Crystallography Open Database

Information card for entry 7709318

Preview

Coordinates	7709318.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	tBu-PBP-Pt-SH
Formula	C24 H45 B N2 P2 Pt S
Calculated formula	C24 H45 B N2 P2 Pt S
SMILES	[Pt]12([P](C(C)(C)C)(C(C)(C)C)CN3B2N(C[P]1(C(C)(C)C)C(C)(C)C)c1c3cccc1)S
Title of publication	Platinum thiolate complexes supported by PBP and POCOP pincer ligands as efficient catalysts for the hydrosilylation of carbonyl compounds
Authors of publication	Xue, Man-Man; Chang, Jiarui; Zhang, Jie; Chen, Xuenian
Journal of publication	Dalton Transactions
Year of publication	2022
a	12.0127 ± 0.0001 Å
b	14.4319 ± 0.0002 Å
c	32.144 ± 0.0005 Å
α	90°
β	90°
γ	90°
Cell volume	5572.68 ± 0.13 Å³
Cell temperature	150 ± 0.3 K
Ambient diffraction temperature	150 ± 0.3 K
Number of distinct elements	7
Space group number	61
Hermann-Mauguin space group symbol	P b c a
Hall space group symbol	-P 2ac 2ab
Residual factor for all reflections	0.0597
Residual factor for significantly intense reflections	0.0416
Weighted residual factors for significantly intense reflections	0.108
Weighted residual factors for all reflections included in the refinement	0.1174
Goodness-of-fit parameter for all reflections included in the refinement	1.088
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
272117 (current)	2022-01-19	cif/ Adding structures of 7709318, 7709319, 7709320, 7709321 via cif-deposit CGI script.	7709318.cif