#------------------------------------------------------------------------------
#$Date: 2016-02-18 14:25:00 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176728 $
#$URL: svn://www.crystallography.net/cod/cif/8/10/31/8103102.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8103102
loop_
_publ_author_name
'Kwang Ha'
_publ_section_title
;
 Crystal structure of
 di(μ2-chloro)-dichlorobis(2,3,5,6-tetra-2-pyridylpyrazine)dimanganese(II),
 Mn2Cl4(C24H16N6)2
;
_journal_issue                   1
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              59
_journal_volume                  226
_journal_year                    2011
_chemical_formula_moiety         'C48 H32 Cl4 Mn2 N12'
_chemical_formula_sum            'C48 H32 Cl4 Mn2 N12'
_chemical_formula_weight         1028.54
_chemical_name_systematic
; 
bis[(μ₂-chloro)(2,3,5,6-tetra-2-pyridylpyrazine)]dichlorodimanganese(II), 
Mn₂Cl₄(C₂₄H₁₆N₆)₂

;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.691(4)
_cell_angle_beta                 107.474(4)
_cell_angle_gamma                101.157(4)
_cell_formula_units_Z            1
_cell_length_a                   9.2657(18)
_cell_length_b                   10.675(2)
_cell_length_c                   12.214(2)
_cell_measurement_reflns_used    2178
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      26.01
_cell_measurement_theta_min      2.32
_cell_volume                     1085.8(3)
_computing_cell_refinement       'SAINT (Bruker, 2000)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    'ORTEP-III (Farrugia, 1997)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0451
_diffrn_reflns_av_sigmaI/netI    0.0891
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            6891
_diffrn_reflns_theta_full        26.18
_diffrn_reflns_theta_max         26.18
_diffrn_reflns_theta_min         1.82
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.880
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.735
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.573
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             522
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.14
_refine_diff_density_max         0.673
_refine_diff_density_min         -0.811
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.079
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     298
_refine_ls_number_reflns         4253
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.079
_refine_ls_R_factor_all          0.0947
_refine_ls_R_factor_gt           0.0545
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0246P)²+1.8139P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1016
_refine_ls_wR_factor_ref         0.1411
_reflns_number_gt                2826
_reflns_number_total             4253
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            1267-3299.cff
_cod_data_source_block           mn2cl4(tppz)2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1085.8(4)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               8103102
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Mn1 Mn 0.47333(8) 0.17101(7) 0.05828(6) 0.0263(2) Uani 1 1 d .
Cl1 Cl 0.35506(13) -0.00776(11) -0.12980(10) 0.0312(3) Uani 1 1 d .
Cl2 Cl 0.31409(15) 0.31504(13) -0.00631(12) 0.0402(3) Uani 1 1 d .
N1 N 0.5918(4) 0.2979(3) 0.2480(3) 0.0206(8) Uani 1 1 d .
N2 N 0.7254(4) 0.4667(3) 0.4725(3) 0.0249(9) Uani 1 1 d .
N3 N 0.3269(4) 0.1098(4) 0.1682(3) 0.0255(9) Uani 1 1 d .
N4 N 0.5236(5) 0.1901(4) 0.5337(4) 0.0338(10) Uani 1 1 d .
N5 N 0.9987(4) 0.6771(4) 0.5169(3) 0.0300(10) Uani 1 1 d .
N6 N 0.7103(4) 0.3004(4) 0.0774(3) 0.0253(9) Uani 1 1 d .
C1 C 0.5225(5) 0.2845(4) 0.3273(4) 0.0238(10) Uani 1 1 d .
C2 C 0.6070(5) 0.3588(4) 0.4483(4) 0.0265(11) Uani 1 1 d .
C3 C 0.7799(5) 0.4891(4) 0.3875(4) 0.0227(10) Uani 1 1 d .
C4 C 0.7276(5) 0.3911(4) 0.2766(4) 0.0220(10) Uani 1 1 d .
C5 C 0.3615(5) 0.1939(4) 0.2766(4) 0.0264(10) Uani 1 1 d .
C6 C 0.2496(6) 0.2002(5) 0.3296(4) 0.0313(11) Uani 1 1 d .
H6 H 0.2746 0.2630 0.4044 0.038 Uiso 1 1 calc R
C7 C 0.1009(5) 0.1139(5) 0.2720(5) 0.0350(12) Uani 1 1 d .
H7 H 0.0216 0.1184 0.3059 0.042 Uiso 1 1 calc R
C8 C 0.0680(5) 0.0213(5) 0.1655(4) 0.0320(12) Uani 1 1 d .
H8 H -0.0314 -0.0427 0.1271 0.038 Uiso 1 1 calc R
C9 C 0.1837(5) 0.0242(4) 0.1161(4) 0.0295(11) Uani 1 1 d .
H9 H 0.1606 -0.0378 0.0412 0.035 Uiso 1 1 calc R
C10 C 0.5720(5) 0.3213(4) 0.5483(4) 0.0253(10) Uani 1 1 d .
C11 C 0.5872(5) 0.4150(5) 0.6511(4) 0.0280(11) Uani 1 1 d .
H11 H 0.6286 0.5070 0.6611 0.034 Uiso 1 1 calc R
C12 C 0.5420(6) 0.3737(5) 0.7380(5) 0.0382(13) Uani 1 1 d .
H12 H 0.5498 0.4365 0.8083 0.046 Uiso 1 1 calc R
C13 C 0.4848(6) 0.2391(6) 0.7213(5) 0.0452(15) Uani 1 1 d .
H13 H 0.4482 0.2076 0.7782 0.054 Uiso 1 1 calc R
C14 C 0.4822(6) 0.1520(5) 0.6209(5) 0.0434(14) Uani 1 1 d .
H14 H 0.4492 0.0594 0.6124 0.052 Uiso 1 1 calc R
C15 C 0.8884(5) 0.6218(4) 0.4087(4) 0.0237(10) Uani 1 1 d .
C16 C 0.8683(6) 0.6815(5) 0.3176(5) 0.0345(12) Uani 1 1 d .
H16 H 0.7866 0.6391 0.2425 0.041 Uiso 1 1 calc R
C17 C 0.9687(6) 0.8042(5) 0.3369(5) 0.0448(14) Uani 1 1 d .
H17 H 0.9569 0.8485 0.2760 0.054 Uiso 1 1 calc R
C18 C 1.0860(7) 0.8602(5) 0.4466(6) 0.0467(15) Uani 1 1 d .
H18 H 1.1588 0.9435 0.4625 0.056 Uiso 1 1 calc R
C19 C 1.0966(5) 0.7950(5) 0.5324(5) 0.0357(13) Uani 1 1 d .
H19 H 1.1784 0.8354 0.6078 0.043 Uiso 1 1 calc R
C20 C 0.8051(5) 0.3745(4) 0.1873(4) 0.0235(10) Uani 1 1 d .
C21 C 0.9662(5) 0.4243(4) 0.2176(4) 0.0301(11) Uani 1 1 d .
H21 H 1.0313 0.4732 0.2972 0.036 Uiso 1 1 calc R
C22 C 1.0286(6) 0.4011(5) 0.1295(5) 0.0354(12) Uani 1 1 d .
H22 H 1.1385 0.4337 0.1479 0.042 Uiso 1 1 calc R
C23 C 0.9323(6) 0.3304(5) 0.0141(4) 0.0340(12) Uani 1 1 d .
H23 H 0.9728 0.3166 -0.0488 0.041 Uiso 1 1 calc R
C24 C 0.7765(6) 0.2811(5) -0.0059(4) 0.0323(12) Uani 1 1 d .
H24 H 0.7104 0.2295 -0.0845 0.039 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N1 Mn1 N6 71.29(13) .
N1 Mn1 N3 70.90(13) .
N6 Mn1 N3 141.74(13) .
N1 Mn1 Cl2 95.54(10) .
N6 Mn1 Cl2 98.24(11) .
N3 Mn1 Cl2 90.98(11) .
N1 Mn1 Cl1 167.35(10) .
N6 Mn1 Cl1 112.66(10) .
N3 Mn1 Cl1 103.14(10) .
Cl2 Mn1 Cl1 95.72(5) .
N1 Mn1 Cl1 84.79(10) 2_655
N6 Mn1 Cl1 82.89(10) 2_655
N3 Mn1 Cl1 88.10(11) 2_655
Cl2 Mn1 Cl1 178.86(5) 2_655
Cl1 Mn1 Cl1 83.85(5) 2_655
Mn1 Cl1 Mn1 96.15(5) 2_655
C1 N1 C4 121.7(4) .
C1 N1 Mn1 119.6(3) .
C4 N1 Mn1 118.6(3) .
C3 N2 C2 119.8(4) .
C9 N3 C5 118.2(4) .
C9 N3 Mn1 121.2(3) .
C5 N3 Mn1 116.7(3) .
C10 N4 C14 117.2(4) .
C15 N5 C19 116.2(4) .
C20 N6 C24 116.8(4) .
C20 N6 Mn1 117.5(3) .
C24 N6 Mn1 123.3(3) .
N1 C1 C2 117.8(4) .
N1 C1 C5 114.7(4) .
C2 C1 C5 127.5(4) .
N2 C2 C1 118.8(4) .
N2 C2 C10 118.4(4) .
C1 C2 C10 122.8(4) .
N2 C3 C4 120.0(4) .
N2 C3 C15 118.7(4) .
C4 C3 C15 121.2(4) .
N1 C4 C3 117.1(4) .
N1 C4 C20 114.4(4) .
C3 C4 C20 128.4(4) .
N3 C5 C6 121.6(4) .
N3 C5 C1 114.3(4) .
C6 C5 C1 123.8(4) .
C7 C6 C5 118.9(4) .
C7 C6 H6 120.5 .
C5 C6 H6 120.5 .
C8 C7 C6 119.7(4) .
C8 C7 H7 120.1 .
C6 C7 H7 120.1 .
C7 C8 C9 117.9(4) .
C7 C8 H8 121.0 .
C9 C8 H8 121.0 .
N3 C9 C8 123.3(4) .
N3 C9 H9 118.3 .
C8 C9 H9 118.3 .
N4 C10 C11 122.3(4) .
N4 C10 C2 115.4(4) .
C11 C10 C2 122.3(4) .
C12 C11 C10 119.4(5) .
C12 C11 H11 120.3 .
C10 C11 H11 120.3 .
C11 C12 C13 118.8(5) .
C11 C12 H12 120.6 .
C13 C12 H12 120.6 .
C14 C13 C12 118.5(5) .
C14 C13 H13 120.7 .
C12 C13 H13 120.7 .
N4 C14 C13 123.7(5) .
N4 C14 H14 118.2 .
C13 C14 H14 118.2 .
N5 C15 C16 123.5(4) .
N5 C15 C3 117.6(4) .
C16 C15 C3 118.9(4) .
C15 C16 C17 119.0(5) .
C15 C16 H16 120.5 .
C17 C16 H16 120.5 .
C18 C17 C16 118.1(5) .
C18 C17 H17 121.0 .
C16 C17 H17 121.0 .
C19 C18 C17 119.1(5) .
C19 C18 H18 120.4 .
C17 C18 H18 120.4 .
N5 C19 C18 124.0(5) .
N5 C19 H19 118.0 .
C18 C19 H19 118.0 .
N6 C20 C21 122.8(4) .
N6 C20 C4 114.9(4) .
C21 C20 C4 122.2(4) .
C22 C21 C20 118.2(4) .
C22 C21 H21 120.9 .
C20 C21 H21 120.9 .
C21 C22 C23 120.2(4) .
C21 C22 H22 119.9 .
C23 C22 H22 119.9 .
C24 C23 C22 117.3(5) .
C24 C23 H23 121.3 .
C22 C23 H23 121.3 .
N6 C24 C23 124.6(5) .
N6 C24 H24 117.7 .
C23 C24 H24 117.7 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Mn1 N1 2.244(3) .
Mn1 N6 2.274(3) .
Mn1 N3 2.275(4) .
Mn1 Cl2 2.4153(15) .
Mn1 Cl1 2.4540(13) .
Mn1 Cl1 2.6802(15) 2_655
Cl1 Mn1 2.6802(15) 2_655
N1 C1 1.329(5) .
N1 C4 1.343(5) .
N2 C3 1.326(6) .
N2 C2 1.340(5) .
N3 C9 1.337(5) .
N3 C5 1.347(6) .
N4 C10 1.343(5) .
N4 C14 1.344(7) .
N5 C15 1.333(6) .
N5 C19 1.342(6) .
N6 C20 1.338(5) .
N6 C24 1.339(6) .
C1 C2 1.420(6) .
C1 C5 1.479(6) .
C2 C10 1.464(6) .
C3 C4 1.414(6) .
C3 C15 1.493(6) .
C4 C20 1.477(6) .
C5 C6 1.382(6) .
C6 C7 1.381(6) .
C6 H6 0.9500 .
C7 C8 1.373(7) .
C7 H7 0.9500 .
C8 C9 1.378(6) .
C8 H8 0.9500 .
C9 H9 0.9500 .
C10 C11 1.388(6) .
C11 C12 1.372(7) .
C11 H11 0.9500 .
C12 C13 1.381(7) .
C12 H12 0.9500 .
C13 C14 1.372(8) .
C13 H13 0.9500 .
C14 H14 0.9500 .
C15 C16 1.374(7) .
C16 C17 1.381(7) .
C16 H16 0.9500 .
C17 C18 1.372(7) .
C17 H17 0.9500 .
C18 C19 1.361(8) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C21 1.389(6) .
C21 C22 1.369(7) .
C21 H21 0.9500 .
C22 C23 1.381(7) .
C22 H22 0.9500 .
C23 C24 1.364(6) .
C23 H23 0.9500 .
C24 H24 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Mn1 Cl1 Mn1 -26.2(4) . 2_655
N6 Mn1 Cl1 Mn1 79.64(12) . 2_655
N3 Mn1 Cl1 Mn1 -86.60(11) . 2_655
Cl2 Mn1 Cl1 Mn1 -178.94(5) . 2_655
Cl1 Mn1 Cl1 Mn1 0.0 2_655 2_655
N6 Mn1 N1 C1 -177.7(4) . .
N3 Mn1 N1 C1 -3.6(3) . .
Cl2 Mn1 N1 C1 85.5(3) . .
Cl1 Mn1 N1 C1 -67.3(6) . .
Cl1 Mn1 N1 C1 -93.4(3) 2_655 .
N6 Mn1 N1 C4 6.0(3) . .
N3 Mn1 N1 C4 -179.9(4) . .
Cl2 Mn1 N1 C4 -90.8(3) . .
Cl1 Mn1 N1 C4 116.4(5) . .
Cl1 Mn1 N1 C4 90.3(3) 2_655 .
N1 Mn1 N3 C9 171.4(4) . .
N6 Mn1 N3 C9 -179.4(3) . .
Cl2 Mn1 N3 C9 75.9(4) . .
Cl1 Mn1 N3 C9 -20.2(4) . .
Cl1 Mn1 N3 C9 -103.4(4) 2_655 .
N1 Mn1 N3 C5 14.3(3) . .
N6 Mn1 N3 C5 23.4(5) . .
Cl2 Mn1 N3 C5 -81.3(3) . .
Cl1 Mn1 N3 C5 -177.4(3) . .
Cl1 Mn1 N3 C5 99.4(3) 2_655 .
N1 Mn1 N6 C20 6.0(3) . .
N3 Mn1 N6 C20 -3.1(4) . .
Cl2 Mn1 N6 C20 99.1(3) . .
Cl1 Mn1 N6 C20 -161.1(3) . .
Cl1 Mn1 N6 C20 -80.8(3) 2_655 .
N1 Mn1 N6 C24 167.7(4) . .
N3 Mn1 N6 C24 158.6(3) . .
Cl2 Mn1 N6 C24 -99.2(4) . .
Cl1 Mn1 N6 C24 0.6(4) . .
Cl1 Mn1 N6 C24 80.8(4) 2_655 .
C4 N1 C1 C2 -8.9(7) . .
Mn1 N1 C1 C2 175.0(3) . .
C4 N1 C1 C5 169.9(4) . .
Mn1 N1 C1 C5 -6.3(5) . .
C3 N2 C2 C1 -12.1(6) . .
C3 N2 C2 C10 167.0(4) . .
N1 C1 C2 N2 20.9(6) . .
C5 C1 C2 N2 -157.7(4) . .
N1 C1 C2 C10 -158.2(4) . .
C5 C1 C2 C10 23.3(7) . .
C2 N2 C3 C4 -8.1(7) . .
C2 N2 C3 C15 168.0(4) . .
C1 N1 C4 C3 -10.7(6) . .
Mn1 N1 C4 C3 165.5(3) . .
C1 N1 C4 C20 167.7(4) . .
Mn1 N1 C4 C20 -16.1(5) . .
N2 C3 C4 N1 19.9(6) . .
C15 C3 C4 N1 -156.2(4) . .
N2 C3 C4 C20 -158.3(4) . .
C15 C3 C4 C20 25.6(7) . .
C9 N3 C5 C6 -5.2(7) . .
Mn1 N3 C5 C6 152.7(4) . .
C9 N3 C5 C1 179.8(4) . .
Mn1 N3 C5 C1 -22.3(5) . .
N1 C1 C5 N3 18.8(6) . .
C2 C1 C5 N3 -162.6(5) . .
N1 C1 C5 C6 -156.1(5) . .
C2 C1 C5 C6 22.5(8) . .
N3 C5 C6 C7 3.0(8) . .
C1 C5 C6 C7 177.5(5) . .
C5 C6 C7 C8 1.8(8) . .
C6 C7 C8 C9 -4.1(8) . .
C5 N3 C9 C8 2.7(7) . .
Mn1 N3 C9 C8 -154.1(4) . .
C7 C8 C9 N3 1.9(8) . .
C14 N4 C10 C11 3.3(7) . .
C14 N4 C10 C2 -176.5(4) . .
N2 C2 C10 N4 -144.9(4) . .
C1 C2 C10 N4 34.2(6) . .
N2 C2 C10 C11 35.3(6) . .
C1 C2 C10 C11 -145.7(5) . .
N4 C10 C11 C12 -4.4(7) . .
C2 C10 C11 C12 175.4(4) . .
C10 C11 C12 C13 1.1(7) . .
C11 C12 C13 C14 2.8(8) . .
C10 N4 C14 C13 0.9(8) . .
C12 C13 C14 N4 -4.0(8) . .
C19 N5 C15 C16 -2.7(7) . .
C19 N5 C15 C3 178.6(4) . .
N2 C3 C15 N5 41.1(6) . .
C4 C3 C15 N5 -142.8(4) . .
N2 C3 C15 C16 -137.7(5) . .
C4 C3 C15 C16 38.4(7) . .
N5 C15 C16 C17 1.4(8) . .
C3 C15 C16 C17 -179.9(5) . .
C15 C16 C17 C18 0.8(8) . .
C16 C17 C18 C19 -1.5(9) . .
C15 N5 C19 C18 1.9(7) . .
C17 C18 C19 N5 0.2(9) . .
C24 N6 C20 C21 -3.3(7) . .
Mn1 N6 C20 C21 159.5(4) . .
C24 N6 C20 C4 -179.0(4) . .
Mn1 N6 C20 C4 -16.1(5) . .
N1 C4 C20 N6 21.0(6) . .
C3 C4 C20 N6 -160.8(4) . .
N1 C4 C20 C21 -154.7(4) . .
C3 C4 C20 C21 23.6(7) . .
N6 C20 C21 C22 2.9(7) . .
C4 C20 C21 C22 178.2(4) . .
C20 C21 C22 C23 0.3(8) . .
C21 C22 C23 C24 -2.7(8) . .
C20 N6 C24 C23 0.6(7) . .
Mn1 N6 C24 C23 -161.2(4) . .
C22 C23 C24 N6 2.4(8) . .
