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Information card for entry 7708154
Preview
| Coordinates | 7708154.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C42 H44 La P S Si |
|---|---|
| Calculated formula | C42 H44 La P S Si |
| SMILES | [La]123456789%10%11%12([cH]%13[cH]%10[cH]%11[cH]1[cH]2%13)([cH]1[cH]3[cH]4[cH]5[cH]61)[cH]1[cH]7[cH]8[cH]9[cH]1%12.[S-][Si](C)(C)C.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1 |
| Title of publication | Heavy silylchalcogenido lanthanates synthesis Ph<sub>4</sub>P[Cp<sub>3</sub>La-ESiMe<sub>3</sub>] (E = S, Se, and Te) <i>via</i> fluoride-induced demethylation of dimethylcarbonate to Ph<sub>4</sub>P[OCO<sub>2</sub>Me] key intermediate. |
| Authors of publication | Guschlbauer, Jannick; Vollgraff, Tobias; Xie, Xiulan; Fetoh, Ahmed; Sundermeyer, Jörg |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2021 |
| Journal volume | 50 |
| Journal issue | 37 |
| Pages of publication | 13103 - 13111 |
| a | 14.343 ± 0.003 Å |
| b | 15.449 ± 0.003 Å |
| c | 16.998 ± 0.003 Å |
| α | 90° |
| β | 100.44 ± 0.03° |
| γ | 90° |
| Cell volume | 3704.1 ± 1.3 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0273 |
| Residual factor for significantly intense reflections | 0.0208 |
| Weighted residual factors for significantly intense reflections | 0.0448 |
| Weighted residual factors for all reflections included in the refinement | 0.0466 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.063 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 269706 (current) | 2021-10-06 | cif/ Updating files of 7708147, 7708148, 7708149, 7708150, 7708151, 7708152, 7708153, 7708154, 7708155 Original log message: Adding full bibliography for 7708147--7708155.cif. |
7708154.cif |
| 268272 | 2021-08-28 | cif/ Adding structures of 7708147, 7708148, 7708149, 7708150, 7708151, 7708152, 7708153, 7708154, 7708155 via cif-deposit CGI script. |
7708154.cif |
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