#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/89/2228931.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2228931
loop_
_publ_author_name
'Wang, Zhi-Wei'
'Qiao, Peng'
'Wang, Zi-Jia'
'Wan, Chong-Qing'
_publ_section_title
;
 [N-Benzyl-N-(diphenylphosphanylmethyl)pyridin-2-amine]chloridomethylplatinum(II)
;
_journal_coeditor_code           ZQ2076
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m36
_journal_paper_doi               10.1107/S1600536810049652
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Pt (CH3) Cl (C25 H23 N2 P)]'
_chemical_formula_moiety         'C26 H26 Cl N2 P Pt'
_chemical_formula_sum            'C26 H26 Cl N2 P Pt'
_chemical_formula_weight         628.00
_chemical_name_systematic
;[N-Benzyl-N-(diphenylphosphanylmethyl)pyridin-2-
amine]chloridomethylplatinum(II)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                98.367(4)
_cell_angle_beta                 106.256(4)
_cell_angle_gamma                107.266(5)
_cell_formula_units_Z            2
_cell_length_a                   9.538(3)
_cell_length_b                   10.770(3)
_cell_length_c                   13.125(4)
_cell_measurement_temperature    293(2)
_cell_volume                     1197.0(6)
_computing_cell_refinement       'APEX2 and SAINT (Bruker, 2007)'
_computing_data_collection       'APEX2 (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material
'SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0410
_diffrn_reflns_av_sigmaI/netI    0.0831
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            6265
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.29
_exptl_absorpt_coefficient_mu    6.056
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.675
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2007)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.742
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             612
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.20
_refine_diff_density_max         2.178
_refine_diff_density_min         -2.328
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     281
_refine_ls_number_reflns         4201
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0718
_refine_ls_R_factor_gt           0.0497
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0650P)²] P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1107
_refine_ls_wR_factor_ref         0.1233
_reflns_number_gt                3270
_reflns_number_total             4201
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            zq2076.cif
_cod_data_source_block           I
_cod_database_code               2228931
_cod_database_fobs_code          2228931
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt1 0.99999(4) 0.54883(4) 0.70540(3) 0.03520(15) Uani d . 1 . .
Cl Cl1 1.1825(3) 0.4495(3) 0.6820(3) 0.0641(8) Uani d . 1 . .
P P1 0.8409(3) 0.6473(2) 0.73503(19) 0.0340(5) Uani d . 1 . .
N N1 0.8123(9) 0.3822(8) 0.5717(6) 0.0402(19) Uani d . 1 . .
N N2 0.6167(9) 0.4091(8) 0.6379(7) 0.048(2) Uani d . 1 . .
C C1 1.1828(11) 0.6965(10) 0.8263(9) 0.051(3) Uani d . 1 . .
H H1A 1.2417 0.7576 0.7941 0.077 Uiso calc R 1 . .
H H1B 1.2489 0.6572 0.8691 0.077 Uiso calc R 1 . .
H H1C 1.1438 0.7442 0.8726 0.077 Uiso calc R 1 . .
C C2 0.6662(11) 0.3300(10) 0.5714(8) 0.043(2) Uani d . 1 . .
C C3 0.5668(12) 0.2033(10) 0.5068(8) 0.053(3) Uani d . 1 . .
H H3 0.4691 0.1650 0.5125 0.063 Uiso calc R 1 . .
C C4 0.6138(14) 0.1358(11) 0.4352(9) 0.057(3) Uani d . 1 . .
H H4 0.5499 0.0500 0.3922 0.069 Uiso calc R 1 . .
C C5 0.7594(14) 0.1978(11) 0.4276(9) 0.057(3) Uani d . 1 . .
H H5 0.7920 0.1568 0.3759 0.068 Uiso calc R 1 . .
C C6 0.8527(12) 0.3189(11) 0.4967(8) 0.045(2) Uani d . 1 . .
H H6 0.9502 0.3596 0.4913 0.054 Uiso calc R 1 . .
C C7 0.4833(11) 0.3477(11) 0.6713(9) 0.054(3) Uani d . 1 . .
H H7A 0.3919 0.3019 0.6060 0.064 Uiso calc R 1 . .
H H7B 0.4630 0.4184 0.7128 0.064 Uiso calc R 1 . .
C C8 0.5046(12) 0.2502(10) 0.7386(8) 0.046(3) Uani d . 1 . .
C C9 0.6496(15) 0.2476(13) 0.7969(10) 0.066(3) Uani d . 1 . .
H H9 0.7407 0.3058 0.7926 0.080 Uiso calc R 1 . .
C C10 0.656(2) 0.1572(17) 0.8612(12) 0.090(5) Uani d . 1 . .
H H10 0.7536 0.1558 0.8997 0.109 Uiso calc R 1 . .
C C11 0.527(3) 0.0706(16) 0.8707(13) 0.098(6) Uani d . 1 . .
H H11 0.5352 0.0092 0.9130 0.117 Uiso calc R 1 . .
C C12 0.385(2) 0.0762(14) 0.8161(14) 0.090(5) Uani d . 1 . .
H H12 0.2951 0.0215 0.8248 0.108 Uiso calc R 1 . .
C C13 0.3726(14) 0.1606(12) 0.7495(11) 0.067(4) Uani d . 1 . .
H H13 0.2742 0.1588 0.7101 0.080 Uiso calc R 1 . .
C C14 0.6497(11) 0.5486(10) 0.6317(8) 0.042(2) Uani d . 1 . .
H H14A 0.5702 0.5802 0.6461 0.051 Uiso calc R 1 . .
H H14B 0.6510 0.5567 0.5592 0.051 Uiso calc R 1 . .
C C15 0.7980(11) 0.6491(9) 0.8610(8) 0.039(2) Uani d . 1 . .
C C16 0.6740(13) 0.6856(12) 0.8728(9) 0.058(3) Uani d . 1 . .
H H16 0.6184 0.7164 0.8183 0.069 Uiso calc R 1 . .
C C17 0.6329(15) 0.6761(14) 0.9664(11) 0.072(4) Uani d . 1 . .
H H17 0.5494 0.7000 0.9733 0.086 Uiso calc R 1 . .
C C18 0.7140(15) 0.6323(12) 1.0477(10) 0.063(3) Uani d . 1 . .
H H18 0.6868 0.6271 1.1101 0.075 Uiso calc R 1 . .
C C19 0.8370(15) 0.5957(11) 1.0363(9) 0.061(3) Uani d . 1 . .
H H19 0.8923 0.5640 1.0904 0.073 Uiso calc R 1 . .
C C20 0.8774(13) 0.6066(10) 0.9431(8) 0.048(3) Uani d . 1 . .
H H20 0.9621 0.5840 0.9370 0.058 Uiso calc R 1 . .
C C21 0.8791(11) 0.8172(10) 0.7178(9) 0.044(2) Uani d . 1 . .
C C22 0.9235(16) 0.9260(11) 0.8040(12) 0.075(4) Uani d . 1 . .
H H22 0.9322 0.9134 0.8738 0.090 Uiso calc R 1 . .
C C23 0.955(2) 1.0538(16) 0.788(2) 0.107(6) Uani d . 1 . .
H H23 0.9901 1.1264 0.8481 0.129 Uiso calc R 1 . .
C C24 0.9375(19) 1.0761(16) 0.688(2) 0.111(7) Uani d . 1 . .
H H24 0.9531 1.1622 0.6779 0.133 Uiso calc R 1 . .
C C25 0.8956(16) 0.9686(19) 0.6016(16) 0.095(5) Uani d . 1 . .
H H25 0.8833 0.9826 0.5318 0.115 Uiso calc R 1 . .
C C26 0.8710(13) 0.8394(13) 0.6154(10) 0.062(3) Uani d . 1 . .
H H26 0.8493 0.7687 0.5566 0.074 Uiso calc R 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C1 Pt1 P1 . . 90.3(3) ?
C1 Pt1 N1 . . 176.2(4) ?
P1 Pt1 N1 . . 93.5(2) ?
C1 Pt1 Cl1 . . 86.8(3) ?
P1 Pt1 Cl1 . . 176.99(10) ?
N1 Pt1 Cl1 . . 89.5(2) ?
C15 P1 C21 . . 105.9(5) ?
C15 P1 C14 . . 102.0(5) ?
C21 P1 C14 . . 104.8(5) ?
C15 P1 Pt1 . . 119.0(3) ?
C21 P1 Pt1 . . 117.2(3) ?
C14 P1 Pt1 . . 106.0(3) ?
C6 N1 C2 . . 118.0(9) ?
C6 N1 Pt1 . . 117.7(7) ?
C2 N1 Pt1 . . 123.5(7) ?
C2 N2 C14 . . 116.7(8) ?
C2 N2 C7 . . 120.7(9) ?
C14 N2 C7 . . 117.0(8) ?
Pt1 C1 H1A . . 109.5 ?
Pt1 C1 H1B . . 109.5 ?
H1A C1 H1B . . 109.5 ?
Pt1 C1 H1C . . 109.5 ?
H1A C1 H1C . . 109.5 ?
H1B C1 H1C . . 109.5 ?
N1 C2 C3 . . 121.4(9) ?
N1 C2 N2 . . 117.4(9) ?
C3 C2 N2 . . 121.3(9) ?
C4 C3 C2 . . 119.3(10) ?
C4 C3 H3 . . 120.3 ?
C2 C3 H3 . . 120.3 ?
C3 C4 C5 . . 118.5(11) ?
C3 C4 H4 . . 120.8 ?
C5 C4 H4 . . 120.8 ?
C6 C5 C4 . . 118.9(10) ?
C6 C5 H5 . . 120.6 ?
C4 C5 H5 . . 120.6 ?
N1 C6 C5 . . 123.2(10) ?
N1 C6 H6 . . 118.4 ?
C5 C6 H6 . . 118.4 ?
N2 C7 C8 . . 114.6(9) ?
N2 C7 H7A . . 108.6 ?
C8 C7 H7A . . 108.6 ?
N2 C7 H7B . . 108.6 ?
C8 C7 H7B . . 108.6 ?
H7A C7 H7B . . 107.6 ?
C9 C8 C13 . . 117.5(12) ?
C9 C8 C7 . . 123.8(10) ?
C13 C8 C7 . . 118.6(11) ?
C10 C9 C8 . . 119.0(13) ?
C10 C9 H9 . . 120.5 ?
C8 C9 H9 . . 120.5 ?
C11 C10 C9 . . 122.9(16) ?
C11 C10 H10 . . 118.6 ?
C9 C10 H10 . . 118.6 ?
C10 C11 C12 . . 118.2(15) ?
C10 C11 H11 . . 120.9 ?
C12 C11 H11 . . 120.9 ?
C13 C12 C11 . . 120.7(14) ?
C13 C12 H12 . . 119.6 ?
C11 C12 H12 . . 119.6 ?
C12 C13 C8 . . 121.7(13) ?
C12 C13 H13 . . 119.1 ?
C8 C13 H13 . . 119.1 ?
N2 C14 P1 . . 107.1(6) ?
N2 C14 H14A . . 110.3 ?
P1 C14 H14A . . 110.3 ?
N2 C14 H14B . . 110.3 ?
P1 C14 H14B . . 110.3 ?
H14A C14 H14B . . 108.5 ?
C20 C15 C16 . . 118.0(9) ?
C20 C15 P1 . . 121.5(7) ?
C16 C15 P1 . . 120.3(8) ?
C15 C16 C17 . . 120.2(11) ?
C15 C16 H16 . . 119.9 ?
C17 C16 H16 . . 119.9 ?
C18 C17 C16 . . 120.8(11) ?
C18 C17 H17 . . 119.6 ?
C16 C17 H17 . . 119.6 ?
C17 C18 C19 . . 119.3(11) ?
C17 C18 H18 . . 120.4 ?
C19 C18 H18 . . 120.4 ?
C18 C19 C20 . . 119.3(11) ?
C18 C19 H19 . . 120.3 ?
C20 C19 H19 . . 120.3 ?
C15 C20 C19 . . 122.4(10) ?
C15 C20 H20 . . 118.8 ?
C19 C20 H20 . . 118.8 ?
C22 C21 C26 . . 118.4(11) ?
C22 C21 P1 . . 122.4(9) ?
C26 C21 P1 . . 119.2(9) ?
C21 C22 C23 . . 120.5(15) ?
C21 C22 H22 . . 119.7 ?
C23 C22 H22 . . 119.7 ?
C24 C23 C22 . . 121.8(18) ?
C24 C23 H23 . . 119.1 ?
C22 C23 H23 . . 119.1 ?
C23 C24 C25 . . 118.1(16) ?
C23 C24 H24 . . 120.9 ?
C25 C24 H24 . . 120.9 ?
C24 C25 C26 . . 121.7(16) ?
C24 C25 H25 . . 119.2 ?
C26 C25 H25 . . 119.2 ?
C21 C26 C25 . . 119.2(14) ?
C21 C26 H26 . . 120.4 ?
C25 C26 H26 . . 120.4 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Pt1 C1 . 2.039(10) ?
Pt1 P1 . 2.178(2) ?
Pt1 N1 . 2.219(8) ?
Pt1 Cl1 . 2.361(3) ?
P1 C15 . 1.811(10) ?
P1 C21 . 1.818(10) ?
P1 C14 . 1.828(10) ?
N1 C6 . 1.326(12) ?
N1 C2 . 1.338(12) ?
N2 C2 . 1.401(12) ?
N2 C14 . 1.461(12) ?
N2 C7 . 1.464(13) ?
C1 H1A . 0.9600 ?
C1 H1B . 0.9600 ?
C1 H1C . 0.9600 ?
C2 C3 . 1.387(13) ?
C3 C4 . 1.357(14) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.389(16) ?
C4 H4 . 0.9300 ?
C5 C6 . 1.352(15) ?
C5 H5 . 0.9300 ?
C6 H6 . 0.9300 ?
C7 C8 . 1.490(15) ?
C7 H7A . 0.9700 ?
C7 H7B . 0.9700 ?
C8 C9 . 1.391(16) ?
C8 C13 . 1.399(15) ?
C9 C10 . 1.383(19) ?
C9 H9 . 0.9300 ?
C10 C11 . 1.36(2) ?
C10 H10 . 0.9300 ?
C11 C12 . 1.37(2) ?
C11 H11 . 0.9300 ?
C12 C13 . 1.36(2) ?
C12 H12 . 0.9300 ?
C13 H13 . 0.9300 ?
C14 H14A . 0.9700 ?
C14 H14B . 0.9700 ?
C15 C20 . 1.355(13) ?
C15 C16 . 1.392(13) ?
C16 C17 . 1.399(16) ?
C16 H16 . 0.9300 ?
C17 C18 . 1.364(17) ?
C17 H17 . 0.9300 ?
C18 C19 . 1.382(15) ?
C18 H18 . 0.9300 ?
C19 C20 . 1.392(15) ?
C19 H19 . 0.9300 ?
C20 H20 . 0.9300 ?
C21 C22 . 1.372(15) ?
C21 C26 . 1.385(15) ?
C22 C23 . 1.38(2) ?
C22 H22 . 0.9300 ?
C23 C24 . 1.34(2) ?
C23 H23 . 0.9300 ?
C24 C25 . 1.37(2) ?
C24 H24 . 0.9300 ?
C25 C26 . 1.388(19) ?
C25 H25 . 0.9300 ?
C26 H26 . 0.9300 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
C23 H23 Cg1 2_777 0.93 3.10 4.001(2) 154 y
C7 H7B Cl1 1_455 0.97 2.72 3.392(2) 127 y
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C1 Pt1 P1 C15 . . . . -69.7(5) ?
N1 Pt1 P1 C15 . . . . 110.5(4) ?
Cl1 Pt1 P1 C15 . . . . -57(2) ?
C1 Pt1 P1 C21 . . . . 59.9(5) ?
N1 Pt1 P1 C21 . . . . -119.9(4) ?
Cl1 Pt1 P1 C21 . . . . 73(2) ?
C1 Pt1 P1 C14 . . . . 176.3(5) ?
N1 Pt1 P1 C14 . . . . -3.5(4) ?
Cl1 Pt1 P1 C14 . . . . -171(2) ?
C1 Pt1 N1 C6 . . . . -22(5) ?
P1 Pt1 N1 C6 . . . . 154.9(7) ?
Cl1 Pt1 N1 C6 . . . . -25.8(7) ?
C1 Pt1 N1 C2 . . . . 148(5) ?
P1 Pt1 N1 C2 . . . . -35.2(8) ?
Cl1 Pt1 N1 C2 . . . . 144.2(8) ?
C6 N1 C2 C3 . . . . 10.0(15) ?
Pt1 N1 C2 C3 . . . . -159.9(8) ?
C6 N1 C2 N2 . . . . -169.3(9) ?
Pt1 N1 C2 N2 . . . . 20.8(13) ?
C14 N2 C2 N1 . . . . 47.3(12) ?
C7 N2 C2 N1 . . . . -159.6(10) ?
C14 N2 C2 C3 . . . . -132.0(10) ?
C7 N2 C2 C3 . . . . 21.1(15) ?
N1 C2 C3 C4 . . . . -6.0(16) ?
N2 C2 C3 C4 . . . . 173.3(10) ?
C2 C3 C4 C5 . . . . -1.3(17) ?
C3 C4 C5 C6 . . . . 4.3(18) ?
C2 N1 C6 C5 . . . . -7.0(15) ?
Pt1 N1 C6 C5 . . . . 163.6(8) ?
C4 C5 C6 N1 . . . . -0.2(17) ?
C2 N2 C7 C8 . . . . 61.9(13) ?
C14 N2 C7 C8 . . . . -145.1(9) ?
N2 C7 C8 C9 . . . . 20.8(15) ?
N2 C7 C8 C13 . . . . -162.9(9) ?
C13 C8 C9 C10 . . . . 0.5(16) ?
C7 C8 C9 C10 . . . . 176.7(11) ?
C8 C9 C10 C11 . . . . 0(2) ?
C9 C10 C11 C12 . . . . -2(2) ?
C10 C11 C12 C13 . . . . 4(2) ?
C11 C12 C13 C8 . . . . -4(2) ?
C9 C8 C13 C12 . . . . 1.5(16) ?
C7 C8 C13 C12 . . . . -175.0(11) ?
C2 N2 C14 P1 . . . . -90.2(9) ?
C7 N2 C14 P1 . . . . 115.7(8) ?
C15 P1 C14 N2 . . . . -72.7(7) ?
C21 P1 C14 N2 . . . . 177.1(6) ?
Pt1 P1 C14 N2 . . . . 52.5(7) ?
C21 P1 C15 C20 . . . . -125.7(9) ?
C14 P1 C15 C20 . . . . 125.0(9) ?
Pt1 P1 C15 C20 . . . . 8.8(10) ?
C21 P1 C15 C16 . . . . 58.9(9) ?
C14 P1 C15 C16 . . . . -50.5(9) ?
Pt1 P1 C15 C16 . . . . -166.7(7) ?
C20 C15 C16 C17 . . . . -1.0(16) ?
P1 C15 C16 C17 . . . . 174.6(10) ?
C15 C16 C17 C18 . . . . 1(2) ?
C16 C17 C18 C19 . . . . -1(2) ?
C17 C18 C19 C20 . . . . 1.2(18) ?
C16 C15 C20 C19 . . . . 1.6(16) ?
P1 C15 C20 C19 . . . . -174.0(9) ?
C18 C19 C20 C15 . . . . -1.7(18) ?
C15 P1 C21 C22 . . . . 21.9(11) ?
C14 P1 C21 C22 . . . . 129.3(10) ?
Pt1 P1 C21 C22 . . . . -113.6(9) ?
C15 P1 C21 C26 . . . . -161.4(8) ?
C14 P1 C21 C26 . . . . -54.0(9) ?
Pt1 P1 C21 C26 . . . . 63.1(9) ?
C26 C21 C22 C23 . . . . 1.6(19) ?
P1 C21 C22 C23 . . . . 178.3(11) ?
C21 C22 C23 C24 . . . . 3(2) ?
C22 C23 C24 C25 . . . . -4(3) ?
C23 C24 C25 C26 . . . . 0(2) ?
C22 C21 C26 C25 . . . . -5.1(16) ?
P1 C21 C26 C25 . . . . 178.1(9) ?
C24 C25 C26 C21 . . . . 4(2) ?
