Crystallography Open Database

Information card for entry 7711807

Preview

Coordinates	7711807.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C33 H42 O4 Si W
Calculated formula	C33 H42 O4 Si W
SMILES	[W]123456(O[Si](O[C]2(=[CH2]1)C)(c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C)(C#[O])(C#[O])[c]1([c]3([c]4([c]5([c]61C)C)C)C)C
Title of publication	Synthesis and structure of a pyridine-stabilized silanone molybdenum complex and its reactions with PMe3 and acetone
Authors of publication	Muraoka, Takako; Suzuki, Yuzuki; Tsuchimoto, Masato; Trigagema, Gama; Ueno, Keiji; Koyama, Shinji
Journal of publication	Dalton Transactions
Year of publication	2022
a	11.3269 ± 0.0017 Å
b	20.581 ± 0.003 Å
c	13.585 ± 0.002 Å
α	90°
β	105.485 ± 0.004°
γ	90°
Cell volume	3052 ± 0.8 Å³
Cell temperature	120 ± 2 K
Ambient diffraction temperature	120 ± 2 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.028
Residual factor for significantly intense reflections	0.0232
Weighted residual factors for significantly intense reflections	0.0559
Weighted residual factors for all reflections included in the refinement	0.0579
Goodness-of-fit parameter for all reflections included in the refinement	1.043
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
279408 (current)	2022-11-19	cif/ Adding structures of 7711806, 7711807, 7711808, 7711809 via cif-deposit CGI script.	7711807.cif