#------------------------------------------------------------------------------
#$Date: 2017-03-04 16:05:09 +0200 (Sat, 04 Mar 2017) $
#$Revision: 193520 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/12/54/4125410.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4125410
loop_
_publ_author_name
'Piou, Tiffany'
'Romanov-Michailidis, Fedor'
'Romanova-Michaelides, Maria'
'Jackson, Kelvin E.'
'Semakul, Natthawat'
'Taggart, Trevor D.'
'Newell, Brian S.'
'Rithner, Christopher D.'
'Paton, Robert S.'
'Rovis, Tomislav'
_publ_section_title
;
 Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand
 Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental
 and Computational Study.
;
_journal_issue                   3
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              1296
_journal_page_last               1310
_journal_paper_doi               10.1021/jacs.6b11670
_journal_volume                  139
_journal_year                    2017
_chemical_formula_moiety         'C32 H42 Cl4 Rh2, 2(C H Cl3)'
_chemical_formula_sum            'C34 H44 Cl10 Rh2'
_chemical_formula_weight         1013.01
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                74.868(6)
_cell_angle_beta                 75.734(6)
_cell_angle_gamma                68.376(6)
_cell_formula_units_Z            2
_cell_length_a                   10.387(3)
_cell_length_b                   12.581(3)
_cell_length_c                   17.001(4)
_cell_measurement_reflns_used    7253
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      28.60
_cell_measurement_theta_min      2.66
_cell_volume                     1965.6(9)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1750
_diffrn_reflns_av_unetI/netI     0.1360
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            55942
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.282
_diffrn_reflns_theta_min         1.773
_exptl_absorpt_coefficient_mu    1.544
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.712
_exptl_crystal_description       plate
_exptl_crystal_F_000             1016
_exptl_crystal_size_max          0.154
_exptl_crystal_size_mid          0.108
_exptl_crystal_size_min          0.049
_refine_diff_density_max         0.986
_refine_diff_density_min         -1.049
_refine_diff_density_rms         0.284
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.984
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     423
_refine_ls_number_reflns         9667
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.984
_refine_ls_R_factor_all          0.1257
_refine_ls_R_factor_gt           0.0529
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0828P)²+0.4646P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1135
_refine_ls_wR_factor_ref         0.1694
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5686
_reflns_number_total             9667
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            Rh22.cif
_cod_data_source_block           rovis214
_cod_depositor_comments
'Adding full bibliography for 4125410--4125429.cif.'
_cod_original_cell_volume        1965.6(8)
_cod_database_code               4125410
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.797
_shelx_estimated_absorpt_t_max   0.928
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Rh1 Rh 0.45423(6) 0.37088(5) 0.51029(3) 0.01252(14) Uani 1 1 d . .
C1 C 0.5501(7) 0.2083(6) 0.4617(4) 0.0145(15) Uani 1 1 d . .
C2 C 0.6790(7) 0.1190(7) 0.4802(5) 0.0185(16) Uani 1 1 d . .
C3 C 0.6719(8) 0.0275(7) 0.5452(5) 0.0228(17) Uani 1 1 d . .
C4 C 0.5382(8) 0.0245(6) 0.5958(4) 0.0172(15) Uani 1 1 d . .
C5 C 0.4123(8) 0.1111(6) 0.5824(4) 0.0146(15) Uani 1 1 d . .
C6 C 0.4176(7) 0.2061(6) 0.5128(4) 0.0119(10) Uani 1 1 d . .
C7 C 0.3076(7) 0.3111(6) 0.4834(4) 0.0130(14) Uani 1 1 d . .
C8 C 0.3740(8) 0.3685(6) 0.4065(4) 0.0170(15) Uani 1 1 d . .
C9 C 0.5226(7) 0.3102(6) 0.3951(4) 0.0146(15) Uani 1 1 d . .
C10 C 0.8183(8) 0.1280(7) 0.4294(5) 0.0279(19) Uani 1 1 d . .
H10A H 0.8203 0.1276 0.3715 0.042 Uiso 1 1 calc R U
H10B H 0.8953 0.0616 0.4506 0.042 Uiso 1 1 calc R U
H10C H 0.8291 0.2005 0.4332 0.042 Uiso 1 1 calc R U
C11 C 0.8028(8) -0.0717(7) 0.5656(5) 0.0262(18) Uani 1 1 d . .
H11A H 0.7853 -0.1459 0.5753 0.039 Uiso 1 1 calc R U
H11B H 0.8277 -0.0641 0.6153 0.039 Uiso 1 1 calc R U
H11C H 0.8801 -0.0694 0.5192 0.039 Uiso 1 1 calc R U
C12 C 0.5401(9) -0.0791(7) 0.6673(5) 0.0261(18) Uani 1 1 d . .
H12A H 0.5857 -0.1518 0.6460 0.039 Uiso 1 1 calc R U
H12B H 0.4436 -0.0741 0.6940 0.039 Uiso 1 1 calc R U
H12C H 0.5924 -0.0778 0.7076 0.039 Uiso 1 1 calc R U
C13 C 0.2726(8) 0.1100(7) 0.6345(5) 0.0218(17) Uani 1 1 d . .
H13A H 0.2463 0.1611 0.6746 0.033 Uiso 1 1 calc R U
H13B H 0.2795 0.0304 0.6639 0.033 Uiso 1 1 calc R U
H13C H 0.2011 0.1377 0.5989 0.033 Uiso 1 1 calc R U
C14 C 0.1537(8) 0.3546(7) 0.5157(5) 0.0239(18) Uani 1 1 d . .
H14A H 0.1054 0.3139 0.4974 0.036 Uiso 1 1 calc R U
H14B H 0.1165 0.4384 0.4947 0.036 Uiso 1 1 calc R U
H14C H 0.1385 0.3399 0.5762 0.036 Uiso 1 1 calc R U
C15 C 0.2988(9) 0.4736(7) 0.3481(5) 0.0248(18) Uani 1 1 d . .
H15A H 0.3588 0.5225 0.3234 0.037 Uiso 1 1 calc R U
H15B H 0.2110 0.5185 0.3786 0.037 Uiso 1 1 calc R U
H15C H 0.2779 0.4480 0.3043 0.037 Uiso 1 1 calc R U
C16 C 0.6236(8) 0.3464(7) 0.3225(4) 0.0212(17) Uani 1 1 d . .
H16A H 0.6523 0.2932 0.2836 0.032 Uiso 1 1 calc R U
H16B H 0.7065 0.3438 0.3417 0.032 Uiso 1 1 calc R U
H16C H 0.5780 0.4258 0.2948 0.032 Uiso 1 1 calc R U
Cl1 Cl 0.42187(19) 0.34522(16) 0.65762(11) 0.0200(4) Uani 1 1 d . .
Cl2 Cl 0.33101(18) 0.57676(15) 0.50155(11) 0.0170(4) Uani 1 1 d . .
Rh2 Rh 0.36082(6) 0.43218(5) 0.03913(3) 0.01158(14) Uani 1 1 d . .
C17 C 0.1596(7) 0.3972(6) 0.0905(4) 0.0119(10) Uani 1 1 d . .
C18 C 0.1029(7) 0.3691(6) 0.1760(4) 0.0168(15) Uani 1 1 d . .
C19 C 0.0315(7) 0.4595(7) 0.2175(5) 0.0187(16) Uani 1 1 d . .
C20 C 0.0079(7) 0.5798(7) 0.1767(4) 0.0184(16) Uani 1 1 d . .
C21 C 0.0523(7) 0.6097(6) 0.0924(4) 0.0173(15) Uani 1 1 d . .
C22 C 0.1324(7) 0.5170(6) 0.0479(4) 0.0166(15) Uani 1 1 d . .
C23 C 0.2034(7) 0.5173(6) -0.0377(4) 0.0153(15) Uani 1 1 d . .
C24 C 0.2694(7) 0.3974(7) -0.0474(5) 0.0196(16) Uani 1 1 d . .
C25 C 0.2538(7) 0.3219(6) 0.0318(4) 0.0152(15) Uani 1 1 d . .
C26 C 0.1230(9) 0.2426(7) 0.2157(5) 0.031(2) Uani 1 1 d . .
H26A H 0.2137 0.2075 0.2350 0.046 Uiso 1 1 calc R U
H26B H 0.1209 0.2007 0.1751 0.046 Uiso 1 1 calc R U
H26C H 0.0473 0.2379 0.2628 0.046 Uiso 1 1 calc R U
C27 C -0.0304(9) 0.4381(8) 0.3096(5) 0.032(2) Uani 1 1 d . .
H27A H -0.1324 0.4764 0.3171 0.049 Uiso 1 1 calc R U
H27B H 0.0111 0.4699 0.3401 0.049 Uiso 1 1 calc R U
H27C H -0.0094 0.3542 0.3305 0.049 Uiso 1 1 calc R U
C28 C -0.0673(8) 0.6728(7) 0.2284(5) 0.0272(19) Uani 1 1 d . .
H28A H -0.0173 0.6578 0.2741 0.041 Uiso 1 1 calc R U
H28B H -0.1634 0.6717 0.2506 0.041 Uiso 1 1 calc R U
H28C H -0.0701 0.7492 0.1940 0.041 Uiso 1 1 calc R U
C29 C 0.0196(9) 0.7353(7) 0.0480(5) 0.032(2) Uani 1 1 d . .
H29A H -0.0682 0.7830 0.0768 0.048 Uiso 1 1 calc R U
H29B H 0.0096 0.7409 -0.0089 0.048 Uiso 1 1 calc R U
H29C H 0.0962 0.7634 0.0474 0.048 Uiso 1 1 calc R U
C30 C 0.2043(8) 0.6201(7) -0.1072(4) 0.0243(18) Uani 1 1 d . .
H30A H 0.1120 0.6546 -0.1246 0.036 Uiso 1 1 calc R U
H30B H 0.2762 0.5941 -0.1540 0.036 Uiso 1 1 calc R U
H30C H 0.2251 0.6782 -0.0882 0.036 Uiso 1 1 calc R U
C31 C 0.3492(8) 0.3568(8) -0.1271(5) 0.029(2) Uani 1 1 d . .
H31A H 0.4024 0.4089 -0.1587 0.043 Uiso 1 1 calc R U
H31B H 0.2829 0.3578 -0.1597 0.043 Uiso 1 1 calc R U
H31C H 0.4142 0.2775 -0.1147 0.043 Uiso 1 1 calc R U
C32 C 0.3168(8) 0.1908(6) 0.0459(5) 0.0259(18) Uani 1 1 d . .
H32A H 0.3551 0.1625 0.0976 0.039 Uiso 1 1 calc R U
H32B H 0.3922 0.1679 -0.0002 0.039 Uiso 1 1 calc R U
H32C H 0.2440 0.1568 0.0495 0.039 Uiso 1 1 calc R U
Cl3 Cl 0.46214(18) 0.32116(16) 0.16114(11) 0.0184(4) Uani 1 1 d . .
Cl4 Cl 0.41099(17) 0.60821(15) 0.04537(11) 0.0155(4) Uani 1 1 d . .
C33 C 0.2959(9) 0.9352(7) 0.9047(5) 0.0290(19) Uani 1 1 d . .
H33 H 0.3663 0.8579 0.8960 0.035 Uiso 1 1 calc R U
Cl5 Cl 0.1468(3) 0.9581(2) 0.86008(16) 0.0438(6) Uani 1 1 d . .
Cl6 Cl 0.3726(2) 1.04315(19) 0.85605(13) 0.0349(5) Uani 1 1 d . .
Cl7 Cl 0.2456(3) 0.93323(19) 1.01112(14) 0.0440(6) Uani 1 1 d . .
C34 C 0.2551(8) 0.8093(7) 0.2869(5) 0.0228(17) Uani 1 1 d . .
H34 H 0.3330 0.7590 0.3183 0.027 Uiso 1 1 calc R U
Cl8 Cl 0.2583(2) 0.74018(18) 0.20984(12) 0.0312(5) Uani 1 1 d . .
Cl9 Cl 0.2822(4) 0.9426(2) 0.24276(17) 0.0664(9) Uani 1 1 d . .
Cl10 Cl 0.0938(3) 0.8291(3) 0.35640(17) 0.0564(8) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C7 Rh1 C8 40.2(3) . .
C7 Rh1 C9 67.3(3) . .
C8 Rh1 C9 39.0(3) . .
C7 Rh1 C1 66.2(3) . .
C8 Rh1 C1 65.0(3) . .
C9 Rh1 C1 39.3(3) . .
C7 Rh1 C6 39.1(2) . .
C8 Rh1 C6 64.5(3) . .
C9 Rh1 C6 64.9(3) . .
C1 Rh1 C6 38.0(2) . .
C7 Rh1 Cl1 106.92(19) . .
C8 Rh1 Cl1 146.4(2) . .
C9 Rh1 Cl1 153.90(19) . .
C1 Rh1 Cl1 114.63(19) . .
C6 Rh1 Cl1 94.20(18) . .
C7 Rh1 Cl2 102.58(19) . .
C8 Rh1 Cl2 91.5(2) . .
C9 Rh1 Cl2 115.85(19) . .
C1 Rh1 Cl2 154.57(19) . .
C6 Rh1 Cl2 140.74(17) . .
Cl1 Rh1 Cl2 90.18(6) . .
C7 Rh1 Cl2 161.45(19) . 2_666
C8 Rh1 Cl2 123.9(2) . 2_666
C9 Rh1 Cl2 94.14(19) . 2_666
C1 Rh1 Cl2 99.83(19) . 2_666
C6 Rh1 Cl2 133.88(18) . 2_666
Cl1 Rh1 Cl2 89.74(6) . 2_666
Cl2 Rh1 Cl2 85.05(6) . 2_666
C2 C1 C6 120.7(6) . .
C2 C1 C9 131.2(7) . .
C6 C1 C9 108.0(6) . .
C2 C1 Rh1 125.3(5) . .
C6 C1 Rh1 72.2(4) . .
C9 C1 Rh1 68.6(4) . .
C3 C2 C1 118.4(7) . .
C3 C2 C10 121.8(7) . .
C1 C2 C10 119.8(7) . .
C2 C3 C4 120.7(7) . .
C2 C3 C11 121.0(7) . .
C4 C3 C11 118.3(7) . .
C5 C4 C3 122.8(7) . .
C5 C4 C12 119.9(6) . .
C3 C4 C12 117.3(7) . .
C4 C5 C6 117.1(6) . .
C4 C5 C13 123.7(6) . .
C6 C5 C13 119.2(6) . .
C1 C6 C5 120.1(6) . .
C1 C6 C7 108.6(6) . .
C5 C6 C7 131.2(6) . .
C1 C6 Rh1 69.8(4) . .
C5 C6 Rh1 128.0(5) . .
C7 C6 Rh1 66.1(4) . .
C6 C7 C8 106.1(6) . .
C6 C7 C14 130.9(6) . .
C8 C7 C14 122.9(6) . .
C6 C7 Rh1 74.8(4) . .
C8 C7 Rh1 70.9(4) . .
C14 C7 Rh1 122.7(5) . .
C9 C8 C7 109.4(6) . .
C9 C8 C15 124.9(7) . .
C7 C8 C15 125.6(7) . .
C9 C8 Rh1 70.8(4) . .
C7 C8 Rh1 68.9(4) . .
C15 C8 Rh1 126.2(5) . .
C8 C9 C1 107.2(6) . .
C8 C9 C16 123.7(6) . .
C1 C9 C16 128.8(6) . .
C8 C9 Rh1 70.2(4) . .
C1 C9 Rh1 72.2(4) . .
C16 C9 Rh1 126.7(5) . .
Rh1 Cl2 Rh1 94.94(6) . 2_666
C25 Rh2 C23 67.4(3) . .
C25 Rh2 C24 39.6(3) . .
C23 Rh2 C24 39.5(3) . .
C25 Rh2 C22 66.4(3) . .
C23 Rh2 C22 39.3(3) . .
C24 Rh2 C22 65.2(3) . .
C25 Rh2 C17 39.8(2) . .
C23 Rh2 C17 65.5(3) . .
C24 Rh2 C17 65.0(3) . .
C22 Rh2 C17 38.3(2) . .
C25 Rh2 Cl4 112.0(2) . 2_665
C23 Rh2 Cl4 109.55(19) . 2_665
C24 Rh2 Cl4 93.2(2) . 2_665
C22 Rh2 Cl4 148.48(19) . 2_665
C17 Rh2 Cl4 151.73(17) . 2_665
C25 Rh2 Cl3 98.6(2) . .
C23 Rh2 Cl3 158.09(19) . .
C24 Rh2 Cl3 135.4(2) . .
C22 Rh2 Cl3 120.48(19) . .
C17 Rh2 Cl3 92.86(18) . .
Cl4 Rh2 Cl3 91.04(6) 2_665 .
C25 Rh2 Cl4 161.7(2) . .
C23 Rh2 Cl4 97.4(2) . .
C24 Rh2 Cl4 131.9(2) . .
C22 Rh2 Cl4 95.42(19) . .
C17 Rh2 Cl4 125.68(17) . .
Cl4 Rh2 Cl4 82.03(6) 2_665 .
Cl3 Rh2 Cl4 92.67(6) . .
C18 C17 C22 121.0(6) . .
C18 C17 C25 131.0(6) . .
C22 C17 C25 107.9(6) . .
C18 C17 Rh2 126.9(5) . .
C22 C17 Rh2 70.3(4) . .
C25 C17 Rh2 66.5(4) . .
C19 C18 C17 117.6(6) . .
C19 C18 C26 123.4(7) . .
C17 C18 C26 118.9(7) . .
C18 C19 C20 122.1(7) . .
C18 C19 C27 121.5(7) . .
C20 C19 C27 116.5(7) . .
C21 C20 C19 121.4(7) . .
C21 C20 C28 120.6(7) . .
C19 C20 C28 118.0(7) . .
C20 C21 C22 117.8(7) . .
C20 C21 C29 121.8(7) . .
C22 C21 C29 120.3(7) . .
C21 C22 C17 119.8(6) . .
C21 C22 C23 132.0(7) . .
C17 C22 C23 108.1(6) . .
C21 C22 Rh2 124.1(5) . .
C17 C22 Rh2 71.4(4) . .
C23 C22 Rh2 68.0(4) . .
C24 C23 C22 107.3(6) . .
C24 C23 C30 124.0(6) . .
C22 C23 C30 128.6(7) . .
C24 C23 Rh2 70.5(4) . .
C22 C23 Rh2 72.7(4) . .
C30 C23 Rh2 124.9(5) . .
C23 C24 C25 109.5(6) . .
C23 C24 C31 125.4(7) . .
C25 C24 C31 125.0(7) . .
C23 C24 Rh2 70.0(4) . .
C25 C24 Rh2 69.2(4) . .
C31 C24 Rh2 124.7(5) . .
C24 C25 C17 106.7(6) . .
C24 C25 C32 124.1(6) . .
C17 C25 C32 129.1(7) . .
C24 C25 Rh2 71.2(4) . .
C17 C25 Rh2 73.8(4) . .
C32 C25 Rh2 123.3(5) . .
Rh2 Cl4 Rh2 97.97(6) 2_665 .
Cl6 C33 Cl7 111.2(5) . .
Cl6 C33 Cl5 110.0(4) . .
Cl7 C33 Cl5 109.9(5) . .
Cl8 C34 Cl9 110.0(4) . .
Cl8 C34 Cl10 110.6(4) . .
Cl9 C34 Cl10 110.6(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 C7 2.113(7) .
Rh1 C8 2.140(7) .
Rh1 C9 2.149(7) .
Rh1 C1 2.198(6) .
Rh1 C6 2.230(7) .
Rh1 Cl1 2.3945(19) .
Rh1 Cl2 2.4121(19) .
Rh1 Cl2 2.4986(19) 2_666
C1 C2 1.439(10) .
C1 C6 1.441(10) .
C1 C9 1.462(10) .
C2 C3 1.382(11) .
C2 C10 1.518(10) .
C3 C4 1.450(11) .
C3 C11 1.510(10) .
C4 C5 1.384(10) .
C4 C12 1.530(10) .
C5 C6 1.453(9) .
C5 C13 1.505(10) .
C6 C7 1.458(9) .
C7 C8 1.462(10) .
C7 C14 1.495(10) .
C8 C9 1.432(10) .
C8 C15 1.510(10) .
C9 C16 1.500(10) .
Cl2 Rh1 2.4986(18) 2_666
Rh2 C25 2.114(7) .
Rh2 C23 2.135(7) .
Rh2 C24 2.141(7) .
Rh2 C22 2.199(7) .
Rh2 C17 2.214(7) .
Rh2 Cl4 2.3990(18) 2_665
Rh2 Cl3 2.4169(19) .
Rh2 Cl4 2.4876(18) .
C17 C18 1.431(10) .
C17 C22 1.447(10) .
C17 C25 1.476(9) .
C18 C19 1.371(10) .
C18 C26 1.515(10) .
C19 C20 1.447(11) .
C19 C27 1.533(10) .
C20 C21 1.388(10) .
C20 C28 1.509(10) .
C21 C22 1.435(10) .
C21 C29 1.514(10) .
C22 C23 1.460(10) .
C23 C24 1.444(10) .
C23 C30 1.508(10) .
C24 C25 1.442(10) .
C24 C31 1.510(10) .
C25 C32 1.511(10) .
Cl4 Rh2 2.3990(18) 2_665
C33 Cl6 1.747(8) .
C33 Cl7 1.752(8) .
C33 Cl5 1.786(9) .
C34 Cl8 1.739(8) .
C34 Cl9 1.743(8) .
C34 Cl10 1.771(8) .
