#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/46/4074618.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4074618
loop_
_publ_author_name
'Yin, Gang-Qiang'
'Wei, Qiao-Hua'
'Zhang, Li-Yi'
'Chen, Zhong-Ning'
_publ_section_title
;
 Luminescent PtII−MI(M = Cu, Ag, Au) Heteronuclear Alkynyl
 Complexes Prepared by Reaction of [Pt(C⋮CR)4]2-with
 [M2(dppm)2]2+(dppm = Bis(diphenylphosphino)methane)
;
_journal_issue                   3
_journal_name_full               Organometallics
_journal_page_first              580
_journal_paper_doi               10.1021/om050620e
_journal_volume                  25
_journal_year                    2006
_chemical_formula_sum            'C76 H79 Ag1.5 Cl2 F9 O3 P4 Pt Sb1.5'
_chemical_formula_weight         1945.69
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 129.4980(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   38.31670(10)
_cell_length_b                   20.9887(2)
_cell_length_c                   29.0955(2)
_cell_measurement_reflns_used    8192
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      1.19
_cell_volume                     18055.9(3)
_computing_cell_refinement       'Siemens SMART & SAINT'
_computing_data_collection       'Siemens SMART'
_computing_data_reduction        'Siemens XPREP'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Siemens SHELXTL'
_computing_structure_solution    'Siemens SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Siemens SMART CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0490
_diffrn_reflns_av_sigmaI/netI    0.0726
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -44
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            26898
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.19
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    2.497
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  .6304
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.432
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             7672
_exptl_crystal_size_max          .82
_exptl_crystal_size_mid          .80
_exptl_crystal_size_min          .72
_refine_diff_density_max         1.251
_refine_diff_density_min         -1.406
_refine_diff_density_rms         0.348
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.165
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     880
_refine_ls_number_reflns         15492
_refine_ls_number_restraints     84
_refine_ls_restrained_S_all      1.163
_refine_ls_R_factor_all          0.1482
_refine_ls_R_factor_gt           0.0790
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0961P)²+266.7663P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1947
_refine_ls_wR_factor_ref         0.2535
_reflns_number_gt                9365
_reflns_number_total             15492
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om050620esi20051124_094200.cif
_cod_data_source_block           Compoumd_13
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        18055.8(2)
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C76 H79 Ag1.50 Cl2 F9 O3 P4 Pt Sb1.50'
_cod_database_code               4074618
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt 0.778020(18) 0.09631(3) 0.06960(2) 0.05506(19) Uani 1 1 d . . .
Ag1 Ag 0.83548(4) -0.01363(6) 0.14846(5) 0.0770(4) Uani 1 1 d . . .
Ag2 Ag 0.7500 0.2500 0.0000 0.0730(5) Uani 1 2 d S . .
Sb1 Sb 0.74800(6) -0.37166(7) 0.17572(7) 0.1075(5) Uani 1 1 d D . .
Sb2 Sb 1.0000 0.10222(9) 0.2500 0.0871(5) Uani 1 2 d S . .
Cl01 Cl 0.9549(6) -0.2078(9) 0.4542(9) 0.353(9) Uiso 1 1 d D . .
C01 C 0.9220(15) -0.1817(13) 0.3800(12) 0.31(3) Uiso 1 1 d D . .
H01A H 0.8903 -0.1932 0.3564 0.376 Uiso 1 1 calc R . .
H01B H 0.9337 -0.1959 0.3604 0.376 Uiso 1 1 calc R . .
Cl02 Cl 0.9319(6) -0.0992(9) 0.3986(8) 0.344(9) Uiso 1 1 d D . .
P1 P 0.83068(14) -0.06961(19) 0.07265(17) 0.0633(10) Uani 1 1 d . . .
P2 P 0.77642(12) 0.04811(17) -0.00403(15) 0.0563(9) Uani 1 1 d . . .
P3 P 0.82826(14) 0.01129(19) 0.22253(17) 0.0644(10) Uani 1 1 d . . .
P4 P 0.77789(13) 0.13121(17) 0.14526(16) 0.0578(9) Uani 1 1 d . . .
F11 F 0.7645(17) -0.425(3) 0.2350(19) 0.35(6) Uani 0.46(5) 1 d PD A 1
F12 F 0.7332(17) -0.315(4) 0.207(4) 0.27(5) Uani 0.46(5) 1 d PD A 1
F13 F 0.7227(11) -0.302(3) 0.129(5) 0.30(4) Uani 0.54(5) 1 d PD A 1
F14 F 0.7490(19) -0.405(4) 0.120(3) 0.36(7) Uani 0.46(5) 1 d PD A 1
F11' F 0.7508(18) -0.371(4) 0.2397(16) 0.26(4) Uani 0.54(5) 1 d PD A 2
F12' F 0.7247(13) -0.297(3) 0.163(3) 0.25(5) Uani 0.46(5) 1 d PD A 2
F13' F 0.7347(16) -0.356(3) 0.1050(14) 0.27(4) Uani 0.54(5) 1 d PD A 2
F14' F 0.7659(14) -0.4492(18) 0.182(3) 0.28(4) Uani 0.54(5) 1 d PD A 2
F15 F 0.6934(7) -0.4105(12) 0.1344(9) 0.251(12) Uani 1 1 d D A .
F16 F 0.8027(5) -0.3337(9) 0.2173(8) 0.193(7) Uani 1 1 d D A .
F21 F 0.9376(4) 0.1023(8) 0.2020(6) 0.157(5) Uani 1 1 d . . .
F22 F 0.9927(6) 0.1039(17) 0.1843(7) 0.299(17) Uani 1 1 d . . .
F23 F 1.0087(9) 0.0207(12) 0.2377(16) 0.148(13) Uani 0.50 1 d P . .
F24 F 1.0082(11) 0.1851(11) 0.2381(16) 0.147(13) Uani 0.50 1 d P . .
O1 O 0.8735(17) -0.562(3) 0.327(2) 0.217(19) Uiso 0.50 1 d PD . .
O2 O 0.909(3) -0.483(4) 0.391(4) 0.38(4) Uiso 0.50 1 d PD . .
O3 O 0.9334(19) -0.178(3) 0.253(2) 0.48(3) Uiso 1 1 d . . .
O4 O 0.922(2) -0.373(3) 0.221(3) 0.56(4) Uiso 1 1 d . . .
C1 C 0.7805(5) -0.0399(7) 0.0007(6) 0.066(4) Uani 1 1 d . . .
H1A H 0.7538 -0.0568 -0.0068 0.079 Uiso 1 1 calc R . .
H1B H 0.7809 -0.0557 -0.0304 0.079 Uiso 1 1 calc R . .
C2 C 0.7812(5) 0.0668(7) 0.1906(6) 0.065(4) Uani 1 1 d . . .
H2A H 0.7835 0.0857 0.2228 0.077 Uiso 1 1 calc R . .
H2B H 0.7532 0.0428 0.1660 0.077 Uiso 1 1 calc R . .
C02 C 0.866(3) -0.516(3) 0.356(3) 0.42(4) Uiso 1 1 d D . .
C11 C 0.8050(4) 0.1767(6) 0.0680(6) 0.056(3) Uani 1 1 d . . .
C12 C 0.8255(5) 0.2251(7) 0.0705(6) 0.060(3) Uani 1 1 d . . .
C13 C 0.8587(5) 0.2702(7) 0.0833(6) 0.063(4) Uani 1 1 d . . .
C14 C 0.9050(6) 0.2542(9) 0.1255(9) 0.103(6) Uani 1 1 d . . .
H14A H 0.9127 0.2153 0.1451 0.124 Uiso 1 1 calc R . .
C15 C 0.9389(6) 0.2933(10) 0.1388(11) 0.132(10) Uani 1 1 d . . .
H15A H 0.9691 0.2815 0.1673 0.159 Uiso 1 1 calc R . .
C16 C 0.9277(6) 0.3495(11) 0.1096(11) 0.124(8) Uani 1 1 d . B .
C17 C 0.8834(6) 0.3674(8) 0.0685(8) 0.099(6) Uani 1 1 d . . .
H17A H 0.8763 0.4062 0.0489 0.119 Uiso 1 1 calc R . .
C18 C 0.8486(5) 0.3287(7) 0.0556(7) 0.077(4) Uani 1 1 d . . .
H18A H 0.8187 0.3420 0.0283 0.092 Uiso 1 1 calc R . .
C19 C 0.9678(10) 0.3900(13) 0.1224(11) 0.165(11) Uiso 1 1 d D . .
C20 C 1.0093(13) 0.396(2) 0.1891(13) 0.156(10) Uiso 0.56(3) 1 d PD B 1
H20A H 1.0322 0.4214 0.1933 0.234 Uiso 0.56(3) 1 calc PR B 1
H20B H 1.0211 0.3548 0.2058 0.234 Uiso 0.56(3) 1 calc PR B 1
H20C H 1.0004 0.4169 0.2097 0.234 Uiso 0.56(3) 1 calc PR B 1
C20' C 1.0176(12) 0.367(3) 0.1653(19) 0.156(10) Uiso 0.44 1 d PD B 2
H20D H 1.0365 0.3984 0.1666 0.234 Uiso 0.44(3) 1 calc PR B 2
H20E H 1.0201 0.3274 0.1514 0.234 Uiso 0.44(3) 1 calc PR B 2
H20F H 1.0269 0.3616 0.2044 0.234 Uiso 0.44(3) 1 calc PR B 2
C21 C 0.9549(14) 0.4568(16) 0.0946(18) 0.156(10) Uiso 0.56(3) 1 d PD B 1
H21A H 0.9813 0.4776 0.1045 0.234 Uiso 0.56(3) 1 calc PR B 1
H21B H 0.9430 0.4812 0.1097 0.234 Uiso 0.56(3) 1 calc PR B 1
H21C H 0.9324 0.4533 0.0521 0.234 Uiso 0.56(3) 1 calc PR B 1
C21' C 0.9665(18) 0.449(2) 0.154(2) 0.156(10) Uiso 0.44 1 d PD B 2
H21D H 0.9896 0.4789 0.1648 0.234 Uiso 0.44(3) 1 calc PR B 2
H21E H 0.9716 0.4355 0.1895 0.234 Uiso 0.44(3) 1 calc PR B 2
H21F H 0.9374 0.4694 0.1278 0.234 Uiso 0.44(3) 1 calc PR B 2
C22 C 0.9863(15) 0.3540(19) 0.0941(18) 0.156(10) Uiso 0.56(3) 1 d PD B 1
H22A H 1.0107 0.3780 0.1013 0.234 Uiso 0.56(3) 1 calc PR B 1
H22B H 0.9624 0.3496 0.0520 0.234 Uiso 0.56(3) 1 calc PR B 1
H22C H 0.9970 0.3126 0.1119 0.234 Uiso 0.56(3) 1 calc PR B 1
C22' C 0.9592(17) 0.418(3) 0.0666(17) 0.156(10) Uiso 0.44 1 d PD B 2
H22D H 0.9852 0.4413 0.0786 0.234 Uiso 0.44(3) 1 calc PR B 2
H22E H 0.9334 0.4453 0.0459 0.234 Uiso 0.44(3) 1 calc PR B 2
H22F H 0.9536 0.3834 0.0408 0.234 Uiso 0.44(3) 1 calc PR B 2
C31 C 0.7425(5) 0.0219(7) 0.0620(6) 0.060(3) Uani 1 1 d . . .
C32 C 0.7165(5) -0.0202(8) 0.0535(6) 0.069(4) Uani 1 1 d . . .
C33 C 0.6831(5) -0.0661(7) 0.0390(7) 0.068(4) Uani 1 1 d . . .
C34 C 0.6918(7) -0.1117(10) 0.0792(9) 0.112(7) Uani 1 1 d . . .
H34A H 0.7203 -0.1143 0.1164 0.135 Uiso 1 1 calc R . .
C35 C 0.6582(8) -0.1536(10) 0.0643(11) 0.122(8) Uani 1 1 d . . .
H35A H 0.6643 -0.1826 0.0928 0.146 Uiso 1 1 calc R . .
C36 C 0.6167(6) -0.1540(8) 0.0099(9) 0.087(5) Uani 1 1 d . C .
C37 C 0.6111(6) -0.1139(9) -0.0294(8) 0.105(7) Uani 1 1 d . . .
H37A H 0.5836 -0.1144 -0.0680 0.126 Uiso 1 1 calc R . .
C38 C 0.6437(6) -0.0713(8) -0.0164(8) 0.093(6) Uani 1 1 d . . .
H38A H 0.6382 -0.0458 -0.0465 0.111 Uiso 1 1 calc R . .
C39 C 0.5788(7) -0.1984(10) -0.0065(8) 0.114(7) Uiso 1 1 d D . .
C40 C 0.6003(17) -0.2604(18) 0.030(2) 0.11(2) Uiso 0.37(4) 1 d PD C 1
H40A H 0.6291 -0.2673 0.0400 0.172 Uiso 0.37(4) 1 calc PR C 1
H40B H 0.5807 -0.2958 0.0076 0.172 Uiso 0.37(4) 1 calc PR C 1
H40C H 0.6045 -0.2566 0.0665 0.172 Uiso 0.37(4) 1 calc PR C 1
C40' C 0.5883(15) -0.235(2) 0.0460(15) 0.18(2) Uiso 0.63(4) 1 d PD C 2
H40D H 0.5771 -0.2105 0.0623 0.270 Uiso 0.63(4) 1 calc PR C 2
H40E H 0.6203 -0.2410 0.0761 0.270 Uiso 0.63(4) 1 calc PR C 2
H40F H 0.5734 -0.2753 0.0325 0.270 Uiso 0.63(4) 1 calc PR C 2
C41 C 0.5445(19) -0.217(3) -0.0726(13) 0.154(15) Uiso 0.37(4) 1 d PD C 1
H41A H 0.5310 -0.1792 -0.0964 0.232 Uiso 0.37(4) 1 calc PR C 1
H41B H 0.5213 -0.2433 -0.0787 0.232 Uiso 0.37(4) 1 calc PR C 1
H41C H 0.5596 -0.2402 -0.0839 0.232 Uiso 0.37(4) 1 calc PR C 1
C41' C 0.5697(15) -0.2465(18) -0.0533(16) 0.154(15) Uiso 0.63 1 d PD C 2
H41D H 0.5541 -0.2254 -0.0910 0.232 Uiso 0.63(4) 1 calc PR C 2
H41E H 0.5514 -0.2808 -0.0572 0.232 Uiso 0.63(4) 1 calc PR C 2
H41F H 0.5979 -0.2631 -0.0408 0.232 Uiso 0.63(4) 1 calc PR C 2
C42 C 0.554(2) -0.166(3) 0.013(3) 0.18(3) Uiso 0.37(4) 1 d PD C 1
H42A H 0.5400 -0.1272 -0.0096 0.265 Uiso 0.37(4) 1 calc PR C 1
H42B H 0.5747 -0.1564 0.0543 0.265 Uiso 0.37(4) 1 calc PR C 1
H42C H 0.5306 -0.1940 0.0047 0.265 Uiso 0.37(4) 1 calc PR C 1
C42' C 0.5355(12) -0.1582(17) -0.0365(19) 0.161(19) Uiso 0.63(4) 1 d PD C 2
H42D H 0.5366 -0.1218 -0.0556 0.241 Uiso 0.63(4) 1 calc PR C 2
H42E H 0.5334 -0.1441 -0.0069 0.241 Uiso 0.63(4) 1 calc PR C 2
H42F H 0.5095 -0.1836 -0.0657 0.241 Uiso 0.63(4) 1 calc PR C 2
C51 C 0.8170(5) -0.1534(8) 0.0711(7) 0.073(4) Uani 1 1 d . . .
C52 C 0.8322(7) -0.2010(8) 0.0556(10) 0.110(7) Uani 1 1 d . . .
H52A H 0.8492 -0.1919 0.0437 0.132 Uiso 1 1 calc R . .
C53 C 0.8212(10) -0.2651(11) 0.0584(14) 0.148(10) Uani 1 1 d . . .
H53A H 0.8314 -0.2983 0.0485 0.178 Uiso 1 1 calc R . .
C54 C 0.7952(10) -0.2792(11) 0.0759(11) 0.136(9) Uani 1 1 d . . .
H54A H 0.7890 -0.3212 0.0787 0.163 Uiso 1 1 calc R . .
C55 C 0.7799(9) -0.2314(11) 0.0882(11) 0.134(9) Uani 1 1 d . . .
H55A H 0.7627 -0.2408 0.0997 0.161 Uiso 1 1 calc R . .
C56 C 0.7881(7) -0.1684(10) 0.0850(9) 0.100(6) Uani 1 1 d . . .
H56A H 0.7752 -0.1362 0.0917 0.120 Uiso 1 1 calc R . .
C61 C 0.8772(6) -0.0692(7) 0.0712(8) 0.074(4) Uani 1 1 d . . .
C62 C 0.8718(7) -0.0810(8) 0.0204(9) 0.089(5) Uani 1 1 d . . .
H62A H 0.8428 -0.0879 -0.0151 0.107 Uiso 1 1 calc R . .
C63 C 0.9069(11) -0.0830(12) 0.0200(14) 0.126(8) Uani 1 1 d . . .
H63A H 0.9025 -0.0911 -0.0149 0.151 Uiso 1 1 calc R . .
C64 C 0.9485(13) -0.0728(12) 0.072(2) 0.160(15) Uani 1 1 d . . .
H64A H 0.9732 -0.0733 0.0729 0.193 Uiso 1 1 calc R . .
C65 C 0.9555(9) -0.0619(12) 0.1233(15) 0.146(10) Uani 1 1 d . . .
H65A H 0.9848 -0.0572 0.1589 0.176 Uiso 1 1 calc R . .
C66 C 0.9196(8) -0.0578(9) 0.1225(11) 0.103(6) Uani 1 1 d . . .
H66A H 0.9241 -0.0472 0.1570 0.124 Uiso 1 1 calc R . .
C71 C 0.7235(5) 0.0656(8) -0.0767(6) 0.067(4) Uani 1 1 d . . .
C72 C 0.7172(6) 0.1214(8) -0.1047(8) 0.086(5) Uani 1 1 d . . .
H72A H 0.7419 0.1484 -0.0879 0.103 Uiso 1 1 calc R . .
C73 C 0.6762(8) 0.1397(10) -0.1567(9) 0.110(7) Uani 1 1 d . . .
H73A H 0.6735 0.1788 -0.1737 0.133 Uiso 1 1 calc R . .
C74 C 0.6403(9) 0.1021(14) -0.1828(10) 0.137(9) Uani 1 1 d . . .
H74A H 0.6127 0.1143 -0.2184 0.164 Uiso 1 1 calc R . .
C75 C 0.6444(8) 0.0462(15) -0.1572(11) 0.156(11) Uani 1 1 d . . .
H75A H 0.6193 0.0198 -0.1754 0.187 Uiso 1 1 calc R . .
C76 C 0.6865(7) 0.0264(11) -0.1029(9) 0.129(9) Uani 1 1 d . . .
H76A H 0.6889 -0.0123 -0.0855 0.155 Uiso 1 1 calc R . .
C81 C 0.8198(5) 0.0690(6) -0.0088(6) 0.059(3) Uani 1 1 d . . .
C82 C 0.8146(6) 0.0556(7) -0.0596(7) 0.077(4) Uani 1 1 d . . .
H82A H 0.7871 0.0398 -0.0933 0.092 Uiso 1 1 calc R . .
C83 C 0.8506(7) 0.0657(9) -0.0603(9) 0.091(5) Uani 1 1 d . . .
H83A H 0.8465 0.0588 -0.0949 0.109 Uiso 1 1 calc R . .
C84 C 0.8915(7) 0.0859(9) -0.0096(9) 0.091(5) Uani 1 1 d . . .
H84A H 0.9157 0.0911 -0.0093 0.109 Uiso 1 1 calc R . .
C85 C 0.8967(5) 0.0982(8) 0.0401(8) 0.080(5) Uani 1 1 d . . .
H85A H 0.9248 0.1116 0.0743 0.097 Uiso 1 1 calc R . .
C86 C 0.8619(5) 0.0915(7) 0.0417(7) 0.068(4) Uani 1 1 d . . .
H86A H 0.8661 0.1018 0.0760 0.081 Uiso 1 1 calc R . .
C91 C 0.8101(6) -0.0585(7) 0.2411(6) 0.075(4) Uani 1 1 d . . .
C92 C 0.8197(8) -0.1190(10) 0.2334(9) 0.116(7) Uani 1 1 d . . .
H92A H 0.8364 -0.1247 0.2206 0.140 Uiso 1 1 calc R . .
C93 C 0.8043(12) -0.1709(11) 0.2450(14) 0.168(13) Uani 1 1 d . . .
H93A H 0.8096 -0.2114 0.2377 0.202 Uiso 1 1 calc R . .
C94 C 0.7827(12) -0.1665(16) 0.2656(12) 0.159(14) Uani 1 1 d . . .
H94A H 0.7732 -0.2026 0.2734 0.191 Uiso 1 1 calc R . .
C95 C 0.7741(9) -0.1047(13) 0.2755(11) 0.133(9) Uani 1 1 d . . .
H95A H 0.7598 -0.0997 0.2917 0.160 Uiso 1 1 calc R . .
C96 C 0.7868(8) -0.0523(9) 0.2616(9) 0.108(6) Uani 1 1 d . . .
H96A H 0.7794 -0.0119 0.2662 0.129 Uiso 1 1 calc R . .
C101 C 0.8768(5) 0.0446(7) 0.2950(7) 0.069(4) Uani 1 1 d . . .
C102 C 0.9196(6) 0.0418(9) 0.3101(8) 0.094(5) Uani 1 1 d . . .
H10A H 0.9224 0.0247 0.2831 0.112 Uiso 1 1 calc R . .
C103 C 0.9565(7) 0.0633(13) 0.3627(10) 0.122(8) Uani 1 1 d . . .
H10B H 0.9847 0.0603 0.3724 0.146 Uiso 1 1 calc R . .
C104 C 0.9527(9) 0.0888(16) 0.4007(10) 0.157(12) Uani 1 1 d . . .
H10C H 0.9788 0.1012 0.4380 0.188 Uiso 1 1 calc R . .
C105 C 0.9129(11) 0.0973(14) 0.3875(11) 0.159(11) Uani 1 1 d . . .
H10D H 0.9113 0.1189 0.4139 0.191 Uiso 1 1 calc R . .
C106 C 0.8721(7) 0.0733(12) 0.3325(9) 0.129(9) Uani 1 1 d . . .
H10E H 0.8440 0.0773 0.3232 0.154 Uiso 1 1 calc R . .
C111 C 0.8231(5) 0.1827(7) 0.2033(6) 0.064(4) Uani 1 1 d . . .
C112 C 0.8649(5) 0.1826(8) 0.2152(7) 0.079(4) Uani 1 1 d . . .
H11B H 0.8688 0.1590 0.1916 0.094 Uiso 1 1 calc R . .
C113 C 0.9006(6) 0.2189(10) 0.2634(9) 0.101(6) Uani 1 1 d . . .
H11C H 0.9287 0.2204 0.2724 0.121 Uiso 1 1 calc R . .
C114 C 0.8925(9) 0.2535(10) 0.2981(8) 0.123(8) Uani 1 1 d . . .
H11D H 0.9162 0.2756 0.3316 0.147 Uiso 1 1 calc R . .
C115 C 0.8508(8) 0.2551(11) 0.2834(9) 0.109(6) Uani 1 1 d . . .
H11E H 0.8454 0.2809 0.3042 0.131 Uiso 1 1 calc R . .
C116 C 0.8179(6) 0.2184(8) 0.2381(7) 0.085(5) Uani 1 1 d . . .
H11F H 0.7902 0.2172 0.2299 0.102 Uiso 1 1 calc R . .
C121 C 0.7261(5) 0.1738(7) 0.1163(7) 0.067(4) Uani 1 1 d . . .
C122 C 0.6928(7) 0.1471(11) 0.1117(12) 0.138(9) Uani 1 1 d . . .
H12B H 0.6970 0.1070 0.1281 0.165 Uiso 1 1 calc R . .
C123 C 0.6516(8) 0.1782(12) 0.0825(15) 0.175(14) Uani 1 1 d . . .
H12C H 0.6272 0.1580 0.0762 0.210 Uiso 1 1 calc R . .
C124 C 0.6480(8) 0.2391(11) 0.0636(11) 0.123(8) Uani 1 1 d . . .
H12D H 0.6217 0.2618 0.0478 0.147 Uiso 1 1 calc R . .
C125 C 0.6802(7) 0.2668(9) 0.0668(9) 0.102(6) Uani 1 1 d . . .
H12E H 0.6764 0.3073 0.0511 0.122 Uiso 1 1 calc R . .
C126 C 0.7198(6) 0.2334(8) 0.0943(8) 0.086(5) Uani 1 1 d . . .
H12F H 0.7434 0.2526 0.0981 0.103 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C31 Pt C11 171.7(6) . .
C31 Pt P4 86.5(4) . .
C11 Pt P4 94.0(4) . .
C31 Pt P2 86.6(4) . .
C11 Pt P2 93.2(4) . .
P4 Pt P2 172.59(12) . .
C31 Pt Ag1 66.3(4) . .
C11 Pt Ag1 122.0(4) . .
P4 Pt Ag1 87.75(10) . .
P2 Pt Ag1 86.94(9) . .
P3 Ag1 P1 161.26(15) . .
P3 Ag1 Pt 94.09(10) . .
P1 Ag1 Pt 94.80(10) . .
C12 Ag2 C12 180.0(6) . 7_655
C12 Ag2 C11 31.5(4) . .
C12 Ag2 C11 148.5(4) 7_655 .
C12 Ag2 C11 148.5(4) . 7_655
C12 Ag2 C11 31.5(4) 7_655 7_655
C11 Ag2 C11 180.0(15) . 7_655
F12' Sb1 F14' 173.9(19) . .
F12' Sb1 F14 118(4) . .
F14' Sb1 F14 59(3) . .
F12' Sb1 F11 126(4) . .
F14' Sb1 F11 56(3) . .
F14 Sb1 F11 115(4) . .
F12' Sb1 F11' 84(4) . .
F14' Sb1 F11' 98(3) . .
F14 Sb1 F11' 157(4) . .
F11 Sb1 F11' 42(2) . .
F12' Sb1 F13 31(4) . .
F14' Sb1 F13 146(5) . .
F14 Sb1 F13 87(5) . .
F11 Sb1 F13 157(5) . .
F11' Sb1 F13 115(5) . .
F12' Sb1 F12 39(4) . .
F14' Sb1 F12 143(4) . .
F14 Sb1 F12 157(4) . .
F11 Sb1 F12 87(3) . .
F11' Sb1 F12 45(3) . .
F13 Sb1 F12 70(6) . .
F12' Sb1 F13' 82(3) . .
F14' Sb1 F13' 95(3) . .
F14 Sb1 F13' 36(3) . .
F11 Sb1 F13' 151(3) . .
F11' Sb1 F13' 165(3) . .
F13 Sb1 F13' 51(5) . .
F12 Sb1 F13' 121(4) . .
F12' Sb1 F16 88.1(13) . .
F14' Sb1 F16 97.5(15) . .
F14 Sb1 F16 95.6(11) . .
F11 Sb1 F16 94.6(14) . .
F11' Sb1 F16 91.4(11) . .
F13 Sb1 F16 89.3(12) . .
F12 Sb1 F16 88.5(11) . .
F13' Sb1 F16 93.0(10) . .
F12' Sb1 F15 92.4(14) . .
F14' Sb1 F15 82.0(15) . .
F14 Sb1 F15 84.4(11) . .
F11 Sb1 F15 84.9(14) . .
F11' Sb1 F15 88.4(11) . .
F13 Sb1 F15 91.3(14) . .
F12 Sb1 F15 91.7(12) . .
F13' Sb1 F15 87.3(10) . .
F16 Sb1 F15 179.4(13) . .
F22 Sb2 F22 178(2) 2_755 .
F22 Sb2 F23 108.2(17) 2_755 .
F22 Sb2 F23 74.1(15) . .
F22 Sb2 F23 74.1(15) 2_755 2_755
F22 Sb2 F23 108.2(17) . 2_755
F23 Sb2 F23 40.1(18) . 2_755
F22 Sb2 F24 72.7(15) 2_755 2_755
F22 Sb2 F24 105.0(16) . 2_755
F23 Sb2 F24 178.9(12) . 2_755
F23 Sb2 F24 141.0(13) 2_755 2_755
F22 Sb2 F24 105.0(16) 2_755 .
F22 Sb2 F24 72.7(15) . .
F23 Sb2 F24 141.0(13) . .
F23 Sb2 F24 178.9(12) 2_755 .
F24 Sb2 F24 37.9(17) 2_755 .
F22 Sb2 F21 93.2(8) 2_755 .
F22 Sb2 F21 86.8(8) . .
F23 Sb2 F21 99.3(10) . .
F23 Sb2 F21 80.7(10) 2_755 .
F24 Sb2 F21 81.3(12) 2_755 .
F24 Sb2 F21 98.7(11) . .
F22 Sb2 F21 86.8(8) 2_755 2_755
F22 Sb2 F21 93.2(8) . 2_755
F23 Sb2 F21 80.7(10) . 2_755
F23 Sb2 F21 99.3(10) 2_755 2_755
F24 Sb2 F21 98.7(12) 2_755 2_755
F24 Sb2 F21 81.3(12) . 2_755
F21 Sb2 F21 180.0(11) . 2_755
Cl01 C01 Cl02 94.7(16) . .
Cl01 C01 H01A 112.8 . .
Cl02 C01 H01A 112.8 . .
Cl01 C01 H01B 112.8 . .
Cl02 C01 H01B 112.8 . .
H01A C01 H01B 110.2 . .
C61 P1 C51 106.0(7) . .
C61 P1 C1 107.7(7) . .
C51 P1 C1 103.0(7) . .
C61 P1 Ag1 121.2(6) . .
C51 P1 Ag1 110.3(5) . .
C1 P1 Ag1 107.2(5) . .
C71 P2 C81 105.3(7) . .
C71 P2 C1 105.6(7) . .
C81 P2 C1 102.1(6) . .
C71 P2 Pt 109.9(5) . .
C81 P2 Pt 118.5(5) . .
C1 P2 Pt 114.4(4) . .
C2 P3 C91 102.8(7) . .
C2 P3 C101 107.0(7) . .
C91 P3 C101 105.1(7) . .
C2 P3 Ag1 108.8(5) . .
C91 P3 Ag1 111.8(5) . .
C101 P3 Ag1 120.1(5) . .
C111 P4 C121 104.7(7) . .
C111 P4 C2 100.4(6) . .
C121 P4 C2 104.6(7) . .
C111 P4 Pt 119.5(5) . .
C121 P4 Pt 112.0(5) . .
C2 P4 Pt 114.0(5) . .
F23 F23 Sb2 69.9(9) 2_755 .
F24 F24 Sb2 71.0(9) 2_755 .
P1 C1 P2 113.8(7) . .
P1 C1 H1A 108.8 . .
P2 C1 H1A 108.8 . .
P1 C1 H1B 108.8 . .
P2 C1 H1B 108.8 . .
H1A C1 H1B 107.7 . .
P3 C2 P4 115.5(7) . .
P3 C2 H2A 108.4 . .
P4 C2 H2A 108.4 . .
P3 C2 H2B 108.4 . .
P4 C2 H2B 108.4 . .
H2A C2 H2B 107.5 . .
O1 C02 O2 100(6) . .
C12 C11 Pt 174.7(12) . .
C12 C11 Ag2 73.2(9) . .
Pt C11 Ag2 112.1(6) . .
C11 C12 C13 165.6(15) . .
C11 C12 Ag2 75.3(9) . .
C13 C12 Ag2 119.1(10) . .
C18 C13 C14 116.7(14) . .
C18 C13 C12 124.3(13) . .
C14 C13 C12 119.0(14) . .
C15 C14 C13 123.0(15) . .
C15 C14 H14A 118.5 . .
C13 C14 H14A 118.5 . .
C16 C15 C14 118.6(17) . .
C16 C15 H15A 120.7 . .
C14 C15 H15A 120.7 . .
C15 C16 C17 120.6(16) . .
C15 C16 C19 116.6(17) . .
C17 C16 C19 122.6(18) . .
C16 C17 C18 121.2(15) . .
C16 C17 H17A 119.4 . .
C18 C17 H17A 119.4 . .
C13 C18 C17 119.8(15) . .
C13 C18 H18A 120.1 . .
C17 C18 H18A 120.1 . .
C21 C19 C20 108.2(19) . .
C21 C19 C20' 122(4) . .
C20 C19 C20' 42.1(19) . .
C21 C19 C22' 47(2) . .
C20 C19 C22' 130(4) . .
C20' C19 C22' 107(2) . .
C21 C19 C21' 57.9(19) . .
C20 C19 C21' 65.4(18) . .
C20' C19 C21' 104.8(19) . .
C22' C19 C21' 104.9(19) . .
C21 C19 C22 105.3(18) . .
C20 C19 C22 104.6(18) . .
C20' C19 C22 62.7(19) . .
C22' C19 C22 60.1(19) . .
C21' C19 C22 152(4) . .
C21 C19 C16 115(3) . .
C20 C19 C16 114(3) . .
C20' C19 C16 123(3) . .
C22' C19 C16 115(3) . .
C21' C19 C16 100(3) . .
C22 C19 C16 108(3) . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C19 C20' H20D 109.5 . .
C19 C20' H20E 109.5 . .
H20D C20' H20E 109.5 . .
C19 C20' H20F 109.5 . .
H20D C20' H20F 109.5 . .
H20E C20' H20F 109.5 . .
C19 C21 H21A 109.5 . .
C19 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C19 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C19 C21' H21D 109.5 . .
C19 C21' H21E 109.5 . .
H21D C21' H21E 109.5 . .
C19 C21' H21F 109.5 . .
H21D C21' H21F 109.5 . .
H21E C21' H21F 109.5 . .
C19 C22 H22A 109.5 . .
C19 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C19 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C19 C22' H22D 109.5 . .
C19 C22' H22E 109.5 . .
H22D C22' H22E 109.5 . .
C19 C22' H22F 109.5 . .
H22D C22' H22F 109.5 . .
H22E C22' H22F 109.5 . .
C32 C31 Pt 173.1(14) . .
C31 C32 C33 175.0(17) . .
C38 C33 C34 116.2(15) . .
C38 C33 C32 121.5(14) . .
C34 C33 C32 121.9(15) . .
C33 C34 C35 120.2(18) . .
C33 C34 H34A 119.9 . .
C35 C34 H34A 119.9 . .
C36 C35 C34 122.5(19) . .
C36 C35 H35A 118.7 . .
C34 C35 H35A 118.7 . .
C37 C36 C35 115.5(16) . .
C37 C36 C39 121.3(17) . .
C35 C36 C39 123.2(16) . .
C36 C37 C38 123.7(17) . .
C36 C37 H37A 118.2 . .
C38 C37 H37A 118.2 . .
C33 C38 C37 121.1(16) . .
C33 C38 H38A 119.5 . .
C37 C38 H38A 119.5 . .
C36 C39 C40' 115(2) . .
C36 C39 C41 116(3) . .
C40' C39 C41 126(4) . .
C36 C39 C42 108(3) . .
C40' C39 C42 70(2) . .
C41 C39 C42 109.1(17) . .
C36 C39 C41' 108(2) . .
C40' C39 C41' 109.4(15) . .
C41 C39 C41' 37(2) . .
C42 C39 C41' 140(3) . .
C36 C39 C42' 108(2) . .
C40' C39 C42' 108.8(15) . .
C41 C39 C42' 71(2) . .
C42 C39 C42' 43(2) . .
C41' C39 C42' 107.4(15) . .
C36 C39 C40 108(2) . .
C40' C39 C40 37(2) . .
C41 C39 C40 108.0(17) . .
C42 C39 C40 107.5(17) . .
C41' C39 C40 78(2) . .
C42' C39 C40 139(3) . .
C39 C40 H40A 109.5 . .
C39 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
C39 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
C39 C40' H40D 109.5 . .
C39 C40' H40E 109.5 . .
H40D C40' H40E 109.5 . .
C39 C40' H40F 109.5 . .
H40D C40' H40F 109.5 . .
H40E C40' H40F 109.5 . .
C39 C41 H41A 109.5 . .
C39 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
C39 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
C39 C41' H41D 109.5 . .
C39 C41' H41E 109.5 . .
H41D C41' H41E 109.5 . .
C39 C41' H41F 109.5 . .
H41D C41' H41F 109.5 . .
H41E C41' H41F 109.5 . .
C39 C42 H42A 109.5 . .
C39 C42 H42B 109.5 . .
H42A C42 H42B 109.5 . .
C39 C42 H42C 109.5 . .
H42A C42 H42C 109.5 . .
H42B C42 H42C 109.5 . .
C39 C42' H42D 109.5 . .
C39 C42' H42E 109.5 . .
H42D C42' H42E 109.5 . .
C39 C42' H42F 109.5 . .
H42D C42' H42F 109.5 . .
H42E C42' H42F 109.5 . .
C52 C51 C56 119.9(16) . .
C52 C51 P1 122.3(13) . .
C56 C51 P1 117.7(13) . .
C51 C52 C53 118(2) . .
C51 C52 H52A 121.1 . .
C53 C52 H52A 121.1 . .
C54 C53 C52 121(2) . .
C54 C53 H53A 119.3 . .
C52 C53 H53A 119.3 . .
C55 C54 C53 118(2) . .
C55 C54 H54A 120.8 . .
C53 C54 H54A 120.8 . .
C54 C55 C56 123(2) . .
C54 C55 H55A 118.3 . .
C56 C55 H55A 118.3 . .
C55 C56 C51 119(2) . .
C55 C56 H56A 120.6 . .
C51 C56 H56A 120.6 . .
C66 C61 C62 118.1(17) . .
C66 C61 P1 118.8(14) . .
C62 C61 P1 123.1(15) . .
C63 C62 C61 123(2) . .
C63 C62 H62A 118.6 . .
C61 C62 H62A 118.6 . .
C64 C63 C62 117(2) . .
C64 C63 H63A 121.4 . .
C62 C63 H63A 121.4 . .
C63 C64 C65 122(3) . .
C63 C64 H64A 119.0 . .
C65 C64 H64A 119.0 . .
C64 C65 C66 120(3) . .
C64 C65 H65A 120.0 . .
C66 C65 H65A 120.0 . .
C61 C66 C65 120(2) . .
C61 C66 H66A 120.2 . .
C65 C66 H66A 120.2 . .
C72 C71 C76 117.2(16) . .
C72 C71 P2 121.1(12) . .
C76 C71 P2 121.4(13) . .
C71 C72 C73 123.0(17) . .
C71 C72 H72A 118.5 . .
C73 C72 H72A 118.5 . .
C74 C73 C72 120.5(19) . .
C74 C73 H73A 119.7 . .
C72 C73 H73A 119.7 . .
C73 C74 C75 119(2) . .
C73 C74 H74A 120.4 . .
C75 C74 H74A 120.4 . .
C74 C75 C76 121(2) . .
C74 C75 H75A 119.3 . .
C76 C75 H75A 119.3 . .
C71 C76 C75 118.7(19) . .
C71 C76 H76A 120.6 . .
C75 C76 H76A 120.6 . .
C82 C81 C86 118.4(14) . .
C82 C81 P2 121.0(11) . .
C86 C81 P2 120.1(11) . .
C81 C82 C83 120.3(16) . .
C81 C82 H82A 119.9 . .
C83 C82 H82A 119.9 . .
C84 C83 C82 119.5(16) . .
C84 C83 H83A 120.2 . .
C82 C83 H83A 120.2 . .
C85 C84 C83 120.0(17) . .
C85 C84 H84A 120.0 . .
C83 C84 H84A 120.0 . .
C84 C85 C86 122.1(17) . .
C84 C85 H85A 119.0 . .
C86 C85 H85A 119.0 . .
C85 C86 C81 119.6(15) . .
C85 C86 H86A 120.2 . .
C81 C86 H86A 120.2 . .
C96 C91 C92 118.5(18) . .
C96 C91 P3 121.9(13) . .
C92 C91 P3 119.6(16) . .
C91 C92 C93 119(2) . .
C91 C92 H92A 120.5 . .
C93 C92 H92A 120.5 . .
C94 C93 C92 124(3) . .
C94 C93 H93A 118.1 . .
C92 C93 H93A 118.1 . .
C93 C94 C95 117(3) . .
C93 C94 H94A 121.3 . .
C95 C94 H94A 121.3 . .
C96 C95 C94 121(3) . .
C96 C95 H95A 119.7 . .
C94 C95 H95A 119.7 . .
C91 C96 C95 121(2) . .
C91 C96 H96A 119.7 . .
C95 C96 H96A 119.7 . .
C106 C101 C102 119.5(16) . .
C106 C101 P3 122.3(13) . .
C102 C101 P3 118.1(12) . .
C103 C102 C101 121.3(18) . .
C103 C102 H10A 119.4 . .
C101 C102 H10A 119.4 . .
C104 C103 C102 120(2) . .
C104 C103 H10B 120.1 . .
C102 C103 H10B 120.1 . .
C103 C104 C105 122(2) . .
C103 C104 H10C 119.0 . .
C105 C104 H10C 119.0 . .
C104 C105 C106 121(2) . .
C104 C105 H10D 119.7 . .
C106 C105 H10D 119.7 . .
C101 C106 C105 116.3(19) . .
C101 C106 H10E 121.8 . .
C105 C106 H10E 121.8 . .
C116 C111 C112 119.8(14) . .
C116 C111 P4 120.7(12) . .
C112 C111 P4 119.4(12) . .
C111 C112 C113 118.5(16) . .
C111 C112 H11B 120.8 . .
C113 C112 H11B 120.8 . .
C112 C113 C114 117.9(18) . .
C112 C113 H11C 121.0 . .
C114 C113 H11C 121.0 . .
C115 C114 C113 121.8(18) . .
C115 C114 H11D 119.1 . .
C113 C114 H11D 119.1 . .
C116 C115 C114 118(2) . .
C116 C115 H11E 120.8 . .
C114 C115 H11E 120.8 . .
C115 C116 C111 123.3(18) . .
C115 C116 H11F 118.3 . .
C111 C116 H11F 118.3 . .
C122 C121 C126 118.3(16) . .
C122 C121 P4 122.4(14) . .
C126 C121 P4 119.1(12) . .
C121 C122 C123 121(2) . .
C121 C122 H12B 119.6 . .
C123 C122 H12B 119.6 . .
C124 C123 C122 118(2) . .
C124 C123 H12C 121.0 . .
C122 C123 H12C 121.0 . .
C125 C124 C123 123(2) . .
C125 C124 H12D 118.7 . .
C123 C124 H12D 118.7 . .
C124 C125 C126 117.0(17) . .
C124 C125 H12E 121.5 . .
C126 C125 H12E 121.5 . .
C121 C126 C125 123.1(17) . .
C121 C126 H12F 118.5 . .
C125 C126 H12F 118.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt C31 1.989(14) .
Pt C11 1.995(13) .
Pt P4 2.323(3) .
Pt P2 2.335(4) .
Pt Ag1 3.0018(13) .
Ag1 P3 2.399(4) .
Ag1 P1 2.400(4) .
Ag2 C12 2.303(14) .
Ag2 C12 2.303(14) 7_655
Ag2 C11 2.327(13) .
Ag2 C11 2.327(13) 7_655
Sb1 F12' 1.72(6) .
Sb1 F14' 1.73(4) .
Sb1 F14 1.790(18) .
Sb1 F11 1.795(19) .
Sb1 F11' 1.80(3) .
Sb1 F13 1.802(19) .
Sb1 F12 1.804(19) .
Sb1 F13' 1.81(3) .
Sb1 F16 1.806(12) .
Sb1 F15 1.814(14) .
Sb2 F22 1.748(17) 2_755
Sb2 F22 1.748(17) .
Sb2 F23 1.82(2) .
Sb2 F23 1.82(2) 2_755
Sb2 F24 1.84(2) 2_755
Sb2 F24 1.84(2) .
Sb2 F21 1.849(12) .
Sb2 F21 1.849(12) 2_755
Cl01 C01 1.759(19) .
C01 Cl02 1.781(19) .
C01 H01A 0.9700 .
C01 H01B 0.9700 .
P1 C61 1.810(17) .
P1 C51 1.828(16) .
P1 C1 1.830(15) .
P2 C71 1.806(15) .
P2 C81 1.809(14) .
P2 C1 1.851(14) .
P3 C2 1.827(15) .
P3 C91 1.844(17) .
P3 C101 1.845(15) .
P4 C111 1.816(14) .
P4 C121 1.822(15) .
P4 C2 1.836(14) .
F23 F23 1.25(5) 2_755
F24 F24 1.20(5) 2_755
O1 C02 1.43(2) .
O2 C02 1.44(2) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C11 C12 1.256(17) .
C12 C13 1.433(18) .
C13 C18 1.382(19) .
C13 C14 1.41(2) .
C14 C15 1.37(2) .
C14 H14A 0.9300 .
C15 C16 1.35(3) .
C15 H15A 0.9300 .
C16 C17 1.37(2) .
C16 C19 1.58(3) .
C17 C18 1.39(2) .
C17 H17A 0.9300 .
C18 H18A 0.9300 .
C19 C21 1.53(2) .
C19 C20 1.55(2) .
C19 C20' 1.55(2) .
C19 C22' 1.55(2) .
C19 C21' 1.57(2) .
C19 C22 1.58(2) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C20' H20D 0.9600 .
C20' H20E 0.9600 .
C20' H20F 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C21' H21D 0.9600 .
C21' H21E 0.9600 .
C21' H21F 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C22' H22D 0.9600 .
C22' H22E 0.9600 .
C22' H22F 0.9600 .
C31 C32 1.234(18) .
C32 C33 1.43(2) .
C33 C38 1.34(2) .
C33 C34 1.38(2) .
C34 C35 1.38(2) .
C34 H34A 0.9300 .
C35 C36 1.35(3) .
C35 H35A 0.9300 .
C36 C37 1.32(2) .
C36 C39 1.52(3) .
C37 C38 1.38(2) .
C37 H37A 0.9300 .
C38 H38A 0.9300 .
C39 C40' 1.53(2) .
C39 C41 1.54(2) .
C39 C42 1.54(2) .
C39 C41' 1.54(2) .
C39 C42' 1.55(2) .
C39 C40 1.55(2) .
C40 H40A 0.9600 .
C40 H40B 0.9600 .
C40 H40C 0.9600 .
C40' H40D 0.9600 .
C40' H40E 0.9600 .
C40' H40F 0.9600 .
C41 H41A 0.9600 .
C41 H41B 0.9600 .
C41 H41C 0.9600 .
C41' H41D 0.9600 .
C41' H41E 0.9600 .
C41' H41F 0.9600 .
C42 H42A 0.9600 .
C42 H42B 0.9600 .
C42 H42C 0.9600 .
C42' H42D 0.9600 .
C42' H42E 0.9600 .
C42' H42F 0.9600 .
C51 C52 1.37(2) .
C51 C56 1.43(2) .
C52 C53 1.43(3) .
C52 H52A 0.9300 .
C53 C54 1.41(3) .
C53 H53A 0.9300 .
C54 C55 1.32(3) .
C54 H54A 0.9300 .
C55 C56 1.38(3) .
C55 H55A 0.9300 .
C56 H56A 0.9300 .
C61 C66 1.36(2) .
C61 C62 1.38(2) .
C62 C63 1.36(3) .
C62 H62A 0.9300 .
C63 C64 1.34(4) .
C63 H63A 0.9300 .
C64 C65 1.36(4) .
C64 H64A 0.9300 .
C65 C66 1.37(3) .
C65 H65A 0.9300 .
C66 H66A 0.9300 .
C71 C72 1.36(2) .
C71 C76 1.38(2) .
C72 C73 1.37(2) .
C72 H72A 0.9300 .
C73 C74 1.33(3) .
C73 H73A 0.9300 .
C74 C75 1.35(3) .
C74 H74A 0.9300 .
C75 C76 1.42(3) .
C75 H75A 0.9300 .
C76 H76A 0.9300 .
C81 C82 1.386(19) .
C81 C86 1.402(19) .
C82 C83 1.41(2) .
C82 H82A 0.9300 .
C83 C84 1.37(2) .
C83 H83A 0.9300 .
C84 C85 1.35(2) .
C84 H84A 0.9300 .
C85 C86 1.37(2) .
C85 H85A 0.9300 .
C86 H86A 0.9300 .
C91 C96 1.36(2) .
C91 C92 1.38(2) .
C92 C93 1.38(3) .
C92 H92A 0.9300 .
C93 C94 1.30(4) .
C93 H93A 0.9300 .
C94 C95 1.41(4) .
C94 H94A 0.9300 .
C95 C96 1.36(3) .
C95 H95A 0.9300 .
C96 H96A 0.9300 .
C101 C106 1.35(2) .
C101 C102 1.40(2) .
C102 C103 1.34(2) .
C102 H10A 0.9300 .
C103 C104 1.32(3) .
C103 H10B 0.9300 .
C104 C105 1.33(3) .
C104 H10C 0.9300 .
C105 C106 1.44(3) .
C105 H10D 0.9300 .
C106 H10E 0.9300 .
C111 C116 1.37(2) .
C111 C112 1.41(2) .
C112 C113 1.41(2) .
C112 H11B 0.9300 .
C113 C114 1.43(3) .
C113 H11C 0.9300 .
C114 C115 1.36(3) .
C114 H11D 0.9300 .
C115 C116 1.34(2) .
C115 H11E 0.9300 .
C116 H11F 0.9300 .
C121 C122 1.32(2) .
C121 C126 1.35(2) .
C122 C123 1.39(3) .
C122 H12B 0.9300 .
C123 C124 1.36(3) .
C123 H12C 0.9300 .
C124 C125 1.31(3) .
C124 H12D 0.9300 .
C125 C126 1.38(2) .
C125 H12E 0.9300 .
C126 H12F 0.9300 .
