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Information card for entry 7706434
Preview
| Coordinates | 7706434.cif |
|---|---|
| Original paper (by DOI) | HTML |
| External links | PubChem |
| Formula | C28 H32 Co2 N9 O8 |
|---|---|
| Calculated formula | C28 H32 Co2 N9 O8 |
| SMILES | [Co]1234([O]5[Co]67([O]1c1c(C[NH]4CC(C[NH]3Cc3cccc([O]6C)c53)(C)C)cccc1[O]7C)([O]=C(O2)c1cccc(N(=O)=O)c1)N=N#N)N=N#N |
| Title of publication | Phenoxo-bridged dinuclear mixed valence cobalt(III/II) complexes with reduced Schiff base ligands: synthesis, characterization, band gap measurements and fabrication of Schottky barrier diodes. |
| Authors of publication | Banerjee, Abhisek; Das, Dhananjoy; Ray, Partha Pratim; Banerjee, Snehasis; Chattopadhyay, Shouvik |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2021 |
| Journal volume | 50 |
| Journal issue | 5 |
| Pages of publication | 1721 - 1732 |
| a | 9.2657 ± 0.0007 Å |
| b | 22.2015 ± 0.0016 Å |
| c | 15.3398 ± 0.0011 Å |
| α | 90° |
| β | 97.713 ± 0.002° |
| γ | 90° |
| Cell volume | 3127 ± 0.4 Å3 |
| Cell temperature | 273 ± 2 K |
| Ambient diffraction temperature | 273 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0701 |
| Residual factor for significantly intense reflections | 0.0621 |
| Weighted residual factors for significantly intense reflections | 0.1672 |
| Weighted residual factors for all reflections included in the refinement | 0.1798 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.177 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301878 (current) | 2025-08-23 | Add cross-references to PubChem compounds in COD range 7/70/ Each referenced PubChem compound corresponds to the full crystal structure. |
7706434.cif |
| 262624 | 2021-03-05 | cif/ Updating files of 7706434, 7706435 Original log message: Adding full bibliography for 7706434--7706435.cif. |
7706434.cif |
| 261027 | 2021-01-18 | cif/ Adding structures of 7706434, 7706435 via cif-deposit CGI script. |
7706434.cif |
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