Crystallography Open Database

Information card for entry 7241897

Preview

Coordinates	7241897.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C33 H24 O9 Os3 P2
Calculated formula	C33 H24 O9 Os3 P2
SMILES	[Os]([P](C[P]([OsH]([Os](C#[O])(C#[O])(C#[O])C#[O])(O)(C#[O])C#[O])(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])C#[O]
Title of publication	A new synthetic route for the preparation of [Os3(CO)10(μ-OH)(μ-H)] and its reaction with bis(diphenylphosphino)methane (dppm): syntheses and X-ray structures of two isomers of [Os3(CO)8(μ-OH)(μ-H)(μ-dppm)] and [Os3(CO)7(μ3-CO)(μ3-O)(μ-dppm)]
Authors of publication	Joy, Md. Tuhinur R.; Bhoumik, Nikhil C.; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.
Journal of publication	RSC Advances
Year of publication	2020
Journal volume	10
Journal issue	73
Pages of publication	44699 - 44711
a	12.9006 ± 0.0004 Å
b	11.7117 ± 0.0004 Å
c	23.7556 ± 0.0008 Å
α	90°
β	105.593 ± 0.001°
γ	90°
Cell volume	3457.1 ± 0.2 Å³
Cell temperature	193 ± 1 K
Ambient diffraction temperature	193 ± 1 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.0245
Residual factor for significantly intense reflections	0.0186
Weighted residual factors for significantly intense reflections	0.036
Weighted residual factors for all reflections included in the refinement	0.0376
Goodness-of-fit parameter for all reflections included in the refinement	1.046
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
260015 (current)	2020-12-19	cif/ Adding structures of 7241897, 7241898, 7241899, 7241900, 7241901 via cif-deposit CGI script.	7241897.cif