Crystallography Open Database

Information card for entry 7700201

Preview

Coordinates	7700201.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C75 H59 B Co F24 O P4
Calculated formula	C75 H59 B Co F24 O P4
Title of publication	Direct oxide transfer from an η<sup>2</sup>-keto ligand to generate a cobalt PC<sub>carbene</sub>P(O) pincer complex.
Authors of publication	Sung, Simon; Tinnermann, Hendrik; Krämer, Tobias; Young, Rowan D.
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2019
Journal volume	48
Journal issue	27
Pages of publication	9920 - 9924
a	13.892 ± 0.002 Å
b	14.673 ± 0.002 Å
c	19.142 ± 0.003 Å
α	85.307 ± 0.006°
β	82.481 ± 0.006°
γ	81.765 ± 0.006°
Cell volume	3820.5 ± 1 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	99.96 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.1571
Residual factor for significantly intense reflections	0.0902
Weighted residual factors for significantly intense reflections	0.2192
Weighted residual factors for all reflections included in the refinement	0.2582
Goodness-of-fit parameter for all reflections included in the refinement	1.03
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
223876 (current)	2019-11-07	cif/ Updating files of 7700199, 7700200, 7700201, 7700202 Original log message: Adding full bibliography for 7700199--7700202.cif.	7700201.cif
215769	2019-06-08	cif/ Adding structures of 7700199, 7700200, 7700201, 7700202 via cif-deposit CGI script.	7700201.cif