Crystallography Open Database

Information card for entry 7715205

Preview

Coordinates	7715205.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C126 H120 O12 P8 Rh2
Calculated formula	C126 H120 O12 P8 Rh2
Title of publication	The case of a μ<sub>2</sub>-P aromatic phosphinine as a 4-electron donor forming σ- and π-three-center-two-electron bonds.
Authors of publication	Zhang, Jie; Hou, Yuanfeng; Liu, Shihua; Lin, Jieli; Li, Zhongshu
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2024
Journal volume	53
Journal issue	12
Pages of publication	5608 - 5615
a	15.8711 ± 0.0001 Å
b	33.0914 ± 0.0003 Å
c	21.7367 ± 0.0002 Å
α	90°
β	109.992 ± 0.001°
γ	90°
Cell volume	10728.1 ± 0.17 Å³
Cell temperature	149.99 ± 0.1 K
Ambient diffraction temperature	149.99 ± 0.1 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0743
Residual factor for significantly intense reflections	0.0632
Weighted residual factors for significantly intense reflections	0.161
Weighted residual factors for all reflections included in the refinement	0.1674
Goodness-of-fit parameter for all reflections included in the refinement	1.064
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
290993 (current)	2024-04-05	cif/ Updating files of 7715202, 7715203, 7715204, 7715205 Original log message: Adding full bibliography for 7715202--7715205.cif.	7715205.cif
289918	2024-02-22	cif/ Adding structures of 7715202, 7715203, 7715204, 7715205 via cif-deposit CGI script.	7715205.cif