#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/17/2221737.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2221737
loop_
_publ_author_name
'Huck, Lawrence A.'
'Potter, Gregory D.'
'Jenkins, Hilary A.'
'Britten, James F.'
'Leigh, William J.'
_publ_section_title
;
 1,1-Bis[4-(trifluoromethyl)phenyl]germetane
;
_journal_coeditor_code           IM2108
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m602
_journal_paper_doi               10.1107/S1600536809015268
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac          '[Ge (C3 H6) (C7 H4 F3)2]'
_chemical_formula_moiety         'C17 H14 F6 Ge'
_chemical_formula_sum            'C17 H14 F6 Ge'
_chemical_formula_weight         404.87
_chemical_melting_point          319
_chemical_name_systematic
;
1,1-Bis[4-(trifluoromethyl)phenyl]germetane
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.081(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.596(6)
_cell_length_b                   6.412(3)
_cell_length_c                   20.243(9)
_cell_measurement_reflns_used    5916
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.640
_cell_measurement_theta_min      3.543
_cell_volume                     1686.9(13)
_computing_cell_refinement       'SAINT (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        'SAINT (Bruker, 1997)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0525
_diffrn_reflns_av_sigmaI/netI    0.0657
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            14478
_diffrn_reflns_theta_full        27.54
_diffrn_reflns_theta_max         27.54
_diffrn_reflns_theta_min         1.61
_exptl_absorpt_coefficient_mu    1.872
_exptl_absorpt_correction_T_max  0.688
_exptl_absorpt_correction_T_min  0.484
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.594
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             808
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.38
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.679
_refine_diff_density_min         -0.608
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.990
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     258
_refine_ls_number_reflns         3867
_refine_ls_number_restraints     19
_refine_ls_restrained_S_all      1.001
_refine_ls_R_factor_all          0.0909
_refine_ls_R_factor_gt           0.0405
_refine_ls_shift/su_max          0.022
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0275P)²+2.3419P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0794
_refine_ls_wR_factor_ref         0.0970
_reflns_number_gt                2378
_reflns_number_total             3867
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            im2108.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1687.0(10)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2221737
_cod_database_fobs_code          2221737
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge Ge1A 0.88719(3) 0.20119(6) 0.19017(2) 0.03626(13) Uani d PD 0.396(14) A 2
C C15A 0.7582(7) 0.347(4) 0.1861(18) 0.049(3) Uani d PD 0.396(14) A 2
H H15C 0.7483 0.3738 0.2319 0.058 Uiso calc PR 0.396(14) A 2
H H15D 0.7466 0.4755 0.1576 0.058 Uiso calc PR 0.396(14) A 2
C C16A 0.6994(5) 0.152(3) 0.1482(9) 0.058(3) Uani d PD 0.396(14) A 2
H H16C 0.6402 0.1931 0.1086 0.070 Uiso calc PR 0.396(14) A 2
H H16D 0.6745 0.0638 0.1801 0.070 Uiso calc PR 0.396(14) A 2
C C17A 0.7845(7) 0.034(4) 0.1227(15) 0.0493(15) Uani d PD 0.396(14) A 2
H H17C 0.7811 0.0624 0.0740 0.059 Uiso calc PR 0.396(14) A 2
H H17D 0.7889 -0.1177 0.1325 0.059 Uiso calc PR 0.396(14) A 2
Ge Ge1 0.88719(3) 0.20119(6) 0.19017(2) 0.03626(13) Uani d PD 0.604(14) A 1
C C15 0.7486(5) 0.302(3) 0.1857(11) 0.049(3) Uani d PD 0.604(14) A 1
H H15A 0.7232 0.2525 0.2240 0.058 Uiso calc PR 0.604(14) A 1
H H15B 0.7400 0.4551 0.1796 0.058 Uiso calc PR 0.604(14) A 1
C C16 0.7073(5) 0.1749(18) 0.1173(6) 0.058(3) Uani d PD 0.604(14) A 1
H H16A 0.6958 0.2660 0.0763 0.070 Uiso calc PR 0.604(14) A 1
H H16B 0.6424 0.1022 0.1156 0.070 Uiso calc PR 0.604(14) A 1
C C17 0.7979(11) 0.013(6) 0.122(2) 0.0493(15) Uani d PD 0.604(14) A 1
H H17A 0.8172 -0.0008 0.0786 0.059 Uiso calc PR 0.604(14) A 1
H H17B 0.7874 -0.1249 0.1407 0.059 Uiso calc PR 0.604(14) A 1
C C1 0.9675(3) 0.0705(5) 0.27568(18) 0.0341(8) Uani d . 1 . .
C C2 1.0113(3) -0.1241(6) 0.2752(2) 0.0445(9) Uani d . 1 A .
H H2A 1.0030 -0.1936 0.2324 0.053 Uiso calc R 1 . .
C C3 1.0670(3) -0.2189(6) 0.3359(2) 0.0485(10) Uani d . 1 . .
H H3A 1.0965 -0.3526 0.3346 0.058 Uiso calc R 1 A .
C C4 1.0799(3) -0.1212(6) 0.39821(19) 0.0407(9) Uani d . 1 A .
C C5 1.0369(3) 0.0734(6) 0.3998(2) 0.0471(10) Uani d . 1 . .
H H5A 1.0456 0.1424 0.4427 0.056 Uiso calc R 1 A .
C C6 0.9812(3) 0.1671(5) 0.3389(2) 0.0444(9) Uani d . 1 A .
H H6A 0.9517 0.3006 0.3404 0.053 Uiso calc R 1 . .
C C8 0.9769(3) 0.3844(5) 0.15718(18) 0.0379(8) Uani d . 1 . .
C C9 1.0823(3) 0.3923(6) 0.1889(2) 0.0470(10) Uani d . 1 A .
H H9A 1.1126 0.3007 0.2262 0.056 Uiso calc R 1 . .
C C10 1.1437(3) 0.5314(6) 0.1669(2) 0.0510(10) Uani d . 1 . .
H H10A 1.2158 0.5345 0.1889 0.061 Uiso calc R 1 A .
C C11 1.1000(3) 0.6659(6) 0.1130(2) 0.0448(9) Uani d . 1 A .
C C12 0.9955(3) 0.6588(6) 0.0806(2) 0.0512(10) Uani d . 1 . .
H H12A 0.9653 0.7506 0.0433 0.061 Uiso calc R 1 A .
C C13 0.9352(3) 0.5183(6) 0.1024(2) 0.0471(10) Uani d . 1 A .
H H13A 0.8635 0.5130 0.0795 0.057 Uiso calc R 1 . .
C C7 1.1400(4) -0.2268(7) 0.4628(2) 0.0561(11) Uani d PD 0.604(14) A 1
F F1 1.1175(11) -0.4307(12) 0.4626(7) 0.083(3) Uani d PD 0.604(14) A 1
F F2 1.1343(13) -0.146(2) 0.5219(6) 0.078(4) Uani d PD 0.604(14) A 1
F F3 1.2396(5) -0.227(3) 0.4671(8) 0.072(3) Uani d PD 0.604(14) A 1
C C7A 1.1400(4) -0.2268(7) 0.4628(2) 0.0561(11) Uani d PD 0.396(14) A 2
F F1A 1.0871(16) -0.380(3) 0.4803(12) 0.106(7) Uani d PD 0.396(14) A 2
F F2A 1.1506(18) -0.091(3) 0.5158(8) 0.070(5) Uani d PD 0.396(14) A 2
F F3A 1.2337(11) -0.281(4) 0.4667(12) 0.091(8) Uani d PD 0.396(14) A 2
C C14 1.1663(3) 0.8216(7) 0.0908(2) 0.0589(11) Uani d PD 0.410(6) A 1
F F4 1.1154(5) 1.0064(10) 0.0742(5) 0.0613(7) Uiso d PD 0.410(6) A 1
F F5 1.1939(6) 0.7630(11) 0.0372(4) 0.0613(7) Uiso d PD 0.410(6) A 1
F F6 1.2236(6) 0.9328(12) 0.1444(3) 0.0613(7) Uiso d PD 0.410(6) A 1
C C14' 1.1663(3) 0.8216(7) 0.0908(2) 0.0589(11) Uani d P 0.411(6) A 2
F F4' 1.1110(5) 0.9575(12) 0.0424(5) 0.0613(7) Uiso d P 0.411(6) A 2
F F5' 1.2282(6) 0.7196(11) 0.0569(4) 0.0613(7) Uiso d P 0.411(6) A 2
F F6' 1.2569(6) 0.8560(12) 0.1386(4) 0.0613(7) Uiso d P 0.411(6) A 2
C C14A 1.1663(3) 0.8216(7) 0.0908(2) 0.0589(11) Uani d PD 0.179(3) A 3
F F4A 1.1322(12) 0.867(2) 0.0240(6) 0.0613(7) Uiso d PD 0.179(3) A 3
F F5A 1.2639(10) 0.769(2) 0.1061(9) 0.0613(7) Uiso d PD 0.179(3) A 3
F F6A 1.1623(13) 1.0042(19) 0.1205(9) 0.0613(7) Uiso d PD 0.179(3) A 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C1 Ge1A C8 . . 108.72(15) ?
C1 Ge1A C17A . . 118.9(11) ?
C8 Ge1A C17A . . 118.7(11) ?
C1 Ge1A C15A . . 120.2(12) ?
C8 Ge1A C15A . . 109.8(11) ?
C17A Ge1A C15A . . 77.8(3) ?
C1 Ge1A C16A . . 120.4(4) ?
C8 Ge1A C16A . . 130.5(4) ?
C16A C15A Ge1A . . 87.7(4) ?
C16A C15A H15C . . 114.0 ?
Ge1A C15A H15C . . 114.0 ?
C16A C15A H15D . . 114.0 ?
Ge1A C15A H15D . . 114.0 ?
H15C C15A H15D . . 111.2 ?
C15A C16A C17A . . 103.0(8) ?
C15A C16A Ge1A . . 53.0(3) ?
C17A C16A Ge1A . . 52.7(2) ?
C15A C16A H16C . . 111.2 ?
C17A C16A H16C . . 111.2 ?
Ge1A C16A H16C . . 139.4 ?
C15A C16A H16D . . 111.2 ?
C17A C16A H16D . . 111.2 ?
Ge1A C16A H16D . . 111.5 ?
H16C C16A H16D . . 109.1 ?
C16A C17A Ge1A . . 87.1(5) ?
C16A C17A H17C . . 114.1 ?
Ge1A C17A H17C . . 114.1 ?
C16A C17A H17D . . 114.1 ?
Ge1A C17A H17D . . 114.1 ?
H17C C17A H17D . . 111.3 ?
C16 C15 H15A . . 114.1 ?
C16 C15 H15B . . 114.1 ?
H15A C15 H15B . . 111.2 ?
C15 C16 C17 . . 102.6(8) ?
C15 C16 H16A . . 111.2 ?
C17 C16 H16A . . 111.2 ?
C15 C16 H16B . . 111.2 ?
C17 C16 H16B . . 111.2 ?
H16A C16 H16B . . 109.2 ?
C16 C17 H17A . . 114.1 ?
C16 C17 H17B . . 114.1 ?
H17A C17 H17B . . 111.3 ?
C6 C1 C2 . . 117.9(3) ?
C6 C1 Ge1A . . 121.2(3) ?
C2 C1 Ge1A . . 120.8(3) ?
C3 C2 C1 . . 121.0(3) ?
C3 C2 H2A . . 119.5 ?
C1 C2 H2A . . 119.5 ?
C4 C3 C2 . . 120.4(3) ?
C4 C3 H3A . . 119.8 ?
C2 C3 H3A . . 119.8 ?
C3 C4 C5 . . 119.5(3) ?
C3 C4 C7 . . 119.3(3) ?
C5 C4 C7 . . 121.2(4) ?
C6 C5 C4 . . 119.8(3) ?
C6 C5 H5A . . 120.1 ?
C4 C5 H5A . . 120.1 ?
C5 C6 C1 . . 121.4(3) ?
C5 C6 H6A . . 119.3 ?
C1 C6 H6A . . 119.3 ?
C13 C8 C9 . . 118.1(4) ?
C13 C8 Ge1A . . 119.9(3) ?
C9 C8 Ge1A . . 121.9(3) ?
C10 C9 C8 . . 120.9(4) ?
C10 C9 H9A . . 119.5 ?
C8 C9 H9A . . 119.5 ?
C9 C10 C11 . . 119.9(4) ?
C9 C10 H10A . . 120.1 ?
C11 C10 H10A . . 120.1 ?
C12 C11 C10 . . 119.8(4) ?
C12 C11 C14 . . 120.4(4) ?
C10 C11 C14 . . 119.8(4) ?
C13 C12 C11 . . 119.8(4) ?
C13 C12 H12A . . 120.1 ?
C11 C12 H12A . . 120.1 ?
C12 C13 C8 . . 121.4(4) ?
C12 C13 H13A . . 119.3 ?
C8 C13 H13A . . 119.3 ?
F2 C7 F3 . . 105.6(9) ?
F2 C7 F1 . . 108.0(9) ?
F3 C7 F1 . . 103.0(9) ?
F2 C7 C4 . . 117.0(7) ?
F3 C7 C4 . . 110.1(8) ?
F1 C7 C4 . . 112.0(7) ?
F5 C14 F6 . . 125.9(6) ?
F5 C14 F4 . . 107.2(5) ?
F6 C14 F4 . . 82.5(6) ?
F5 C14 C11 . . 113.7(5) ?
F6 C14 C11 . . 111.6(4) ?
F4 C14 C11 . . 110.2(4) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ge1A C1 . 1.944(3) ?
Ge1A C8 . 1.947(4) ?
Ge1A C17A . 1.961(4) ?
Ge1A C15A . 1.969(5) ?
Ge1A C16A . 2.463(6) ?
C15A C16A . 1.562(11) ?
C15A H15C . 0.9900 ?
C15A H15D . 0.9900 ?
C16A C17A . 1.591(13) ?
C16A H16C . 0.9900 ?
C16A H16D . 0.9900 ?
C17A H17C . 0.9900 ?
C17A H17D . 0.9900 ?
C15 C16 . 1.563(11) ?
C15 H15A . 0.9900 ?
C15 H15B . 0.9900 ?
C16 C17 . 1.591(13) ?
C16 H16A . 0.9900 ?
C16 H16B . 0.9900 ?
C17 H17A . 0.9900 ?
C17 H17B . 0.9900 ?
C1 C6 . 1.383(5) ?
C1 C2 . 1.385(5) ?
C2 C3 . 1.381(5) ?
C2 H2A . 0.9500 ?
C3 C4 . 1.372(5) ?
C3 H3A . 0.9500 ?
C4 C5 . 1.382(5) ?
C4 C7 . 1.486(5) ?
C5 C6 . 1.381(5) ?
C5 H5A . 0.9500 ?
C6 H6A . 0.9500 ?
C8 C13 . 1.384(5) ?
C8 C9 . 1.389(5) ?
C9 C10 . 1.381(5) ?
C9 H9A . 0.9500 ?
C10 C11 . 1.382(5) ?
C10 H10A . 0.9500 ?
C11 C12 . 1.379(5) ?
C11 C14 . 1.500(6) ?
C12 C13 . 1.376(5) ?
C12 H12A . 0.9500 ?
C13 H13A . 0.9500 ?
C7 F2 . 1.326(9) ?
C7 F3 . 1.331(9) ?
C7 F1 . 1.342(9) ?
C14 F5 . 1.302(8) ?
C14 F6 . 1.340(7) ?
C14 F4 . 1.363(7) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C1 Ge1A C15A C16A . . . . -102.4(14) ?
C8 Ge1A C15A C16A . . . . 130.5(14) ?
C17A Ge1A C15A C16A . . . . 14(2) ?
Ge1A C15A C16A C17A . . . . -18(2) ?
C1 Ge1A C16A C15A . . . . 102(2) ?
C8 Ge1A C16A C15A . . . . -70(2) ?
C17A Ge1A C16A C15A . . . . -158(3) ?
C1 Ge1A C16A C17A . . . . -100.0(19) ?
C8 Ge1A C16A C17A . . . . 88.2(19) ?
C15A Ge1A C16A C17A . . . . 158(3) ?
C15A C16A C17A Ge1A . . . . 18(2) ?
C1 Ge1A C17A C16A . . . . 104.0(13) ?
C8 Ge1A C17A C16A . . . . -119.9(14) ?
C15A Ge1A C17A C16A . . . . -13.9(19) ?
C8 Ge1A C1 C6 . . . . 86.7(3) ?
C17A Ge1A C1 C6 . . . . -133.3(7) ?
C15A Ge1A C1 C6 . . . . -40.9(8) ?
C16A Ge1A C1 C6 . . . . -86.8(6) ?
C8 Ge1A C1 C2 . . . . -94.4(3) ?
C17A Ge1A C1 C2 . . . . 45.6(7) ?
C15A Ge1A C1 C2 . . . . 138.0(8) ?
C16A Ge1A C1 C2 . . . . 92.1(6) ?
C6 C1 C2 C3 . . . . 0.0(6) ?
Ge1A C1 C2 C3 . . . . -178.9(3) ?
C1 C2 C3 C4 . . . . 0.0(6) ?
C2 C3 C4 C5 . . . . -0.1(6) ?
C2 C3 C4 C7 . . . . 179.9(4) ?
C3 C4 C5 C6 . . . . 0.2(6) ?
C7 C4 C5 C6 . . . . -179.8(4) ?
C4 C5 C6 C1 . . . . -0.2(6) ?
C2 C1 C6 C5 . . . . 0.1(6) ?
Ge1A C1 C6 C5 . . . . 179.0(3) ?
C1 Ge1A C8 C13 . . . . -170.8(3) ?
C17A Ge1A C8 C13 . . . . 49.1(6) ?
C15A Ge1A C8 C13 . . . . -37.5(9) ?
C16A Ge1A C8 C13 . . . . 1.8(7) ?
C1 Ge1A C8 C9 . . . . 6.4(4) ?
C17A Ge1A C8 C9 . . . . -133.7(6) ?
C15A Ge1A C8 C9 . . . . 139.7(9) ?
C16A Ge1A C8 C9 . . . . 179.0(7) ?
C13 C8 C9 C10 . . . . 0.7(6) ?
Ge1A C8 C9 C10 . . . . -176.5(3) ?
C8 C9 C10 C11 . . . . 0.4(6) ?
C9 C10 C11 C12 . . . . -0.9(6) ?
C9 C10 C11 C14 . . . . 178.0(4) ?
C10 C11 C12 C13 . . . . 0.3(6) ?
C14 C11 C12 C13 . . . . -178.6(4) ?
C11 C12 C13 C8 . . . . 0.9(6) ?
C9 C8 C13 C12 . . . . -1.4(6) ?
Ge1A C8 C13 C12 . . . . 175.9(3) ?
C3 C4 C7 F2 . . . . -167.6(9) ?
C5 C4 C7 F2 . . . . 12.3(10) ?
C3 C4 C7 F3 . . . . 71.9(9) ?
C5 C4 C7 F3 . . . . -108.2(9) ?
C3 C4 C7 F1 . . . . -42.2(8) ?
C5 C4 C7 F1 . . . . 137.8(7) ?
C12 C11 C14 F5 . . . . -82.7(6) ?
C10 C11 C14 F5 . . . . 98.4(6) ?
C12 C11 C14 F6 . . . . 127.5(6) ?
C10 C11 C14 F6 . . . . -51.4(7) ?
C12 C11 C14 F4 . . . . 37.7(7) ?
C10 C11 C14 F4 . . . . -141.2(6) ?
