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Information card for entry 7708149
Preview
| Coordinates | 7708149.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C39 H34.5 N1.5 O3 P2 |
|---|---|
| Calculated formula | C39 H34.5 N1.5 O3 P2 |
| SMILES | P(=N[P+](c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.O=C([O-])OC.N#CC |
| Title of publication | Heavy silylchalcogenido lanthanates synthesis Ph<sub>4</sub>P[Cp<sub>3</sub>La-ESiMe<sub>3</sub>] (E = S, Se, and Te) <i>via</i> fluoride-induced demethylation of dimethylcarbonate to Ph<sub>4</sub>P[OCO<sub>2</sub>Me] key intermediate. |
| Authors of publication | Guschlbauer, Jannick; Vollgraff, Tobias; Xie, Xiulan; Fetoh, Ahmed; Sundermeyer, Jörg |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2021 |
| Journal volume | 50 |
| Journal issue | 37 |
| Pages of publication | 13103 - 13111 |
| a | 10.62 ± 0.002 Å |
| b | 35.75 ± 0.007 Å |
| c | 17.32 ± 0.003 Å |
| α | 90° |
| β | 97.36 ± 0.03° |
| γ | 90° |
| Cell volume | 6522 ± 2 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0544 |
| Residual factor for significantly intense reflections | 0.0412 |
| Weighted residual factors for significantly intense reflections | 0.0905 |
| Weighted residual factors for all reflections included in the refinement | 0.0961 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.093 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 294865 (current) | 2024-09-24 | cif/7: Fixing Z values and formulae |
7708149.cif |
| 269706 | 2021-10-06 | cif/ Updating files of 7708147, 7708148, 7708149, 7708150, 7708151, 7708152, 7708153, 7708154, 7708155 Original log message: Adding full bibliography for 7708147--7708155.cif. |
7708149.cif |
| 268272 | 2021-08-28 | cif/ Adding structures of 7708147, 7708148, 7708149, 7708150, 7708151, 7708152, 7708153, 7708154, 7708155 via cif-deposit CGI script. |
7708149.cif |
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Users of the data should acknowledge the original authors of the
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