Crystallography Open Database

Information card for entry 7715239

Preview

Coordinates	7715239.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C40 H58 Cl2 Ga2 N4
Calculated formula	C40 H58 Cl2 Ga2 N4
Title of publication	Metal-metal cooperativity boosts Lewis basicity and reduction properties of the bis(gallanediyl) <sup>Cy</sup>L<sub>2</sub>Ga<sub>2</sub>.
Authors of publication	Helling, Christoph; Döhler, Lotta; Kysliak, Oleksandr; Görls, Helmar; Liebing, Phil; Wölper, Christoph; Kretschmer, Robert; Schulz, Stephan
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2024
Journal volume	53
Journal issue	11
Pages of publication	4922 - 4929
a	8.818 ± 0.0009 Å
b	14.0432 ± 0.0015 Å
c	16.3175 ± 0.0018 Å
α	88.348 ± 0.004°
β	82.154 ± 0.004°
γ	79.18 ± 0.004°
Cell volume	1966.1 ± 0.4 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	5
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0323
Residual factor for significantly intense reflections	0.0248
Weighted residual factors for significantly intense reflections	0.0604
Weighted residual factors for all reflections included in the refinement	0.0631
Goodness-of-fit parameter for all reflections included in the refinement	1.026
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
290976 (current)	2024-04-05	cif/ Updating files of 7715237, 7715238, 7715239, 7715240, 7715241, 7715242 Original log message: Adding full bibliography for 7715237--7715242.cif.	7715239.cif
289949	2024-02-24	cif/ Adding structures of 7715237, 7715238, 7715239, 7715240, 7715241, 7715242 via cif-deposit CGI script.	7715239.cif