(3) . . . .
C75 P2 C85 C20 -72.7(3) . . . .
C76A P2 C85 C20 44.7(3) . . . .
C10 C71 C86 C87 -3.9(10) . . . .
C71 C86 C87 C22 3.2(10) . . . .
C44 C22 C87 C86 -0.2(9) . . . .
C41 C17 C88 C30 -1.2(8) . . . .
C28 C30 C88 C17 0.6(8) . . . .
C29 C1 C89 C93 0.7(7) . . . .
C6 C38 C90 C8 -1.5(9) . . . .
C24 C8 C90 C38 1.2(8) . . . .
C47 C26 C91 C46 -0.2(7) . . . .
C63 C46 C91 C26 0.3(7) . . . .
C29 C42 C92 C93 1.1(6) . . . .
C1 C89 C93 C92 -1.9(8) . . . .
C42 C92 C93 C89 1.1(7) . . . .
C39 C67 C94 C15 -0.8(7) . . . .
C37 C15 C94 C67 0.1(6) . . . .
C62 C68A C76A C65 0.1(5) 6_576 . . 6_576
C62 C68A C76A P2 175.3(3) 6_576 . . .
O2 P2 C76A C65 122.8(3) . . . 6_576
C75 P2 C76A C65 -3.2(3) . . . 6_576
C85 P2 C76A C65 -117.7(3) . . . 6_576
O2 P2 C76A C68A -52.0(3) . . . .
C75 P2 C76A C68A -178.0(2) . . . .
C85 P2 C76A C68A 67.6(3) . . . .
