#------------------------------------------------------------------------------
#$Date: 2016-02-18 14:25:00 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176728 $
#$URL: svn://www.crystallography.net/cod/cif/8/10/19/8101973.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8101973
loop_
_publ_author_name
'Warad, I.'
'Al-Resayes, S.'
'Eichele, K.'
_publ_section_title
;
Crystal structure of trans-dichloro-1,3-propanediamine-bis[(2-methoxyethyl)
diphenylphosphine]ruthenium(II), RuCl₂(C₃H₁₀N₂)(C₁₅H₁₇OP)
₂
;
_journal_issue                   3
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              275
_journal_page_last               277
_journal_volume                  221
_journal_year                    2006
_chemical_formula_structural     RuCl2(C15H17OP)2(C3H10N2)
_chemical_formula_sum            'C33 H44 Cl2 N2 O2 P2 Ru'
_chemical_formula_weight         734.61
_chemical_name_systematic
; 
trans-dichloro-1,3-propanediamine-bis[(2-
methoxyethyl)diphenylphosphine]ruthenium(II)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.340(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.2780(14)
_cell_length_b                   10.3152(14)
_cell_length_c                   24.825(3)
_cell_measurement_reflns_used    51
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      14.00
_cell_measurement_theta_min      4.81
_cell_volume                     3400.1(7)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       omega
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0275
_diffrn_reflns_av_sigmaI/netI    0.0257
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            22999
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_reflns_theta_min         2.14
_diffrn_standards_interval_count 98
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    0.744
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.435
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1520
_exptl_crystal_size_max          0.66
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.33
_refine_diff_density_max         0.431
_refine_diff_density_min         -0.776
_refine_diff_density_rms         0.051
_refine_ls_extinction_coef       0.00274(17)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     382
_refine_ls_number_reflns         7802
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.0275
_refine_ls_R_factor_gt           0.0234
_refine_ls_shift/su_max          0.083
_refine_ls_shift/su_mean         0.004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0242P)²+1.4148P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0573
_refine_ls_wR_factor_ref         0.0590
_reflns_number_gt                7097
_reflns_number_total             7802
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            1267-1779.cff
_cod_data_source_block           C33H44Cl2N2O2P2Ru
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_cell_volume        3400.2(7)
_cod_original_sg_symbol_H-M      P12(1)/c1
_cod_database_code               8101973
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.629822(9) 0.688747(11) 0.411012(4) 0.01837(5) Uani 1 4 e d . . .
Cl1 Cl 0.53881(3) 0.48512(4) 0.413651(15) 0.02855(9) Uani 1 4 e d . . .
Cl2 Cl 0.68341(3) 0.91181(3) 0.419712(15) 0.02652(9) Uani 1 4 e d . . .
P1 P 0.78245(3) 0.62380(4) 0.445613(15) 0.02068(8) Uani 1 4 e d . . .
P2 P 0.68179(3) 0.64474(4) 0.325100(14) 0.01953(8) Uani 1 4 e d . . .
O3 O 1.07369(10) 0.76023(13) 0.43775(5) 0.0389(3) Uani 1 4 e d . . .
O19 O 0.78831(11) 0.33208(14) 0.24706(5) 0.0423(3) Uani 1 4 e d . . .
N1 N 0.56121(11) 0.70821(13) 0.49075(5) 0.0266(3) Uani 1 4 e d . . .
H2C H 0.5245 0.6339 0.4966 0.032 Uiso 1 4 e calc R . .
H2D H 0.6131 0.7078 0.5155 0.032 Uiso 1 4 e calc R . .
N2 N 0.48574(11) 0.76613(14) 0.38095(6) 0.0299(3) Uani 1 4 e d . . .
H1C H 0.4963 0.7944 0.3463 0.036 Uiso 1 4 e calc R . .
H1D H 0.4415 0.6976 0.3787 0.036 Uiso 1 4 e calc R . .
C1 C 0.89145(13) 0.72548(16) 0.42746(6) 0.0269(3) Uani 1 4 e d . . .
H13A H 0.9103 0.7053 0.3899 0.032 Uiso 1 4 e calc R . .
H13B H 0.8701 0.8174 0.4285 0.032 Uiso 1 4 e calc R . .
C2 C 0.98557(14) 0.71050(18) 0.46312(7) 0.0328(4) Uani 1 4 e d . . .
H14A H 0.9749 0.7569 0.4975 0.039 Uiso 1 4 e calc R . .
H14B H 0.9958 0.6176 0.4715 0.039 Uiso 1 4 e calc R . .
C4 C 1.08151(19) 0.8952(2) 0.44146(11) 0.0579(6) Uani 1 4 e d . . .
H15A H 1.0290 0.9355 0.4192 0.087 Uiso 1 4 e calc R . .
H15B H 1.1479 0.9227 0.4287 0.087 Uiso 1 4 e calc R . .
H15C H 1.0731 0.9219 0.4791 0.087 Uiso 1 4 e calc R . .
C5 C 0.82655(13) 0.45875(15) 0.43101(6) 0.0251(3) Uani 1 4 e d . . .
C6 C 0.91639(14) 0.43209(18) 0.40413(7) 0.0313(4) Uani 1 4 e d . . .
H2 H 0.9618 0.5005 0.3961 0.038 Uiso 1 4 e calc R . .
C7 C 0.93964(16) 0.30509(19) 0.38912(8) 0.0411(5) Uani 1 4 e d . . .
H3 H 1.0009 0.2876 0.3710 0.049 Uiso 1 4 e calc R . .
C8 C 0.87421(18) 0.20487(18) 0.40046(8) 0.0429(5) Uani 1 4 e d . . .
H4 H 0.8899 0.1189 0.3896 0.051 Uiso 1 4 e calc R . .
C9 C 0.78589(17) 0.23009(17) 0.42765(8) 0.0403(4) Uani 1 4 e d . . .
H5 H 0.7413 0.1611 0.4361 0.048 Uiso 1 4 e calc R . .
C10 C 0.76211(15) 0.35600(16) 0.44271(7) 0.0322(4) Uani 1 4 e d . . .
H6 H 0.7010 0.3724 0.4613 0.039 Uiso 1 4 e calc R . .
C11 C 0.78900(13) 0.63283(16) 0.51982(6) 0.0260(3) Uani 1 4 e d . . .
C12 C 0.80173(14) 0.52568(18) 0.55309(7) 0.0324(4) Uani 1 4 e d . . .
H8 H 0.8099 0.4419 0.5378 0.039 Uiso 1 4 e calc R . .
C13 C 0.80257(17) 0.5414(2) 0.60912(7) 0.0441(5) Uani 1 4 e d . . .
H9 H 0.8116 0.4678 0.6316 0.053 Uiso 1 4 e calc R . .
C14 C 0.79058(17) 0.6616(2) 0.63203(7) 0.0465(5) Uani 1 4 e d . . .
H10 H 0.7909 0.6708 0.6701 0.056 Uiso 1 4 e calc R . .
C15 C 0.77804(17) 0.7688(2) 0.59943(7) 0.0436(5) Uani 1 4 e d . . .
H11 H 0.7700 0.8521 0.6151 0.052 Uiso 1 4 e calc R . .
C16 C 0.77720(15) 0.75525(18) 0.54361(7) 0.0350(4) Uani 1 4 e d . . .
H12 H 0.7686 0.8295 0.5214 0.042 Uiso 1 4 e calc R . .
C17 C 0.71683(14) 0.47497(15) 0.31142(6) 0.0260(3) Uani 1 4 e d . . .
H28A H 0.7854 0.4604 0.3260 0.031 Uiso 1 4 e calc R . .
H28B H 0.6705 0.4182 0.3317 0.031 Uiso 1 4 e calc R . .
C18 C 0.71566(14) 0.43129(17) 0.25251(6) 0.0299(4) Uani 1 4 e d . . .
H29A H 0.6481 0.3983 0.2425 0.036 Uiso 1 4 e calc R . .
H29B H 0.7322 0.5050 0.2286 0.036 Uiso 1 4 e calc R . .
C20 C 0.7915(2) 0.2847(3) 0.19359(9) 0.0641(7) Uani 1 4 e d . . .
H30A H 0.7265 0.2452 0.1843 0.096 Uiso 1 4 e calc R . .
H30B H 0.8449 0.2195 0.1906 0.096 Uiso 1 4 e calc R . .
H30C H 0.8052 0.3565 0.1688 0.096 Uiso 1 4 e calc R . .
C21 C 0.78709(12) 0.73670(16) 0.29660(6) 0.0238(3) Uani 1 4 e d . . .
C22 C 0.87182(14) 0.67876(19) 0.27386(7) 0.0343(4) Uani 1 4 e d . . .
H17 H 0.8756 0.5870 0.2714 0.041 Uiso 1 4 e calc R . .
C23 C 0.95044(15) 0.7540(2) 0.25480(8) 0.0459(5) Uani 1 4 e d . . .
H18 H 1.0079 0.7134 0.2396 0.055 Uiso 1 4 e calc R . .
C24 C 0.94584(16) 0.8870(2) 0.25779(9) 0.0491(5) Uani 1 4 e d . . .
H19 H 0.9997 0.9381 0.2444 0.059 Uiso 1 4 e calc R . .
C25 C 0.86271(16) 0.9463(2) 0.28033(7) 0.0413(5) Uani 1 4 e d . . .
H20 H 0.8594 1.0381 0.2823 0.050 Uiso 1 4 e calc R . .
C26 C 0.78415(14) 0.87162(16) 0.30003(6) 0.0285(3) Uani 1 4 e d . . .
H21 H 0.7278 0.9129 0.3160 0.034 Uiso 1 4 e calc R . .
C27 C 0.58304(13) 0.66257(15) 0.27262(6) 0.0240(3) Uani 1 4 e d . . .
C28 C 0.59352(15) 0.73760(17) 0.22642(7) 0.0325(4) Uani 1 4 e d . . .
H27 H 0.6515 0.7905 0.2222 0.039 Uiso 1 4 e calc R . .
C29 C 0.51947(17) 0.7359(2) 0.18619(8) 0.0432(5) Uani 1 4 e d . . .
H26 H 0.5282 0.7862 0.1545 0.052 Uiso 1 4 e calc R . .
C30 C 0.43445(18) 0.6622(2) 0.19204(9) 0.0474(5) Uani 1 4 e d . . .
H25 H 0.3845 0.6609 0.1645 0.057 Uiso 1 4 e calc R . .
C31 C 0.42181(16) 0.5897(2) 0.23849(9) 0.0464(5) Uani 1 4 e d . . .
H24 H 0.3621 0.5404 0.2432 0.056 Uiso 1 4 e calc R . .
C32 C 0.49609(15) 0.58879(18) 0.27822(7) 0.0352(4) Uani 1 4 e d . . .
H23 H 0.4873 0.5372 0.3095 0.042 Uiso 1 4 e calc R . .
C33 C 0.49514(15) 0.81845(16) 0.50489(7) 0.0327(4) Uani 1 4 e d . . .
H33A H 0.5351 0.8994 0.5043 0.039 Uiso 1 4 e calc R . .
H33B H 0.4700 0.8062 0.5420 0.039 Uiso 1 4 e calc R . .
C34 C 0.40589(15) 0.83263(19) 0.46677(8) 0.0383(4) Uani 1 4 e d . . .
H32A H 0.3694 0.7490 0.4652 0.046 Uiso 1 4 e calc R . .
H32B H 0.3592 0.8981 0.4817 0.046 Uiso 1 4 e calc R . .
C35 C 0.43337(14) 0.87228(18) 0.41001(7) 0.0340(4) Uani 1 4 e d . . .
H31A H 0.3714 0.8963 0.3900 0.041 Uiso 1 4 e calc R . .
H31B H 0.4776 0.9495 0.4114 0.041 Uiso 1 4 e calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ru1 N2 84.71(5) . . ?
N1 Ru1 P2 170.90(4) . . ?
N2 Ru1 P2 91.27(4) . . ?
N1 Ru1 P1 93.41(4) . . ?
N2 Ru1 P1 175.40(4) . . ?
P2 Ru1 P1 91.170(16) . . ?
N1 Ru1 Cl2 87.47(4) . . ?
N2 Ru1 Cl2 86.55(4) . . ?
P2 Ru1 Cl2 100.464(14) . . ?
P1 Ru1 Cl2 89.176(16) . . ?
N1 Ru1 Cl1 81.09(4) . . ?
N2 Ru1 Cl1 83.74(4) . . ?
P2 Ru1 Cl1 90.368(15) . . ?
P1 Ru1 Cl1 100.140(16) . . ?
Cl2 Ru1 Cl1 165.608(15) . . ?
C5 P1 C1 103.13(8) . . ?
C5 P1 C11 103.33(7) . . ?
C1 P1 C11 100.52(8) . . ?
C5 P1 Ru1 118.56(5) . . ?
C1 P1 Ru1 115.75(5) . . ?
C11 P1 Ru1 113.25(6) . . ?
C21 P2 C17 103.08(8) . . ?
C21 P2 C27 102.43(7) . . ?
C17 P2 C27 98.23(7) . . ?
C21 P2 Ru1 119.40(5) . . ?
C17 P2 Ru1 115.93(5) . . ?
C27 P2 Ru1 114.80(5) . . ?
C4 O3 C2 112.91(16) . . ?
C18 O19 C20 111.34(15) . . ?
C33 N1 Ru1 122.31(10) . . ?
C35 N2 Ru1 120.75(11) . . ?
C2 C1 P1 116.04(11) . . ?
O3 C2 C1 112.08(14) . . ?
C10 C5 C6 118.46(16) . . ?
C10 C5 P1 117.82(13) . . ?
C6 C5 P1 123.41(13) . . ?
C7 C6 C5 120.17(18) . . ?
C8 C7 C6 120.50(19) . . ?
C7 C8 C9 119.72(17) . . ?
C8 C9 C10 120.19(19) . . ?
C9 C10 C5 120.95(18) . . ?
C12 C11 C16 118.63(15) . . ?
C12 C11 P1 123.91(13) . . ?
C16 C11 P1 117.43(12) . . ?
C11 C12 C13 119.92(18) . . ?
C14 C13 C12 121.02(18) . . ?
C13 C14 C15 119.63(17) . . ?
C14 C15 C16 120.22(19) . . ?
C15 C16 C11 120.57(18) . . ?
C18 C17 P2 117.03(11) . . ?
O19 C18 C17 107.55(13) . . ?
C26 C21 C22 118.34(16) . . ?
C26 C21 P2 118.08(13) . . ?
C22 C21 P2 123.53(13) . . ?
C23 C22 C21 120.58(18) . . ?
C24 C23 C22 120.4(2) . . ?
C23 C24 C25 119.91(19) . . ?
C24 C25 C26 120.06(19) . . ?
C25 C26 C21 120.70(17) . . ?
C32 C27 C28 118.30(16) . . ?
C32 C27 P2 117.39(12) . . ?
C28 C27 P2 124.15(13) . . ?
C27 C28 C29 120.57(18) . . ?
C30 C29 C28 120.57(18) . . ?
C29 C30 C31 119.45(18) . . ?
C30 C31 C32 120.3(2) . . ?
C27 C32 C31 120.73(18) . . ?
N1 C33 C34 112.81(14) . . ?
C35 C34 C33 114.48(16) . . ?
N2 C35 C34 111.64(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N1 2.1932(13) . ?
Ru1 N2 2.1993(15) . ?
Ru1 P2 2.2910(4) . ?
Ru1 P1 2.2963(5) . ?
Ru1 Cl2 2.4177(5) . ?
Ru1 Cl1 2.4244(5) . ?
P1 C5 1.8372(16) . ?
P1 C1 1.8455(17) . ?
P1 C11 1.8461(16) . ?
P2 C21 1.8349(16) . ?
P2 C17 1.8440(16) . ?
P2 C27 1.8521(16) . ?
O3 C4 1.399(3) . ?
O3 C2 1.427(2) . ?
O19 C18 1.413(2) . ?
O19 C20 1.416(2) . ?
N1 C33 1.480(2) . ?
N2 C35 1.486(2) . ?
C1 C2 1.535(2) . ?
C5 C10 1.394(2) . ?
C5 C6 1.398(2) . ?
C6 C7 1.397(2) . ?
C7 C8 1.380(3) . ?
C8 C9 1.381(3) . ?
C9 C10 1.388(2) . ?
C11 C12 1.389(2) . ?
C11 C16 1.403(2) . ?
C12 C13 1.400(2) . ?
C13 C14 1.374(3) . ?
C14 C15 1.380(3) . ?
C15 C16 1.393(2) . ?
C17 C18 1.530(2) . ?
C21 C26 1.395(2) . ?
C21 C22 1.396(2) . ?
C22 C23 1.386(3) . ?
C23 C24 1.376(3) . ?
C24 C25 1.383(3) . ?
C25 C26 1.388(2) . ?
C27 C32 1.390(2) . ?
C27 C28 1.391(2) . ?
C28 C29 1.397(3) . ?
C29 C30 1.369(3) . ?
C30 C31 1.385(3) . ?
C31 C32 1.391(3) . ?
C33 C34 1.519(3) . ?
C34 C35 1.514(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ru1 P1 C5 114.90(7) . . . . ?
N2 Ru1 P1 C5 -179(86) . . . . ?
P2 Ru1 P1 C5 -57.23(6) . . . . ?
Cl2 Ru1 P1 C5 -157.68(6) . . . . ?
Cl1 Ru1 P1 C5 33.35(6) . . . . ?
N1 Ru1 P1 C1 -121.75(7) . . . . ?
N2 Ru1 P1 C1 -56.0(5) . . . . ?
P2 Ru1 P1 C1 66.12(6) . . . . ?
Cl2 Ru1 P1 C1 -34.33(6) . . . . ?
Cl1 Ru1 P1 C1 156.70(6) . . . . ?
N1 Ru1 P1 C11 -6.41(7) . . . . ?
N2 Ru1 P1 C11 59.3(5) . . . . ?
P2 Ru1 P1 C11 -178.54(6) . . . . ?
Cl2 Ru1 P1 C11 81.01(6) . . . . ?
Cl1 Ru1 P1 C11 -87.96(6) . . . . ?
N1 Ru1 P2 C21 176.2(2) . . . . ?
N2 Ru1 P2 C21 112.54(7) . . . . ?
P1 Ru1 P2 C21 -63.57(6) . . . . ?
Cl2 Ru1 P2 C21 25.81(6) . . . . ?
Cl1 Ru1 P2 C21 -163.72(6) . . . . ?
N1 Ru1 P2 C17 -59.6(3) . . . . ?
N2 Ru1 P2 C17 -123.21(8) . . . . ?
P1 Ru1 P2 C17 60.68(7) . . . . ?
Cl2 Ru1 P2 C17 150.06(7) . . . . ?
Cl1 Ru1 P2 C17 -39.47(7) . . . . ?
N1 Ru1 P2 C27 54.0(3) . . . . ?
N2 Ru1 P2 C27 -9.63(7) . . . . ?
P1 Ru1 P2 C27 174.26(6) . . . . ?
Cl2 Ru1 P2 C27 -96.36(6) . . . . ?
Cl1 Ru1 P2 C27 74.11(6) . . . . ?
N2 Ru1 N1 C33 -37.81(14) . . . . ?
P2 Ru1 N1 C33 -101.9(2) . . . . ?
P1 Ru1 N1 C33 137.98(13) . . . . ?
Cl2 Ru1 N1 C33 48.96(13) . . . . ?
Cl1 Ru1 N1 C33 -122.28(13) . . . . ?
N1 Ru1 N2 C35 39.91(13) . . . . ?
P2 Ru1 N2 C35 -148.28(13) . . . . ?
P1 Ru1 N2 C35 -26.2(6) . . . . ?
Cl2 Ru1 N2 C35 -47.87(13) . . . . ?
Cl1 Ru1 N2 C35 121.49(13) . . . . ?
C5 P1 C1 C2 -67.25(14) . . . . ?
C11 P1 C1 C2 39.26(14) . . . . ?
Ru1 P1 C1 C2 161.63(11) . . . . ?
C4 O3 C2 C1 80.0(2) . . . . ?
P1 C1 C2 O3 162.27(12) . . . . ?
C1 P1 C5 C10 177.34(13) . . . . ?
C11 P1 C5 C10 72.98(14) . . . . ?
Ru1 P1 C5 C10 -53.25(14) . . . . ?
C1 P1 C5 C6 -9.16(15) . . . . ?
C11 P1 C5 C6 -113.52(14) . . . . ?
Ru1 P1 C5 C6 120.26(13) . . . . ?
C10 C5 C6 C7 0.6(2) . . . . ?
P1 C5 C6 C7 -172.85(13) . . . . ?
C5 C6 C7 C8 0.2(3) . . . . ?
C6 C7 C8 C9 -1.1(3) . . . . ?
C7 C8 C9 C10 1.1(3) . . . . ?
C8 C9 C10 C5 -0.3(3) . . . . ?
C6 C5 C10 C9 -0.6(3) . . . . ?
P1 C5 C10 C9 173.25(14) . . . . ?
C5 P1 C11 C12 -13.21(18) . . . . ?
C1 P1 C11 C12 -119.55(16) . . . . ?
Ru1 P1 C11 C12 116.33(15) . . . . ?
C5 P1 C11 C16 168.83(14) . . . . ?
C1 P1 C11 C16 62.48(16) . . . . ?
Ru1 P1 C11 C16 -61.63(15) . . . . ?
C16 C11 C12 C13 0.0(3) . . . . ?
P1 C11 C12 C13 -177.93(15) . . . . ?
C11 C12 C13 C14 0.2(3) . . . . ?
C12 C13 C14 C15 -0.4(3) . . . . ?
C13 C14 C15 C16 0.2(3) . . . . ?
C14 C15 C16 C11 0.0(3) . . . . ?
C12 C11 C16 C15 -0.1(3) . . . . ?
P1 C11 C16 C15 177.93(16) . . . . ?
C21 P2 C17 C18 -68.67(15) . . . . ?
C27 P2 C17 C18 36.22(15) . . . . ?
Ru1 P2 C17 C18 159.01(11) . . . . ?
C20 O19 C18 C17 179.31(19) . . . . ?
P2 C17 C18 O19 150.79(13) . . . . ?
C17 P2 C21 C26 179.75(12) . . . . ?
C27 P2 C21 C26 78.12(13) . . . . ?
Ru1 P2 C21 C26 -49.99(14) . . . . ?
C17 P2 C21 C22 -3.16(16) . . . . ?
C27 P2 C21 C22 -104.79(14) . . . . ?
Ru1 P2 C21 C22 127.10(13) . . . . ?
C26 C21 C22 C23 -0.6(3) . . . . ?
P2 C21 C22 C23 -177.63(14) . . . . ?
C21 C22 C23 C24 -0.3(3) . . . . ?
C22 C23 C24 C25 0.5(3) . . . . ?
C23 C24 C25 C26 0.2(3) . . . . ?
C24 C25 C26 C21 -1.1(3) . . . . ?
C22 C21 C26 C25 1.2(2) . . . . ?
P2 C21 C26 C25 178.49(13) . . . . ?
C21 P2 C27 C32 171.48(13) . . . . ?
C17 P2 C27 C32 66.06(14) . . . . ?
Ru1 P2 C27 C32 -57.55(14) . . . . ?
C21 P2 C27 C28 -3.79(16) . . . . ?
C17 P2 C27 C28 -109.22(15) . . . . ?
Ru1 P2 C27 C28 127.17(13) . . . . ?
C32 C27 C28 C29 -1.6(3) . . . . ?
P2 C27 C28 C29 173.62(15) . . . . ?
C27 C28 C29 C30 1.3(3) . . . . ?
C28 C29 C30 C31 0.5(3) . . . . ?
C29 C30 C31 C32 -1.8(3) . . . . ?
C28 C27 C32 C31 0.3(3) . . . . ?
P2 C27 C32 C31 -175.30(15) . . . . ?
C30 C31 C32 C27 1.5(3) . . . . ?
Ru1 N1 C33 C34 56.16(19) . . . . ?
N1 C33 C34 C35 -67.6(2) . . . . ?
Ru1 N2 C35 C34 -60.91(19) . . . . ?
C33 C34 C35 N2 70.2(2) . . . . ?
