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Information card for entry 7711431
Preview
| Coordinates | 7711431.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C31 H44 F3 Ir N3 O7 S Si |
|---|---|
| Calculated formula | C31 H44 F3 Ir N3 O7 S Si |
| Title of publication | Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes. |
| Authors of publication | Iizuka, Kosuke; Nakajima, Yumiko; Sato, Kazuhiko |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2022 |
| Journal volume | 51 |
| Journal issue | 34 |
| Pages of publication | 12781 - 12785 |
| a | 11.3688 ± 0.0003 Å |
| b | 11.7329 ± 0.0003 Å |
| c | 15.0057 ± 0.0003 Å |
| α | 104.111 ± 0.002° |
| β | 91.708 ± 0.002° |
| γ | 113.962 ± 0.002° |
| Cell volume | 1755.06 ± 0.08 Å3 |
| Cell temperature | 100 ± 1 K |
| Ambient diffraction temperature | 100 ± 1 K |
| Number of distinct elements | 8 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0641 |
| Residual factor for significantly intense reflections | 0.047 |
| Weighted residual factors for significantly intense reflections | 0.1043 |
| Weighted residual factors for all reflections included in the refinement | 0.1102 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.026 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 1.54184 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 278364 (current) | 2022-10-05 | cif/ Adding structures of 7711430, 7711431 via cif-deposit CGI script. |
7711431.cif |
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Users of the data should acknowledge the original authors of the
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