#------------------------------------------------------------------------------
#$Date: 2022-05-06 12:27:30 +0300 (Fri, 06 May 2022) $
#$Revision: 275102 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/51/8105169.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8105169
loop_
_publ_author_name
'Gichumbi, Joel M.'
'Omondi, Bernard'
'Friedrich, Holger B.'
_publ_section_title
;
 Crystal structure of chlorido-(η
 6-p-cymene)-(N-(2-fluorophenyl)-1-(pyridin-2-yl)methanimine-κ 2
 N,N′)ruthenium(II) -- acetone (1/1), C22H23ClN2F7OPRu
;
_journal_issue                   3
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              551
_journal_page_last               553
_journal_paper_doi               10.1515/ncrs-2019-0793
_journal_volume                  235
_journal_year                    2020
_chemical_formula_moiety         'C22 H23 Cl F N2 Ru, F6 P, C3 H6 O'
_chemical_formula_sum            'C25 H29 Cl F7 N2 O P Ru'
_chemical_formula_weight         673.99
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 96.6990(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.30480(10)
_cell_length_b                   12.9540(3)
_cell_length_c                   28.7076(6)
_cell_measurement_reflns_used    9387
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.29
_cell_measurement_theta_min      2.66
_cell_measurement_wavelength     0.71073
_cell_volume                     2697.95(9)
_computing_cell_refinement       'SAINT-plus (Bruker, 2012)'
_computing_data_collection       'APEX2 (Bruker, 2012)'
_computing_data_reduction        'SAINT-Plus and XPREP (Bruker, 2012)'
_computing_molecular_graphics    'ORTEP3 (Farrugia, 2012)'
_computing_publication_material  'WinGX (Farrugia, 2012)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2013)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker Smart ApexII CCD'
_diffrn_measurement_method       'φ scans and ω scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0199
_diffrn_reflns_av_unetI/netI     0.0076
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_number            101207
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.301
_diffrn_reflns_theta_min         1.727
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_interval_count .
_diffrn_standards_interval_time  .
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.810
_exptl_absorpt_correction_T_max  0.862
_exptl_absorpt_correction_T_min  0.799
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2012)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.659
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1360
_exptl_crystal_size_max          0.260
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.220
_refine_diff_density_max         1.005
_refine_diff_density_min         -0.520
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.136
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     346
_refine_ls_number_reflns         6690
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.136
_refine_ls_R_factor_all          0.0205
_refine_ls_R_factor_gt           0.0196
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0160P)²+2.3116P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0474
_refine_ls_wR_factor_ref         0.0479
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6475
_reflns_number_total             6690
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            suppl_ncrs-2019-0793_suppl.cif
_cod_data_source_block           2MeOTerpy
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_diffrn_radiation_probe' value 'X-ray' was changed to
'x-ray' in accordance with the built-in table derived from the CIF
Core dictionary named 'cif_core.dic' version 2.4.5 last updated on
2014-11-21.

Automatic conversion script
Id: cif_fix_values 8738 2021-04-28 16:35:53Z antanas 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               8105169
_shelx_estimated_absorpt_t_min   0.817
_shelx_estimated_absorpt_t_max   0.842
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C23 C 0.1629(3) 0.3209(2) 0.44231(7) 0.0428(5) Uani 1 1 d . . . . .
H23A H 0.2809 0.2871 0.4392 0.064 Uiso 1 1 calc R U . . .
H23B H 0.1788 0.3960 0.4417 0.064 Uiso 1 1 calc R U . . .
H23C H 0.0718 0.2999 0.4162 0.064 Uiso 1 1 calc R U . . .
C24 C 0.0973(2) 0.28990(13) 0.48774(6) 0.0255(3) Uani 1 1 d . . . . .
C25 C -0.0875(2) 0.33045(16) 0.49642(6) 0.0326(4) Uani 1 1 d . . . . .
H25A H -0.1840 0.2937 0.4764 0.049 Uiso 1 1 calc R U . . .
H25B H -0.0945 0.4043 0.4891 0.049 Uiso 1 1 calc R U . . .
H25C H -0.1049 0.3199 0.5294 0.049 Uiso 1 1 calc R U . . .
O1 O 0.1869(2) 0.23504(12) 0.51589(5) 0.0443(4) Uani 1 1 d . . . . .
C1 C 0.96435(18) 0.17810(10) 0.72779(5) 0.0135(2) Uani 1 1 d . . . . .
C2 C 0.97641(19) 0.09853(11) 0.76040(5) 0.0164(3) Uani 1 1 d . . . . .
C3 C 1.06889(19) 0.10925(12) 0.80501(5) 0.0189(3) Uani 1 1 d . . . . .
H3 H 1.0734 0.0541 0.8269 0.023 Uiso 1 1 calc R U . . .
C4 C 1.1548(2) 0.20259(12) 0.81690(5) 0.0204(3) Uani 1 1 d . . . . .
H4 H 1.2220 0.2111 0.8470 0.024 Uiso 1 1 calc R U . . .
C5 C 1.1435(2) 0.28396(12) 0.78505(5) 0.0199(3) Uani 1 1 d . . . . .
H5 H 1.2024 0.3477 0.7936 0.024 Uiso 1 1 calc R U . . .
C6 C 1.04645(19) 0.27232(11) 0.74080(5) 0.0162(3) Uani 1 1 d . . . . .
H6 H 1.0361 0.3286 0.7194 0.019 Uiso 1 1 calc R U . . .
C7 C 0.91593(18) 0.09242(11) 0.65526(5) 0.0162(3) Uani 1 1 d . . . . .
H7 H 1.0073 0.0434 0.6665 0.019 Uiso 1 1 calc R U . . .
C8 C 0.82373(18) 0.08754(11) 0.60784(5) 0.0152(2) Uani 1 1 d . . . . .
C9 C 0.60555(19) 0.16595(11) 0.55441(5) 0.0174(3) Uani 1 1 d . . . . .
H9 H 0.5139 0.2173 0.5471 0.021 Uiso 1 1 calc R U . . .
C10 C 0.6446(2) 0.09750(12) 0.51947(5) 0.0215(3) Uani 1 1 d . . . . .
H10 H 0.5810 0.1029 0.4888 0.026 Uiso 1 1 calc R U . . .
C11 C 0.7762(2) 0.02170(12) 0.52974(5) 0.0232(3) Uani 1 1 d . . . . .
H11 H 0.8036 -0.0259 0.5063 0.028 Uiso 1 1 calc R U . . .
C12 C 0.8677(2) 0.01627(12) 0.57480(5) 0.0213(3) Uani 1 1 d . . . . .
H12 H 0.9586 -0.0352 0.5829 0.026 Uiso 1 1 calc R U . . .
C13 C 0.45898(18) 0.39326(10) 0.64335(5) 0.0138(2) Uani 1 1 d . . . . .
C14 C 0.36734(18) 0.30125(11) 0.62899(5) 0.0145(2) Uani 1 1 d . . . . .
H14 H 0.2978 0.2977 0.5989 0.017 Uiso 1 1 calc R U . . .
C15 C 0.37743(18) 0.21297(11) 0.65902(5) 0.0149(2) Uani 1 1 d . . . . .
H15 H 0.3187 0.1506 0.6481 0.018 Uiso 1 1 calc R U . . .
C16 C 0.47334(19) 0.21686(11) 0.70469(5) 0.0152(3) Uani 1 1 d . . . . .
C17 C 0.56286(19) 0.31154(11) 0.71980(5) 0.0153(3) Uani 1 1 d . . . . .
H17 H 0.6264 0.3166 0.7505 0.018 Uiso 1 1 calc R U . . .
C18 C 0.55750(18) 0.39651(10) 0.68971(5) 0.0146(2) Uani 1 1 d . . . . .
H18 H 0.6205 0.4579 0.7001 0.017 Uiso 1 1 calc R U . . .
C19 C 0.45954(19) 0.48809(11) 0.61267(5) 0.0160(3) Uani 1 1 d . . . . .
H19 H 0.5773 0.5260 0.6220 0.019 Uiso 1 1 calc R U . . .
C20 C 0.4495(2) 0.46452(12) 0.56042(5) 0.0253(3) Uani 1 1 d . . . . .
H20A H 0.4505 0.5293 0.5428 0.038 Uiso 1 1 calc R U . . .
H20B H 0.5560 0.4225 0.5545 0.038 Uiso 1 1 calc R U . . .
H20C H 0.3357 0.4266 0.5503 0.038 Uiso 1 1 calc R U . . .
C21 C 0.3006(2) 0.55837(11) 0.62313(5) 0.0221(3) Uani 1 1 d . . . . .
H21A H 0.2989 0.6204 0.6035 0.033 Uiso 1 1 calc R U . . .
H21B H 0.1835 0.5214 0.6163 0.033 Uiso 1 1 calc R U . . .
H21C H 0.3177 0.5784 0.6563 0.033 Uiso 1 1 calc R U . . .
C22 C 0.4856(2) 0.12441(11) 0.73640(5) 0.0197(3) Uani 1 1 d . . . . .
H22A H 0.3730 0.1192 0.7518 0.030 Uiso 1 1 calc R U . . .
H22B H 0.5923 0.1317 0.7603 0.030 Uiso 1 1 calc R U . . .
H22C H 0.4996 0.0619 0.7179 0.030 Uiso 1 1 calc R U . . .
F1 F 0.89194(13) 0.00775(7) 0.74847(3) 0.02501(19) Uani 1 1 d . . . . .
F2 F 0.49083(18) 0.82957(10) 0.59316(4) 0.0432(3) Uani 1 1 d . . . . .
F3 F 0.19196(16) 0.83020(8) 0.60659(4) 0.0407(3) Uani 1 1 d . . . . .
F4 F 0.33518(16) 0.98103(8) 0.59499(4) 0.0376(3) Uani 1 1 d . . . . .
F5 F 0.55918(13) 0.94162(8) 0.65351(4) 0.0299(2) Uani 1 1 d . . . . .
F6 F 0.26128(14) 0.94113(8) 0.66716(4) 0.0333(2) Uani 1 1 d . . . . .
F7 F 0.41625(14) 0.79047(7) 0.66533(3) 0.0264(2) Uani 1 1 d . . . . .
P3 P 0.37645(5) 0.88512(3) 0.63004(2) 0.01883(8) Uani 1 1 d . . . . .
Cl2 Cl 0.89479(4) 0.36426(3) 0.62383(2) 0.01570(6) Uani 1 1 d . . . . .
Ru1 Ru 0.65734(2) 0.26281(2) 0.65280(2) 0.01010(3) Uani 1 1 d . . . . .
N1 N 0.86875(15) 0.16607(9) 0.68160(4) 0.0128(2) Uani 1 1 d . . . . .
N2 N 0.69313(15) 0.16166(9) 0.59806(4) 0.0136(2) Uani 1 1 d . . . . .
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C24 C23 122.46(17) . .
O1 C24 C25 121.57(17) . .
C23 C24 C25 115.96(15) . .
C2 C1 C6 118.60(12) . .
C2 C1 N1 121.93(12) . .
C6 C1 N1 119.47(12) . .
F1 C2 C3 118.73(12) . .
F1 C2 C1 118.89(12) . .
C3 C2 C1 122.38(13) . .
C2 C3 C4 118.27(13) . .
C3 C4 C5 120.55(13) . .
C6 C5 C4 120.24(14) . .
C5 C6 C1 119.92(13) . .
N1 C7 C8 117.19(12) . .
N2 C8 C12 122.78(13) . .
N2 C8 C7 113.67(12) . .
C12 C8 C7 123.51(13) . .
N2 C9 C10 122.11(14) . .
C11 C10 C9 119.63(14) . .
C10 C11 C12 118.86(14) . .
C11 C12 C8 118.61(14) . .
C14 C13 C18 117.80(12) . .
C14 C13 C19 123.49(12) . .
C18 C13 C19 118.71(12) . .
C14 C13 Ru1 70.87(8) . .
C18 C13 Ru1 70.14(7) . .
C19 C13 Ru1 130.02(9) . .
C13 C14 C15 120.84(12) . .
C13 C14 Ru1 72.13(7) . .
C15 C14 Ru1 69.65(7) . .
C16 C15 C14 121.07(13) . .
C16 C15 Ru1 72.30(8) . .
C14 C15 Ru1 72.25(8) . .
C15 C16 C17 118.08(12) . .
C15 C16 C22 121.48(13) . .
C17 C16 C22 120.43(12) . .
C15 C16 Ru1 69.99(8) . .
C17 C16 Ru1 71.36(7) . .
C22 C16 Ru1 128.92(10) . .
C18 C17 C16 120.54(12) . .
C18 C17 Ru1 71.08(8) . .
C16 C17 Ru1 70.72(7) . .
C17 C18 C13 121.62(13) . .
C17 C18 Ru1 71.97(8) . .
C13 C18 Ru1 71.90(7) . .
C13 C19 C20 114.05(12) . .
C13 C19 C21 108.36(11) . .
C20 C19 C21 111.18(12) . .
F2 P3 F7 90.23(6) . .
F2 P3 F5 90.57(7) . .
F7 P3 F5 90.17(5) . .
F2 P3 F3 90.05(7) . .
F7 P3 F3 90.44(6) . .
F5 P3 F3 179.13(6) . .
F2 P3 F4 90.43(6) . .
F7 P3 F4 179.33(6) . .
F5 P3 F4 89.79(6) . .
F3 P3 F4 89.60(6) . .
F2 P3 F6 179.95(8) . .
F7 P3 F6 89.81(6) . .
F5 P3 F6 89.42(6) . .
F3 P3 F6 89.96(6) . .
F4 P3 F6 89.52(6) . .
N1 Ru1 N2 76.63(4) . .
N1 Ru1 C15 116.74(5) . .
N2 Ru1 C15 94.42(5) . .
N1 Ru1 C18 123.69(5) . .
N2 Ru1 C18 159.33(5) . .
C15 Ru1 C18 79.99(5) . .
N1 Ru1 C16 92.96(5) . .
N2 Ru1 C16 118.68(5) . .
C15 Ru1 C16 37.71(5) . .
C18 Ru1 C16 67.91(5) . .
N1 Ru1 C14 154.08(5) . .
N2 Ru1 C14 96.23(5) . .
C15 Ru1 C14 38.10(5) . .
C18 Ru1 C14 67.10(5) . .
C16 Ru1 C14 68.32(5) . .
N1 Ru1 C17 96.82(5) . .
N2 Ru1 C17 156.13(5) . .
C15 Ru1 C17 67.71(5) . .
C18 Ru1 C17 36.95(5) . .
C16 Ru1 C17 37.91(5) . .
C14 Ru1 C17 79.58(5) . .
N1 Ru1 C13 161.53(5) . .
N2 Ru1 C13 121.54(5) . .
C15 Ru1 C13 68.24(5) . .
C18 Ru1 C13 37.96(5) . .
C16 Ru1 C13 81.22(5) . .
C14 Ru1 C13 37.00(5) . .
C17 Ru1 C13 67.89(5) . .
N1 Ru1 Cl2 86.26(3) . .
N2 Ru1 Cl2 85.63(3) . .
C15 Ru1 Cl2 156.43(4) . .
C18 Ru1 Cl2 91.68(4) . .
C16 Ru1 Cl2 154.84(4) . .
C14 Ru1 Cl2 118.40(4) . .
C17 Ru1 Cl2 117.18(4) . .
C13 Ru1 Cl2 91.64(4) . .
C7 N1 C1 119.24(11) . .
C7 N1 Ru1 116.68(9) . .
C1 N1 Ru1 124.07(9) . .
C9 N2 C8 117.99(12) . .
C9 N2 Ru1 126.18(10) . .
C8 N2 Ru1 115.77(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C23 C24 1.496(2) .
C24 O1 1.210(2) .
C24 C25 1.496(2) .
C1 C2 1.3883(19) .
C1 C6 1.3917(19) .
C1 N1 1.4333(16) .
C2 F1 1.3535(16) .
C2 C3 1.383(2) .
C3 C4 1.387(2) .
C4 C5 1.392(2) .
C5 C6 1.3887(19) .
C7 N1 1.2890(18) .
C7 C8 1.4480(19) .
C8 N2 1.3596(17) .
C8 C12 1.3879(19) .
C9 N2 1.3399(17) .
C9 C10 1.393(2) .
C10 C11 1.382(2) .
C11 C12 1.387(2) .
C13 C14 1.4051(19) .
C13 C18 1.4378(18) .
C13 C19 1.5118(18) .
C13 Ru1 2.2219(13) .
C14 C15 1.4289(19) .
C14 Ru1 2.2057(13) .
C15 C16 1.4136(19) .
C15 Ru1 2.1714(13) .
C16 C17 1.433(2) .
C16 C22 1.5007(19) .
C16 Ru1 2.2016(13) .
C17 C18 1.3970(19) .
C17 Ru1 2.2100(13) .
C18 Ru1 2.1987(13) .
C19 C20 1.524(2) .
C19 C21 1.5325(19) .
F2 P3 1.5949(11) .
F3 P3 1.6012(11) .
F4 P3 1.6051(10) .
F5 P3 1.6004(10) .
F6 P3 1.6058(10) .
F7 P3 1.5954(10) .
Cl2 Ru1 2.4008(3) .
Ru1 N1 2.0835(11) .
Ru1 N2 2.0858(11) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C25 H25C Cl2 0.98 2.77 3.7011(17) 158.7 1_455
C3 H3 Cl2 0.95 2.83 3.7668(15) 167.9 2_746
C6 H6 F1 0.95 2.53 3.0929(16) 118.1 2_756
C7 H7 F6 0.95 2.28 3.1812(17) 158.6 1_645
C9 H9 O1 0.95 2.46 3.254(2) 140.8 .
C10 H10 F2 0.95 2.51 3.4028(19) 157.3 3_666
C12 H12 F3 0.95 2.48 3.4275(19) 178.1 1_645
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C6 C1 C2 F1 177.95(12) . . . .
N1 C1 C2 F1 -1.4(2) . . . .
C6 C1 C2 C3 -0.8(2) . . . .
N1 C1 C2 C3 179.77(13) . . . .
F1 C2 C3 C4 -179.95(13) . . . .
C1 C2 C3 C4 -1.2(2) . . . .
C2 C3 C4 C5 1.7(2) . . . .
C3 C4 C5 C6 -0.3(2) . . . .
C4 C5 C6 C1 -1.7(2) . . . .
C2 C1 C6 C5 2.3(2) . . . .
N1 C1 C6 C5 -178.32(13) . . . .
N1 C7 C8 N2 -1.85(19) . . . .
N1 C7 C8 C12 176.18(14) . . . .
N2 C9 C10 C11 0.6(2) . . . .
C9 C10 C11 C12 -0.5(2) . . . .
C10 C11 C12 C8 -0.2(2) . . . .
N2 C8 C12 C11 0.8(2) . . . .
C7 C8 C12 C11 -177.03(14) . . . .
C18 C13 C14 C15 -2.07(19) . . . .
C19 C13 C14 C15 177.74(12) . . . .
Ru1 C13 C14 C15 51.83(11) . . . .
C18 C13 C14 Ru1 -53.90(10) . . . .
C19 C13 C14 Ru1 125.92(12) . . . .
C13 C14 C15 C16 2.6(2) . . . .
Ru1 C14 C15 C16 55.56(11) . . . .
C13 C14 C15 Ru1 -52.94(11) . . . .
C14 C15 C16 C17 -0.97(19) . . . .
Ru1 C15 C16 C17 54.57(11) . . . .
C14 C15 C16 C22 -179.66(12) . . . .
Ru1 C15 C16 C22 -124.12(12) . . . .
C14 C15 C16 Ru1 -55.54(11) . . . .
C15 C16 C17 C18 -1.13(19) . . . .
C22 C16 C17 C18 177.57(12) . . . .
Ru1 C16 C17 C18 52.76(11) . . . .
C15 C16 C17 Ru1 -53.90(11) . . . .
C22 C16 C17 Ru1 124.81(12) . . . .
C16 C17 C18 C13 1.7(2) . . . .
Ru1 C17 C18 C13 54.26(11) . . . .
C16 C17 C18 Ru1 -52.60(11) . . . .
C14 C13 C18 C17 -0.04(19) . . . .
C19 C13 C18 C17 -179.87(12) . . . .
Ru1 C13 C18 C17 -54.29(11) . . . .
C14 C13 C18 Ru1 54.25(11) . . . .
C19 C13 C18 Ru1 -125.57(11) . . . .
C14 C13 C19 C20 -31.38(19) . . . .
C18 C13 C19 C20 148.43(13) . . . .
Ru1 C13 C19 C20 61.05(17) . . . .
C14 C13 C19 C21 93.02(15) . . . .
C18 C13 C19 C21 -87.17(15) . . . .
Ru1 C13 C19 C21 -174.55(10) . . . .
C8 C7 N1 C1 -176.02(12) . . . .
C8 C7 N1 Ru1 2.88(16) . . . .
C2 C1 N1 C7 -56.15(18) . . . .
C6 C1 N1 C7 124.47(14) . . . .
C2 C1 N1 Ru1 125.04(12) . . . .
C6 C1 N1 Ru1 -54.34(16) . . . .
C10 C9 N2 C8 0.0(2) . . . .
C10 C9 N2 Ru1 177.06(11) . . . .
C12 C8 N2 C9 -0.7(2) . . . .
C7 C8 N2 C9 177.33(12) . . . .
C12 C8 N2 Ru1 -178.11(11) . . . .
C7 C8 N2 Ru1 -0.06(15) . . . .
