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Information card for entry 7707483
Preview
| Coordinates | 7707483.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C51 H79 Ga N5 Na O7 Si |
|---|---|
| Calculated formula | C51 H79 Ga N5 Na O7 Si |
| SMILES | [Ga]1(O[Si](C)(C)C)(N(C2=C(N1c1c(cccc1C(C)C)C(C)C)c1c3c2cccc3ccc1)c1c(cccc1C(C)C)C(C)C)N=N#N.[Na]123([O](C)CC[O]1C)([O](C)CC[O]2C)[O](C)CC[O]3C |
| Title of publication | Activation and modification of carbon dioxide by redox-active low-valent gallium species. |
| Authors of publication | Dodonov, Vladimir A.; Kushnerova, Olga A.; Baranov, Evgeny V.; Novikov, Alexander S.; Fedushkin, Igor L. |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2021 |
| Journal volume | 50 |
| Journal issue | 25 |
| Pages of publication | 8899 - 8906 |
| a | 12.7877 ± 0.0007 Å |
| b | 18.021 ± 0.0009 Å |
| c | 23.464 ± 0.0013 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 5407.2 ± 0.5 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 19 |
| Hermann-Mauguin space group symbol | P 21 21 21 |
| Hall space group symbol | P 2ac 2ab |
| Residual factor for all reflections | 0.078 |
| Residual factor for significantly intense reflections | 0.0484 |
| Weighted residual factors for significantly intense reflections | 0.0852 |
| Weighted residual factors for all reflections included in the refinement | 0.0945 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.031 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 287906 (current) | 2023-11-30 | cif/7/ (antanas@oposumas) Removed data items that had the '\^A' values from multiple entries. These values convey no meaning and most likely arose due to data corruption. The same values are also present in the original supplementary material data files. |
7707483.cif |
| 267183 | 2021-07-05 | cif/ Updating files of 7707480, 7707481, 7707482, 7707483, 7707484, 7707485, 7707486, 7707487, 7707488, 7707489 Original log message: Adding full bibliography for 7707480--7707489.cif. |
7707483.cif |
| 265520 | 2021-05-27 | cif/ Adding structures of 7707480, 7707481, 7707482, 7707483, 7707484, 7707485, 7707486, 7707487, 7707488, 7707489 via cif-deposit CGI script. |
7707483.cif |
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