Crystallography Open Database

Information card for entry 7709336

Preview

Coordinates	7709336.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	Bis(triphenylsilyl)phosphanide sodium(18-crown-6)(1,2-dimethoxyethane)1/2 salt
Formula	C50 H59 Na O7 P Si2
Calculated formula	C50 H59 Na O7 P Si2
Title of publication	Simple conversion of trisodium phosphide, Na3P, into silyl- and cyanophosphides and structure of a terminal silver phosphide
Authors of publication	Grützmacher, Hansjörg; Le Corre, Grégoire
Journal of publication	Dalton Transactions
Year of publication	2022
a	12.2084 ± 0.0003 Å
b	12.5732 ± 0.0004 Å
c	16.8295 ± 0.0005 Å
α	98.695 ± 0.002°
β	107.907 ± 0.002°
γ	101.613 ± 0.002°
Cell volume	2344.09 ± 0.13 Å³
Cell temperature	100.01 ± 0.15 K
Ambient diffraction temperature	100 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0564
Residual factor for significantly intense reflections	0.0393
Weighted residual factors for significantly intense reflections	0.0861
Weighted residual factors for all reflections included in the refinement	0.0938
Goodness-of-fit parameter for all reflections included in the refinement	1.018
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
272145 (current)	2022-01-20	cif/ Adding structures of 7709334, 7709335, 7709336, 7709337, 7709338, 7709339, 7709340 via cif-deposit CGI script.	7709336.cif